5-(4-dimethylaminophenyl)-8-methoxyquinoline | 916162-52-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 5-(4-dimethylaminophenyl)-8-methoxyquinoline
• 英文别名: 4-(8-Methoxyquinolin-5-yl)-N,N-dimethylaniline；4-(8-methoxyquinolin-5-yl)-N,N-dimethylaniline
• CAS: 916162-52-2
• 化学式: C₁₈H₁₈N₂O
• 分子量: 278.354
• InChiKey: WGQKJVDEDPKEQT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  25.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  5-(4-dimethylaminophenyl)-8-methoxyquinoline 、 (p-(t)BuC6H4)2BBr 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 以0.60 g的产率得到4-[8-bis(4-tert-butylphenyl)boranyloxyquinolin-5-yl]-N,N-dimethylaniline
  参考文献：
  名称：

  Luminescence Tuning of Organoboron Quinolates through Substituent Variation at the 5-Position of the Quinolato Moiety

  摘要：

  A series of organoboron quinolates with emission colors ranging from blue to red have been prepared. In comparison to the respective AlQ(3) derivatives a distinct blue-shift of the emission is observed. Theoretical calculations serve to provide insight into the nature of the frontier orbitals and the effect of the substituents in the 5-position of the quinolate ligands on the relative HOMO and LUMO energy levels. An efficient new blue emitting material with a pinacolborane substituent has been identified.

  DOI：

  10.1021/ol0619664

文献信息

• RAFT polymerization of luminescent boron quinolate monomers
  作者：Fei Cheng、Frieder Jäkle

  DOI：10.1039/b920667a

  日期：——

  Fluorescent homopolymers and amphiphilic block copolymers were prepared by reversible addition-fragmentation chain transfer (RAFT) polymerization of two new styryl-type organoboron monomers; the fluorescence characteristics of PEO block copolymers in aqueous solution were studied.

  通过可逆加成-断裂链转移（RAFT）聚合两种新的苯乙烯类有机硼单体，制备了荧光均聚物和两亲性嵌段共聚物；研究了PEO嵌段共聚物在水溶液中的荧光特性。