Formic acid (1R,4aS)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydro-phenanthren-1-yl ester

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Formic acid (1R,4aS)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydro-phenanthren-1-yl ester
• 英文别名: (1,4a-Dimethyl-7-propan-2-yl-2,3,4,9,10,10a-hexahydrophenanthren-1-yl) formate；(1,4a-dimethyl-7-propan-2-yl-2,3,4,9,10,10a-hexahydrophenanthren-1-yl) formate
• 化学式: C₂₀H₂₈O₂
• 分子量: 300.441
• InChiKey: LHNCQXBBPDDBCQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Formic acid (1R,4aS)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydro-phenanthren-1-yl ester 在 碘 、 三苯基膦 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以92%的产率得到19-Norabieta-3,8,11,13-tetraen
  参考文献：
  名称：

  Synthesis of alkenes from tertiary esters utilizing the triphenylphosphine–iodine system

  摘要：

  The treatment of tertiary esters with triphenylphosphine and iodine under mild conditions gives the most stable alkene in good yield. Formates, acetates and trifluoroacetates were studied. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.12.104

文献信息

• POLYESTER POLYMER, RESIN COMPOSITION, MOLDED PRODUCT, AND FILM
  申请人：FUJIFILM Corporation

  公开号：US20130281619A1

  公开（公告）日：2013-10-24

  Provided is a polyester polymer including a repeating unit derived from a dicarboxylic acid compound containing a partial structure represented by the following Formula (C) and a repeating unit derived from a diol compound containing a cyclic structure, in which the partial structure represented by Formula (C) constitutes a portion of the main chain: wherein in Formula (C), R A and R B each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; n and in each independently represent an integer from 0 to 2; Cy represents an unsaturated 6-membered or 7-membered ring which may contain a heteroatom; and * and ** each represent a bonding hand, while * may be a bonding hand extending from R A .
• ELECTROPHOTOGRAPHIC PHOTORECEPTOR AND COPYING MACHINE USING SAME, AND DOPE FOR FORMING PHOTOSENSITIVE LAYER OF SAME
  申请人：FUJIFILM Corporation

  公开号：US20140220484A1

  公开（公告）日：2014-08-07

  In an electrophotographic photoreceptor having a photosensitive layer on a conductive support, a binder resin that constitutes the photosensitive layer includes a polymer containing a skeleton derived from dehydroabietic acid in the main chain. An electrophotographic photoreceptor which accelerates conversion to natural materials from the viewpoint of manufactured product quality or production suitability, since the binder resin of the photosensitive layer has satisfactory solvent solubility.
• US9250515B2
  申请人：——

  公开号：US9250515B2

  公开（公告）日：2016-02-02
• US9321882B2
  申请人：——

  公开号：US9321882B2

  公开（公告）日：2016-04-26
• Synthesis of alkenes from tertiary esters utilizing the triphenylphosphine–iodine system
  作者：E.J. Alvarez-Manzaneda、R. Chahboun、E. Cabrera Torres、E. Alvarez、R. Alvarez-Manzaneda、A. Haidour、J. Ramos

  DOI：10.1016/j.tetlet.2004.12.104

  日期：2005.2

  The treatment of tertiary esters with triphenylphosphine and iodine under mild conditions gives the most stable alkene in good yield. Formates, acetates and trifluoroacetates were studied. (C) 2004 Elsevier Ltd. All rights reserved.