marchantin P

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物
• 英文名称: marchantin P
• 英文别名: 4-Methoxy-2,15-dioxapentacyclo[22.2.2.13,7.110,14.016,21]triaconta-1(26),3,5,7(30),10(29),11,13,16(21),17,19,24,27-dodecaen-17-ol；4-methoxy-2,15-dioxapentacyclo[22.2.2.13,7.110,14.016,21]triaconta-1(26),3,5,7(30),10(29),11,13,16(21),17,19,24,27-dodecaen-17-ol
• 化学式: C₂₉H₂₆O₄
• 分子量: 438.523
• InChiKey: RYMZJKXPOISVKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  33
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  47.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  marchantin P 、 碘甲烷 在 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 3.0h， 以12.5 mg的产率得到marchantin C dimethyl ether
  参考文献：
  名称：

  Chenopodene, marchantin P and riccardin G from the liverwort Marchantia chenopoda

  摘要：

  Marchantia chenopoda collected in Venezuela has been studied and chenopodene, which has a new sesquiterpene skeleton, together with marchantin P and riccardin G, both of which are macrocyclic bis(bibenzyls), were isolated.

  DOI：

  10.1016/s0031-9422(00)97015-8

文献信息

• Chenopodene, marchantin P and riccardin G from the liverwort Marchantia chenopoda
  作者：Motoo Tori、Mamiko Aoki、Yoshinori Asakawa

  DOI：10.1016/s0031-9422(00)97015-8

  日期：1994.5

  Marchantia chenopoda collected in Venezuela has been studied and chenopodene, which has a new sesquiterpene skeleton, together with marchantin P and riccardin G, both of which are macrocyclic bis(bibenzyls), were isolated.