10-bromo-9,9'-bianthracene | 122447-72-7

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 10-bromo-9,9'-bianthracene
• 英文别名: 10-bromo-9,9'-bianthryl；9-anthracen-9-yl-10-bromoanthracene
• CAS: 122447-72-7
• 化学式: C₂₈H₁₇Br
• 分子量: 433.347
• InChiKey: GJOPBRAZGFUAEN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  29
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  10-bromo-9,9'-bianthracene 在 N-溴代丁二酰亚胺(NBS) 、 四(三苯基膦)钯 、 正丁基锂 、 三叔丁基膦 、 palladium diacetate 、 potassium carbonate 、 溶剂黄146 、 sodium t-butanolate 作用下， 以 四氢呋喃 、 乙醇 、 氯仿 、 甲苯 为溶剂， 反应 10.0h， 生成 [10’-(4,6-diphenyl- [1,3,5]triazin-2-yl)-[9,9']bianthracenyl-10-yl]diphenylamine
  参考文献：
  名称：

  Fine tuning of bipolar side group on dual anthracene core derivatives for highly efficient blue emitters

  摘要：

  Three bipolar blue fluorescent materials were newly synthesized by attaching diphenylamine (DPA), triphenylamine (TPA), and 9-phenylcarbazole amine (PCA) as an electron donating group and 2,4- diphenyl-1,3,5-triazine (DPT) as an electron withdrawing group to the dual anthracene core moiety. Compounds are [10'-(4,6-Diphenyl-[1,3,5]triazin-2-yl)-[9,9']bianthracenyl-10-yl]-diphenyl-amine (DPA-AA-DPT), {4-[10'-(4,6-Diphenyl-[1,3,5]triazin-2-yl)-[9,9']bianthracenyl-10-yl]-phenyl}-diphenyl- amine (TPA-AA-DPT), and 9-(4-(10'-(4,6-diphenyl-1,3,5-triazin-2-yl)-[9,9']-bianthracenl-10-yl]-ephenyl)- 9H-carbazole (PCA-AA-DPT), respectively. The optical, thermal, and electroluminescence (EL) properties of the synthesized materials were measured. Newly bipolar materials were found to have blue emission in the solution state and to acquire high PLQY values. A device doped with PCA-AA- DPT showed a very high efficiency of 6.86 cd/A and EQE of 5.53% at a high current density without roll-off phenomenon.

  DOI：

  10.1016/j.dyepig.2020.108555
• 作为产物：
  描述：

  蒽醌 在 盐酸 、 N-溴代丁二酰亚胺(NBS) 、 溶剂黄146 、 锌 作用下， 以 氯仿 、 水 为溶剂， 反应 2.0h， 生成 10-bromo-9,9'-bianthracene
  参考文献：
  名称：

  三重融合的卟啉-石墨烯纳米带杂化物的表面合成和表征。

  摘要：

  表面合成为制备新型的碳基纳米结构提供了一种通用的方法，而这些是常规溶液化学无法获得的。石墨烯纳米带（GNR）具有多种应用潜力。它们在分子电子学中应用的关键问题是通过结构修饰（例如杂原子掺杂或引入非苯环）来微调其电子性能。在这种情况下，GNR和卟啉（Pors）的共价融合是一种极具吸引力的策略。在本文中，我们介绍了Por-GNR杂种的选择性表面合成，该杂种由通过短GNR片段连接的两个Pors组成。Por-GNR杂化物的原子精确结构已通过键分辨扫描隧道显微镜（STM）和非接触原子力显微镜（nc-AFM）进行了表征。

  DOI：

  10.1002/anie.201913024

文献信息

• INDENOTRIPHENYLENE DERIVATIVES AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME
  申请人：LUMINESCENCE TECHNOLOGY CORPORATION

  公开号：US20140131664A1

  公开（公告）日：2014-05-15

  The present invention discloses a new indenotriphenylene derivatives and organic light emitting device using the derivatives. The organic light emitting device employing new indenotriphenylene derivatives as host material can lower driving voltage, prolong half-lifetime, increasing efficiency. The new indenotriphenylene derivatives are represented by the following formula (A): Wherein A 1 , A 2 are substituted or unsubstituted fused ring hydrocarbon units with one to five rings. Preferably A 1 , A 2 are phenyl group, naphthyl group, anthracenyl group, pyrenyl group, chrysenyl group. Perylenyl group. R 1 to R 4 are identical or different. R 1 to R 4 are independently selected from the group consisting of a hydrogen atom, a halide, alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 6 to 30 carbon atoms. X is selected from carbon atom or nitrogen atom.

  本发明公开了一种新的茚三苯衍生物以及使用这些衍生物的有机发光器件。采用新的茚三苯衍生物作为主体材料的有机发光器件可以降低驱动电压，延长半寿命，并提高效率。新的茚三苯衍生物由以下式（A）表示：其中A1，A2是具有一个至五个环的取代或未取代的融合环烃基。最好的情况是A1，A2是苯基，萘基，蒽基，芘基，芴基，蒽基或苝基。R1到R4是相同或不同的。R1到R4独立地选自由氢原子，卤素，具有1至20个碳原子的烷基，具有6至30个碳原子的取代或未取代的芳基，具有6至30个碳原子的取代或未取代的芳基烷基，具有6至30个碳原子的取代或未取代的杂芳基。X选自碳原子或氮原子。
• ORGANIC LIGHT-EMITTING MATERIAL, ORGANIC LIGHT-EMITTING ELEMENT USING THE SAME AND METHOD OF FORMING THE SAME
  申请人：Meng Hsin-Fei

  公开号：US20110163300A1

  公开（公告）日：2011-07-07

  The present invention provides compound of formula (I) wherein each substituent is defined in the specification. The compound may be used, in combination with other organic light-emitting materials, in a light-emitting layer of an organic light-emitting element. The present invention also provides an organic light-emitting element including a first electrode, a second electrode and at least three layers of organic material layers disposed between the first electrode and the second electrode, wherein the layer used as a light-emitting layer contains a compound of formula (I). Further, an all-solution process, which is used for fabricating the organic light-emitting element of the present invention, has the advantages such as avoiding miscibility among the layers to fabricate an element with a large surface area and lower production cost.

  本发明提供了式（I）的化合物，其中每个取代基在说明书中定义。该化合物可与其他有机发光材料结合，在有机发光元件的发光层中使用。本发明还提供了一种有机发光元件，包括第一电极、第二电极和至少三层有机材料层，这些层位于第一电极和第二电极之间，其中用作发光层的层含有式（I）的化合物。此外，本发明用于制造有机发光元件的全溶液工艺具有诸如避免层间混溶等优点，以制造具有较大表面积和较低生产成本的元件。
• Organic electroluminescence device
  申请人：NEC Corporation

  公开号：US06582837B1

  公开（公告）日：2003-06-24

  An organic electroluminescence device having one or more organic thin layers including a luminescent layer between an anode and a cathode, wherein at least one of the organic thin layers contains a compound or compounds selected from the group consisting of particular bianthryl, binaphthyl, trianthrylene and naphthylanthracene compounds, alone or in combination, the general formula of bianthryl compound being shown as follows:

  一种有机电致发光装置，包括一个阳极和一个阴极之间的一个或多个有机薄层，其中至少一个有机薄层包含从特定的苯并二芘、二萘、三苯芘和萘蒽化合物组中选择的一个或多个化合物，单独或组合使用，其中苯并二芘化合物的一般式如下：
• Indenotriphenylene derivatives and organic light emitting device using the same
  申请人：LUMINESCENCE TECHNOLOGY CORPORATION

  公开号：US09260363B2

  公开（公告）日：2016-02-16

  The present invention discloses a new indenotriphenylene derivatives and an organic light emitting device using the derivative. The organic light emitting device employing the new indenotriphenylene derivative as host material can lower driving voltage, prolong half-lifetime, increasing efficiency. The new indenotriphenylene derivative is represented by the following formula(A): According to formula(A), A1, A2 are substituted or unsubstituted aromatic ring systems with one to five rings and independently selected from the group consisting of a phenyl group, a naphthyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group and a perylenyl group. R1 to R4 are identical or different. R1 to R4 are independently selected from the group consisting of a hydrogen atom, a halide, an alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms and a substituted or unsubstituted heteroaryl group having 6 to 30 carbon atoms. X is selected from carbon atom or nitrogen atom.

  本发明揭示了一种新的茚三苯衍生物及其在有机发光器件中的应用。采用新的茚三苯衍生物作为主体材料的有机发光器件可以降低驱动电压，延长半衰期，提高效率。新的茚三苯衍生物由以下公式(A)表示：根据公式(A)，A1、A2是具有1到5个环的取代或未取代芳香环系统，可独立地选自苯基、萘基、蒽基、芘基、蒽醌基和苝基。R1到R4相同或不同，可独立地选自氢原子、卤素、具有1到20个碳原子的烷基、具有6到30个碳原子的取代或未取代芳基、具有6到30个碳原子的取代或未取代芳基烷基、以及具有6到30个碳原子的取代或未取代杂环芳基。X选自碳原子或氮原子。
• Herges, Rainer; Neumann, Helfried, Liebigs Annalen, 1995, # 7, p. 1283 - 1290
  作者：Herges, Rainer、Neumann, Helfried

  DOI：——

  日期：——