| 1044541-09-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 1044541-09-4
• 化学式: C₂₂H₂₄N₂
• 分子量: 316.446
• InChiKey: OLRCJCNSYVAKAU-OEAKJJBVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.23
• 重原子数：
  24.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  25.25
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  、 三甲基铝 以 甲苯 为溶剂， 以94%的产率得到C9H6NCHMeNH(2,6-diisopropylphenyl)
  参考文献：
  名称：

  （氨基甲基）吡啶锆和and配合物：合成与结构表征

  摘要：

  将一系列的2-甲酰基和2-乙酰基吡啶与2，6-二异丙基苯胺缩合，得到相应的亚胺。他们与硼氢化钠的反应得到各自的N-芳基氨基甲基吡啶。用三甲基铝处理N-芳基甲亚氨基-或-乙酰胺基吡啶，然后水解，得到一系列各自取代的N-芳基氨基乙基吡啶衍生物。它们与四苄基锆或四（二甲基氨基）锆或-的反应生成了相应的（螯合物）MX 3系统在各种情况下。这些中的一些在用甲基铝氧烷活化后得到了非常活泼的乙烯聚合催化剂。X射线衍射表征了六个中性氨基烷基吡啶，八种锆或ha配合物和两个铝螯合配合物系统也是如此。

  DOI：

  10.1016/j.jorganchem.2007.12.004
• 作为产物：
  描述：

  2-[(2,6-diisopropylphenylamino)methyl]quinoline-N-oxide 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  (N-Arylaminomethyl)pyridine-N-oxides: Synthesis and characterization of potential ligand systems and the formation of their N,O-chelate aluminum complexes

  摘要：

  Pyridine-N-oxide-2-carbaldehyde (4a) was converted to the corresponding imine (5a) by treatment with 2,6-diisopropylaniline. Subsequent reduction with a sodium borohydride gave the corresponding ( N-arylaminomethyl) pyridine-N-oxide derivative (6a). A series of analogous compounds was prepared starting from the respective ( aldimino) quinoline-N-oxide ( 4b) or ( ketimino) pyridine-N-oxide ( 10) systems. Deprotonation of the ( aminomethyl) pyridine-N-oxides resulted in a series of unexpected reactions, such as coupling, internal redox reactions or fragmentation. Eventually, the N,O-chelate aluminum complexes ( 22, 23) derived from the ( aminoethyl) pyridine-N-oxide ligand systems could be obtained by treatment of the respective iminopyridine-N-oxides with trimethylaluminum. Many products were characterized by X-ray diffraction. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.05.032

文献信息

• IRIDIUM CONTAINING HYDROSILYLATION CATALYSTS AND COMPOSITIONS CONTAINING THE CATALYSTS
  申请人：Dow Corning Corporation

  公开号：EP2758413B1

  公开（公告）日：2018-03-07
• METHOD FOR PRODUCING POLAR GROUP-CONTAINING OLEFIN COPOLYMERS
  申请人：Okumura Yoshikuni

  公开号：US20130165607A1

  公开（公告）日：2013-06-27

  The present invention relates to a method of producing a polymer in the method for producing a copolymer of olefin and a polar group-containing monomer represented by formula (1): C(R 1 ) 2 ═C(R 1 )(C(R 1 ) 2 ) n R 2 (1) (in the formula, the symbols have the same meanings as described in the description), the method comprising using a complex of a metal in Group 10 of the periodic table as a catalyst; and supplying a catalyst solution separated from a polymer after the polymerization reaction to a polymerization reaction system to recycle and re-use the catalyst. The production method of the present invention can dramatically reduce the catalyst cost.
• Titanium Containing Hydrosilylation Catalysts And Compositions Containing The Catalysts
  申请人：Dow Corning Corporation

  公开号：US20140182483A1

  公开（公告）日：2014-07-03

  A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a metal-ligand complex that can be prepared by a method including reacting a metal precursor and a ligand.
• Nickel Containing Hydrosilylation Catalysts and Compositions Containing the Catalysts
  申请人：DOW CORNING CORPORATION

  公开号：US20140183398A1

  公开（公告）日：2014-07-03

  A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a metal-ligand complex that can be prepared by a method including reacting a metal precursor and a ligand,
• Iridium Containing Hydrosilylation Catalysts and Compositions Containing the Catalysts
  申请人：Dow Corning Corporation

  公开号：US20140206869A1

  公开（公告）日：2014-07-24

  A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable, of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a metal-ligand complex that can be prepared by a method including reacting a metal precursor and a ligand.