8,9-epoxy-p-menthane | 35650-70-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: 8,9-epoxy-p-menthane
• 英文别名: 2-Methyl-2-(4-methylcyclohexyl)oxirane
• CAS: 35650-70-5
• 化学式: C₁₀H₁₈O
• 分子量: 154.252
• InChiKey: MONDAUXORXOUDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  8,9-epoxy-p-menthane 在 吡啶 、 lead(IV) acetate 、 sodium hydroxide 、 双氧水 、 calcium carbonate 、 sodium iodide 、 diborane(6) 、 lithium diisopropyl amide 作用下， 以 乙醚 、 丙酮 、 苯 为溶剂， 反应 38.0h， 生成 3,9-epoxy-p-menthyl-10-iodide
  参考文献：
  名称：

  Brocksom, Timothy J.; Ferreira, Tercio B., Synthetic Communications, 1981, vol. 11, # 2, p. 105 - 120

  摘要：

  DOI：
• 作为产物：
  描述：

  4-isopropenyl-1-methylcyclohexane 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以76%的产率得到8,9-epoxy-p-menthane
  参考文献：
  名称：

  Brocksom, Timothy J.; Ferreira, Tercio B., Synthetic Communications, 1981, vol. 11, # 2, p. 105 - 120

  摘要：

  DOI：

文献信息

• THERMOSETTING RESIN COMPOSITION AND PHOTOSEMICONDUCTOR ENCAPSULATION MATERIAL
  申请人：Asahi Kasei Kabushiki Kaisha

  公开号：EP1947128A1

  公开（公告）日：2008-07-23

  A thermosetting resin compositing having an essential component (A) organopolysiloxane containing a compound represented by following general formula (1) or (2) and optical semiconductor peripheral material using the composition. [Herein, in the formulas, R1 independently represents a substituted or non-substituted monovalent hydrocarbon radical with the carbon number of 1 to 10, R2 represents an epoxy group-containing organic group, R3 represents R1 or R2, a independently represents an integer of 2 or more, b independently represents an integer of 0 or more, X represents general formula (3), Y represents -o- or a bivalent hydrocarbon radical with the carbon number of 1 to 6, Z represents following formula (4), R1 in the formula independently represents a substituted or non-substituted monovalent hydrocarbon radical with the carbon number of 1 to 10, and c represents an integer of 0 or more.]

  一种热固性树脂组合物，其基本成分（A）是含有通式（1）或（2）所代表化合物的有机聚硅氧烷，以及使用该组合物的光学半导体外围材料。[这里，在通式中，R1 独立地代表碳原子数为 1～10 的取代或非取代的一价烃基，R2 代表含环氧基的有机基团，R3 代表 R1 或 R2，a 独立地代表 2 以上的整数，b 独立地代表 0 以上的整数、X 代表通式 (3)，Y 代表-o-或碳原子数为 1-6 的二价烃基，Z 代表下式 (4)，式中的 R1 独立地代表碳原子数为 1-10 的取代或非取代的一价烃基，c 代表 0 或以上的整数。]
• Thermosetting resin composition and photosemiconductor encapsulation material
  申请人：Asahi Kasei Chemicals Corporation

  公开号：EP2508545A1

  公开（公告）日：2012-10-10

  A thermosetting resin compositing having an essential component (A) organopolysiloxane containing a compound represented by following general formula a (1) or (2) and optical semiconductor peripheral material using the composition. [Herein, in the formulas, R1 independently represents a substituted or non-substituted monovalent hydrocarbon radical with the carbon number of 1 to 10, R2 represents an epoxy group-containing organic group, R3 represents R1 or R2, a independently represents an integer of 2 or more, b independently represents an integer of 0 or more, X represents general formula (3), Y represents -o- or a bivalent hydrocarbon radical with the carbon number of 1 to 6, Z represents following formula (4), R1 in the formula independently represents a substituted or non-substituted monovalent hydrocarbon radical with the carbon number of 1 to 10, and c represents an integer of 0 or more.]

  一种热固性树脂组合物，其基本成分（A）为含有通式 a（1）或（2）所代表化合物的有机聚硅氧烷，以及使用该组合物的光学半导体外围材料。[这里，在通式中，R1 独立地代表碳原子数为 1-10 的取代或非取代的一价烃基，R2 代表含环氧基的有机基团，R3 代表 R1 或 R2，a 独立地代表 2 以上的整数，b 独立地代表 0 以上的整数、X 代表通式 (3)，Y 代表-o-或碳原子数为 1-6 的二价烃基，Z 代表下式 (4)，式中的 R1 独立地代表碳原子数为 1-10 的取代或非取代的一价烃基，c 代表 0 或以上的整数。]
• Optimization of the lipase mediated epoxidation of monoterpenes using the design of experiments—Taguchi method
  作者：Sumanth Ranganathan、Johannes Tebbe、Lars O. Wiemann、Volker Sieber

  DOI：10.1016/j.procbio.2016.07.005

  日期：2016.10

  This work deals with the optimization of the Candida antartica lipase B (CALB) mediated epoxidation of monoterpenes by using the design of experiments (DoE) working with the Taguchi Method. Epoxides are essential organic intermediates that find various industrial applications making the epoxidation one of the most investigated processes in chemical industry. As many as 8 parameters such as the reaction medium, carboxylic acid type, carboxylic acid concentration, temperature, monoterpene type, monoterpene concentration, hydrogen peroxide concentration and amount of lipase were optimized using as less as 18 runs in triplicates (54 runs). As a result, the hydrogen peroxide concentration used was found to be the most influential parameter of this process while the type of monoterpene was least influential. Scaling up of the reaction conditions according to the findings of the optimization achieved full conversion in less than 6 h. In addition, a purification process for the epoxides was developed leading to an isolated yield of ca. 72.3%, 88.8% and 62.5% for alpha-pinene, 3-carene and limonene, respectively. (C) 2016 Elsevier Ltd. All rights reserved.
• NITRILE PERFUMERY MATERIAL
  申请人：Bush Boake Allen Inc.

  公开号：EP0963194A1

  公开（公告）日：1999-12-15
• COSMETIC FORMULATIONS FOR THE PREVENTION AND THERAPY OF HAIR LOSS
  申请人：Verona, Giancarlo

  公开号：EP1023034A1

  公开（公告）日：2000-08-02