nicotinic acid bornyl ester | 88382-44-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: nicotinic acid bornyl ester
• 英文别名: Nicotinsaeure-bornylester；1,7,7-Trimethylbicyclo[2.2.1]heptan-2-yl pyridine-3-carboxylate；(1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl) pyridine-3-carboxylate
• CAS: 88382-44-9
• 化学式: C₁₆H₂₁NO₂
• mdl: MFCD24741041
• 分子量: 259.348
• InChiKey: DTFIJWHXPYDRKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.625
• 拓扑面积：
  39.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  烟酸 、 borneol 以2.5%的产率得到nicotinic acid bornyl ester
  参考文献：
  名称：

  Esterification reaction on deformation of mixtures of solid organic acids and alcohols under the action of pressure

  摘要：

  DOI：

  10.1007/bf00954695

文献信息

• Enzymatic method for producing fatty acid bornyl ester
  申请人：Jiangnan University

  公开号：US11365434B2

  公开（公告）日：2022-06-21

  The present invention provides an enzymatic method for producing a fatty acid bornyl ester including using borneol and a fatty acid as a substrate for reaction and adding a lipase in a solvent system or a solvent-free system to catalyze the esterification reaction for a period of time to obtain fatty acid bornyl ester. The present method preferably uses fatty acids or their derivatives as acyl donors to prepare fatty acid bornyl esters. By utilizing the characteristics of the substrate, the synthesis process is simple; the reaction efficiency is high; and the content of fatty acid bornyl ester is up to 97%.

  本发明提供了一种生产脂肪酸硼醇酯的酶法，包括以硼醇和脂肪酸为底物进行反应，在溶剂体系或无溶剂体系中加入脂肪酶催化酯化反应一段时间，得到脂肪酸硼醇酯。本方法优选使用脂肪酸或其衍生物作为酰基供体来制备脂肪酸硼酯。利用底物的特性，合成工艺简单，反应效率高，脂肪酸硼酯的含量可达 97%。
• YAKOVLEVA, I. I.;ZHAROV, A. A.;ZHULIN, O. M., IZV. AN CCCP. CEP. XIM., 1983, N 9, 2174-2175
  作者：YAKOVLEVA, I. I.、ZHAROV, A. A.、ZHULIN, O. M.

  DOI：——

  日期：——
• ENZYMATIC METHOD FOR PRODUCING FATTY ACID BORNYL ESTER
  申请人：Jiangnan University

  公开号：US20210130859A1

  公开（公告）日：2021-05-06

  The present invention provides an enzymatic method for producing a fatty acid bornyl ester including using borneol and a fatty acid as a substrate for reaction and adding a lipase in a solvent system or a solvent-free system to catalyze the esterification reaction for a period of time to obtain fatty acid bornyl ester. The present method preferably uses fatty acids or their derivatives as acyl donors to prepare fatty acid bornyl esters. By utilizing the characteristics of the substrate, the synthesis process is simple; the reaction efficiency is high; and the content of fatty acid bornyl ester is up to 97%.
• Esterification reaction on deformation of mixtures of solid organic acids and alcohols under the action of pressure
  作者：I. I. Yakovleva、A. A. Zharov、V. M. Zhulin

  DOI：10.1007/bf00954695

  日期：1983.9