2-Hydroxy-2-methyl-decanenitrile | 144981-07-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-Hydroxy-2-methyl-decanenitrile
• 英文别名: 2-Hydroxy-2-methyldecanenitrile
• CAS: 144981-07-7
• 化学式: C₁₁H₂₁NO
• 分子量: 183.294
• InChiKey: YAOMWVDZIQXKRA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  44
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-Hydroxy-2-methyl-decanenitrile 、 三氟乙酸酐 在 吡啶 作用下， 以 二氯甲烷 、 异丙醚 为溶剂， 生成
  参考文献：
  名称：

  AnR-Selective Hydroxynitrile Lyase fromArabidopsis thalianawith an α/β-Hydrolase Fold

  摘要：

  DOI：

  10.1002/anie.200701455
• 作为产物：
  描述：

  2-癸酮 、 氰化钾 在 溶剂黄146 作用下， 以 水 为溶剂， 生成 2-Hydroxy-2-methyl-decanenitrile
  参考文献：
  名称：

  梅一种新的（R）-羟基腈裂解酶：氰醇的不对称合成。

  摘要：

  从日本杏（Prunus mume）的种子中分离出一种新的羟腈裂解酶（HNL ）。该酶与从其他李属物种中分离的HNL具有相似的特性，并且是含FAD的酶。它接受大量非天然底物（苯甲醛及其变体）以添加HCN，从而以优异的光学和化学收率生产相应的氰醇。针对该酶开发了一种新的基于HPLC的对映选择性测定技术，该技术可促进在缓冲溶液（pH = 4.5）中将KCN添加到苯甲醛中。

  DOI：

  10.1016/j.tet.2005.08.105

文献信息

• Fungicidal 4-thixooxazolidin-2-ones and 4-iminooxazolindin-2-ones
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0503798A1

  公开（公告）日：1992-09-16

  This invention pertains to compounds of Formula I including all geometric and stereoisomers, agriculturally suitable salts thereof, agricultural compositions containing them and their use as fungicides.

  这项发明涉及包括所有几何和立体异构体的化合物I的农业适用盐，含有它们的农业组合物以及它们作为杀菌剂的用途。
• FUNGICIDAL 4-THIOXOOXAZOLIDIN-2-ONES AND 4-IMINOOXAZOLINDIN-2-ONES
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0577712B1

  公开（公告）日：1998-07-29
• US20140274682A1
  申请人：——

  公开号：US20140274682A1

  公开（公告）日：2014-09-18
• COMPOUNDS, COMPOSITIONS, AND METHODS FOR ALTERING INSECT AND ORGANISM BEHAVIOR
  申请人：BAYER CROPSCIENCE LP

  公开号：US20150257384A1

  公开（公告）日：2015-09-17

  The disclosure provides for methods of repelling, directing, altering the behavior, and controlling an insect by utilizing a compound or composition described herein. The disclosure also provides for methods of promoting the health of an insect by repelling a pest that preys on insect and/or by providing an antibiotic or nutritional supplement composition to an insect. The disclosure also provides for a composition including at least one repelling, controlling, or directing compound or composition described herein together with an insecticide, herbicide, fungicide, or miticide. Compounds, compositions, seeds, and plants useful in these methods are also described.
• COMPOUNDS, COMPOSITIONS, AND METHODS FOR REPELLING AN INSECT FROM AN AREA,ARTICLE, AND/OR STRUCTURE
  申请人：BAYER CROPSCIENCE LP

  公开号：US20160029628A1

  公开（公告）日：2016-02-04

  The disclosure provides for methods of repelling, directing, altering the behavior, and/or controlling an insect by utilizing a compound or composition described herein. The disclosure also provides for methods of repelling or directing an insect from an organism, article, or structure by utilizing a compound or composition described herein. The disclosure also provides for an article or structure treated with a composition including at least one repellent, controlling, or directing compound described herein.