5,5'-(3,3'-((4-nitrophenyl)methylene)-bis-(1H-indole-3,1-diyl)-bis-(methylene)diquinolin-8-ol) | 1278403-27-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 5,5'-(3,3'-((4-nitrophenyl)methylene)-bis-(1H-indole-3,1-diyl)-bis-(methylene)diquinolin-8-ol)
• 英文别名: 5,5'-(3,3'-((4-nitrophenyl)methylene)-bis(1H-indole-3,1-diyl)-bis(methylene))diquinolin-8-ol；NIMQ；5-[[3-[[1-[(8-Hydroxyquinolin-5-yl)methyl]indol-3-yl]-(4-nitrophenyl)methyl]indol-1-yl]methyl]quinolin-8-ol
• CAS: 1278403-27-2
• 化学式: C₄₃H₃₁N₅O₄
• 分子量: 681.75
• InChiKey: ODJUIZSMQJODMH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  52
• 可旋转键数：
  7
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  122
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  5,5'-(3,3'-((4-nitrophenyl)methylene)-bis-(1H-indole-3,1-diyl)-bis-(methylene)diquinolin-8-ol) 、 nickel diacetate 在 NH₄OH 作用下， 以 甲酸 为溶剂， 以82%的产率得到[nickel(II)(5,5'-(3,3'-((4-nitrophenyl)methylene)-bis-(1H-indole-3,1-diyl)-bis(methylene))diquinolin-8-ol(-2H))]
  参考文献：
  名称：

  Coordination Polymers of Indole Based Bis-ligand: Thermal, Spectral, and Antimicrobial Aspects

  摘要：

  A few coordination polymers of Cu(II), Zn(II), Mn(II), Co(II), and Ni(II), obtained from the reaction of metal acetate with newly synthesized ligand, namely [(5,5'-(3, 3'-((4-nitrophenyl)methylene)-bis-(1H-indole-3,1-diyl)-bis-(methylene)diquinolin-8-ol)] (NIMQ), are described here. The ligand has been characterized by elemental analysis, 1H-NMR, and 13C-NMR spectra and thermogravimetric analysis. Elemental analysis, infrared and electronic reflectance spectra, magnetic susceptibility measurements, and thermogravimetry have been employed to characterize the coordination polymers. Magnetic moment and reflectance spectral studies reveal that a distorted octahedral geometry has been assigned to all the prepared coordination polymers. The microbicidal activity of all the samples has also been monitored against plant pathogens.

  DOI：

  10.1080/15533174.2010.522882
• 作为产物：
  描述：

  5-(氯甲基)-8-羟基喹啉盐酸盐 、 3-[(1H-indol-3-yl)(4-nitrophenyl)methyl]-1H-indole 以 丙酮 为溶剂， 反应 2.5h， 以70%的产率得到5,5'-(3,3'-((4-nitrophenyl)methylene)-bis-(1H-indole-3,1-diyl)-bis-(methylene)diquinolin-8-ol)
  参考文献：
  名称：

  Coordination Polymers of Indole Based Bis-ligand: Thermal, Spectral, and Antimicrobial Aspects

  摘要：

  A few coordination polymers of Cu(II), Zn(II), Mn(II), Co(II), and Ni(II), obtained from the reaction of metal acetate with newly synthesized ligand, namely [(5,5'-(3, 3'-((4-nitrophenyl)methylene)-bis-(1H-indole-3,1-diyl)-bis-(methylene)diquinolin-8-ol)] (NIMQ), are described here. The ligand has been characterized by elemental analysis, 1H-NMR, and 13C-NMR spectra and thermogravimetric analysis. Elemental analysis, infrared and electronic reflectance spectra, magnetic susceptibility measurements, and thermogravimetry have been employed to characterize the coordination polymers. Magnetic moment and reflectance spectral studies reveal that a distorted octahedral geometry has been assigned to all the prepared coordination polymers. The microbicidal activity of all the samples has also been monitored against plant pathogens.

  DOI：

  10.1080/15533174.2010.522882

文献信息

• Coordination Polymers of Indole Based Bis-ligand: Thermal, Spectral, and Antimicrobial Aspects
  作者：Hasmukh S. Patel、Darshana J. Patel

  DOI：10.1080/15533174.2010.522882

  日期：2011.1.31

  A few coordination polymers of Cu(II), Zn(II), Mn(II), Co(II), and Ni(II), obtained from the reaction of metal acetate with newly synthesized ligand, namely [(5,5'-(3, 3'-((4-nitrophenyl)methylene)-bis-(1H-indole-3,1-diyl)-bis-(methylene)diquinolin-8-ol)] (NIMQ), are described here. The ligand has been characterized by elemental analysis, 1H-NMR, and 13C-NMR spectra and thermogravimetric analysis. Elemental analysis, infrared and electronic reflectance spectra, magnetic susceptibility measurements, and thermogravimetry have been employed to characterize the coordination polymers. Magnetic moment and reflectance spectral studies reveal that a distorted octahedral geometry has been assigned to all the prepared coordination polymers. The microbicidal activity of all the samples has also been monitored against plant pathogens.