18-(3-Dibenzothiophen-4-ylphenyl)-16-oxahexacyclo[12.11.0.02,7.08,13.015,23.017,22]pentacosa-1(14),2,4,6,8,10,12,15(23),17(22),18,20,24-dodecaene | 1417161-03-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 18-(3-Dibenzothiophen-4-ylphenyl)-16-oxahexacyclo[12.11.0.02,7.08,13.015,23.017,22]pentacosa-1(14),2,4,6,8,10,12,15(23),17(22),18,20,24-dodecaene
• 英文别名: 18-(3-dibenzothiophen-4-ylphenyl)-16-oxahexacyclo[12.11.0.02,7.08,13.015,23.017,22]pentacosa-1(14),2,4,6,8,10,12,15(23),17(22),18,20,24-dodecaene
• CAS: 1417161-03-5
• 化学式: C₄₂H₂₄OS
• 分子量: 576.718
• InChiKey: MBUHSUURJSNHQB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.2
• 重原子数：
  44
• 可旋转键数：
  2
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  41.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-(2-bromophenyl)dibenzofuran 在 四(三苯基膦)钯 、 正丁基锂 、 1,1'-双(二苯膦基)二茂铁二氯化钯(II)二氯甲烷复合物 、 potassium acetate 、 sodium carbonate 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 乙醚 、 乙醇 、 正己烷 、 水 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 37.5h， 生成 18-(3-Dibenzothiophen-4-ylphenyl)-16-oxahexacyclo[12.11.0.02,7.08,13.015,23.017,22]pentacosa-1(14),2,4,6,8,10,12,15(23),17(22),18,20,24-dodecaene
  参考文献：
  名称：

  [EN] TRIPHENYLENO-BENZOFURAN COMPOUND AND ORGANIC LIGHT EMITTING ELEMENT INCLUDING THE SAME
  [FR] COMPOSÉ DE TRIPHÉNYLÉNO-BENZOFURANNE ET ÉLÉMENT ORGANIQUE LUMINESCENT LE CONTENANT

  摘要：

  提供了一种实现高效长寿命发光的有机发光元件。提供了一种由权利要求书中所述的通式[1]表示的有机化合物。在通式[1]中，R1至R3分别独立地选自氢原子、取代或未取代的芳基团和取代或未取代的杂环基。但是，R1至R3中至少有一个代表芳基团或杂环基。芳基团代表苯基、萘基、菲基、芴基、三苯基基团或蒽基团。杂环基代表二苯并呋喃基或二苯并噻吩基。

  公开号：

  WO2013001997A1

文献信息

• TRIPHENYLENO-BENZOFURAN COMPOUND AND ORGANIC LIGHT EMITTING ELEMENT INCLUDING THE SAME
  申请人：Horiuchi Takayuki

  公开号：US20140197392A1

  公开（公告）日：2014-07-17

  An organic light emitting element which realizes a high efficiency and long-life light emission is provided. An organic compound represented by the general formula [1] described in Claim 1 is provided. In the general formula [1], R 1 to R 3 are each independently selected from a hydrogen atom, a substituted or unsubstituted aryl group, and a substituted or unsubstituted heterocyclic group. However, at least one of R 1 to R 3 represents the aryl group or the heterocyclic group. The aryl group represents a phenyl group, a naphthyl group, a phenanthrenyl group, a fluorenyl group, a triphenylenyl group, or a chrysenyl group. The heterocyclic group represents a dibenzofuranyl group or a dibenzothienyl group.
• [EN] TRIPHENYLENO-BENZOFURAN COMPOUND AND ORGANIC LIGHT EMITTING ELEMENT INCLUDING THE SAME<br/>[FR] COMPOSÉ DE TRIPHÉNYLÉNO-BENZOFURANNE ET ÉLÉMENT ORGANIQUE LUMINESCENT LE CONTENANT
  申请人：CANON KK

  公开号：WO2013001997A1

  公开（公告）日：2013-01-03

  An organic light emitting element which realizes a high efficiency and long-life light emission is provided. An organic compound represented by the general formula [1] described in Claim 1 is provided. In the general formula [1], R1 to R3 are each independently selected from a hydrogen atom, a substituted or unsubstituted aryl group, and a substituted or unsubstituted heterocyclic group. However, at least one of R1 to R3 represents the aryl group or the heterocyclic group. The aryl group represents a phenyl group, a naphthyl group, a phenanthrenyl group, a fluorenyl group, a triphenylenyl group, or a chrysenyl group. The heterocyclic group represents a dibenzofuranyl group or a dibenzothienyl group.

  提供了一种实现高效长寿命发光的有机发光元件。提供了一种由权利要求书中所述的通式[1]表示的有机化合物。在通式[1]中，R1至R3分别独立地选自氢原子、取代或未取代的芳基团和取代或未取代的杂环基。但是，R1至R3中至少有一个代表芳基团或杂环基。芳基团代表苯基、萘基、菲基、芴基、三苯基基团或蒽基团。杂环基代表二苯并呋喃基或二苯并噻吩基。