2-(β-D-Glucopyranosyloxy)-2-phenylacetonitril | 13093-89-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-(β-D-Glucopyranosyloxy)-2-phenylacetonitril
• 英文别名: Sambunigrin；Glucopyranoside, I+/--cyanobenzyl, D-；2-phenyl-2-[(3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyacetonitrile
• CAS: 13093-89-5
• 化学式: C₁₄H₁₇NO₆
• 分子量: 295.292
• InChiKey: ZKSZEJFBGODIJW-JURVZFMHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.7
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  123
• 氢给体数：
  4
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  扁桃腈 在 sodium methylate 、 氰化汞 、 mercury dibromide 作用下， 以 甲醇 、 乙腈 为溶剂， 反应 0.32h， 生成 2-(β-D-Glucopyranosyloxy)-2-phenylacetonitril
  参考文献：
  名称：

  Junghans, Pharmazie, 1982, vol. 37, # 3, p. 172 - 175

  摘要：

  DOI：

文献信息

• Liposome comprising a novel phosphate as membrane constituent, liposome preparations and cosmetic preparations comprising said phosphate
  申请人：KAO CORPORATION

  公开号：EP0370491A2

  公开（公告）日：1990-05-30

  A novel monophosphate and a novel diphosphate prepared by a phosphatidyl transfer reaction of a phospholipid and an alcohol in the presence of phospholipase D are disclosed. The phosphates can independently or together form small and stable liposomes which can include active components therein. Cosmetic compositions comprising these phosphates or liposomes penetrate well into the hair and the skin, and exhibit long-lasting excellent moisture-retaining, beauty, skin-activation effects.

  本研究公开了一种新型单磷酸盐和一种新型二磷酸盐，它们是在磷脂酶 D 的存在下，通过磷脂和醇的磷脂酰转移反应制备的。这些磷酸盐可单独或共同形成小而稳定的脂质体，其中可包含活性成分。包含这些磷酸盐或脂质体的化妆品组合物可以很好地渗透到头发和皮肤中，并表现出持久的出色保湿、美容和活肤效果。
• Pesticidal compositions from prunus
  申请人：——

  公开号：US20040105901A1

  公开（公告）日：2004-06-03

  The foliage and stems of plant species from the family Rosaceae, genus Prunus, yield natural pesticides when macerated. Hydrodistillation of macerated plant biomass yields a concentrated solution of organic volatile compounds that act synergistically as a natural pesticide. Volatile compounds liberated from Prunus biomass include 2-propanol, hexanal, trans-2-hexenal, 1-hexanol, cis-3-hexenol, mandelonitrile, benzoic acid, benzaldehyde, benzyl alcohol, hydrocyanic acid and others. These compounds may be removed from the distillate and reformulated to form a standard concentrated solution, with benzaldehyde, mandelonitrile and hydrogen cyanide being the major components. The extracts may be used as a soil treatment or soil fumigant for soil-borne pests. They also may be formulated for application as solutions with or without a surfactant or formulated as powders for foliar treatment. In a particular application, such extracts may be applied to postharvest commodities such as fruits, vegetables, roots, grains and nuts to protect against certain fungi and insects.

  蔷薇科梅属植物的叶子和茎经浸渍后可产生天然杀虫剂。对浸渍过的植物生物质进行水蒸馏，可得到一种有机挥发性化合物的浓缩溶液，这种溶液具有天然杀虫剂的协同作用。从梅花生物质中释放出的挥发性化合物包括 2-丙醇、己醛、反式-2-己烯醛、1-己醇、顺式-3-己烯醇、扁桃腈、苯甲酸、苯甲醛、苯甲醇、氢氰酸等。这些化合物可以从蒸馏液中去除，并重新配制成标准浓缩溶液，其中苯甲醛、扁桃腈和氰化氢是主要成分。萃取物可用作土壤处理剂或土壤熏蒸剂，用于防治土壤中的害虫。它们还可以配制成溶液（含或不含表面活性剂），或配制成粉末用于叶面处理。在一种特殊的应用中，这种提取物可用于收获后的商品，如水果、蔬菜、根茎、谷物和坚果，以防止某些真菌和昆虫。
• Method of Obtaining Cyanogenic Glycoside and Related Glycosides, as Well as Genin and Sapogenins Derivatives of Plants of the Family Sapotaceae for the Preparation of Cosmetics and Dermatological Compositions
  申请人：De La Llata Romero Luis

  公开号：US20080261291A1

  公开（公告）日：2008-10-23

  Procedure for the obtaining of genin and sapogenins extracts by enzymatic hydrolysis of kernels derived of the family Sapotaceae, genus Calocarpum, Chrysophyllum and Lucuma . The enzymes that catalyzes the hydrolysis are exogenous β-glucosidases, of vegetable or microbial origin. The process uses mainly diverse kernel (seeds removed of the endocarp) derived but can also use the cyanogenic glycoside, lucumin and the related similar glycosides directly. It is also object of protection the process for the obtaining of these glycosides, starting of those kernels derived and the usage of these in the obtaining of genin and sapogenins and its uses in cosmetic and dermatologic compositions. The genin and sapogenins extracts are the main products used with these basic similar aims. The obtained genin extract are used in topical compositions to promote the opening of the pore facilitating the epithelial penetration or it can be used as flavouring or scent agent in foods or in alternating similar uses like in perfumery. The obtained sapogenins extract are used in topical compositions as astringent, defoliant, to favour oily skin penetration, to promote the renovation of the skin, to combat the epithelial aging, the growth of the hair or slow its fallen. The effect of oily skin penetration is enhanced synergised with a lipidic phase of the same Sapotaceae family. Besides the sapogenins have bacteriostatic and fungistatic activity in the compositions, in its topical use or in diverse preparations.
• Method for Processing Rosaceous Kernels
  申请人：Hwang Richard

  公开号：US20160101140A1

  公开（公告）日：2016-04-14

  A method for processing rosaceous kernels includes the steps of preparing a predetermined amount of rosaceous kernels, heating the rosaceous kernels to a predetermined temperature range for a predetermined time, lowering a temperature of the rosaceous kernels to a normal temperature, and making the rosaceous kernels edible for users to intake Vit B17 contained in the rosaceous kernels. Through the heating process, the beta-glucosidase contained in the rosaceous kernels can be destroyed completely, but the Vit B17 still stays in the rosaceous kernels.
• US4490523A
  申请人：——

  公开号：US4490523A

  公开（公告）日：1984-12-25