1,1,2,2,5,5,6,6,9,9,10,10-dodecahydroperfluoro-1-dodecanol | 1159854-10-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1,2,2,5,5,6,6,9,9,10,10-dodecahydroperfluoro-1-dodecanol
• 英文别名: 3,3,4,4,7,7,8,8,11,11,12,12,12-tridecafluoro-dodecan-1-ol；3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-dodecan-1-ol；3,3,4,4,7,7,8,8,11,11,12,12,12-Tridecafluorododecane-1-ol；3,3,4,4,7,7,8,8,11,11,12,12,12-tridecafluorododecan-1-ol
• CAS: 1159854-10-0
• 化学式: C₁₂H₁₃F₁₃O
• 分子量: 420.214
• InChiKey: ZSSGQKVHSWOMGP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  26
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  1,1,2,2,5,5,6,6,9,9,10,10-dodecahydroperfluoro-1-dodecanol 、 丙烯酰氯 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 以84%的产率得到1,1,2,2,5,5,6,6,9,9,10,10-dodecahydroperfluorododecyl acrylate
  参考文献：
  名称：

  Ethylene-tetrafluoroethylene intermediates

  摘要：

  公式(I)的寡聚物：CnF2n+1(CH2)x[(CF2CF2)y(CH2CH2)z]mG  (I)其中G是I; OH; OC(O)CH═CH2; OC(O)CCH3═CH2; OC(O)CCl═CH2; NR1H; N3; NCO; SQ，其中Q是H，烷基，(CH2)nOH，(CH2)nNH2，(CH2)nOC(O)C(Me)═CH2，或(CH2)nNHC(O)C(Me)═CH2; SCN; COOH; SO3H; NHCOCH═CH2; NHCOC(CH3)═CH2); OC(O)NHCH2CH2OC(O)C(CH3)═CH2; 或OC(O)NHCH2CH2OC(O)C(CH3)═CH2;下标n是1到约6的整数，下标x是1到约6的整数，下标y、z和m各自独立地为1、2或3，或其混合物，不包括G在内的公式(I)中碳的总数范围从约8到约22，并提供其制备方法。

  公开号：

  US20090287010A1
• 作为产物：
  描述：

  1,1,2,2,5,5,6,6,9,9,10,10-dodecahydroperfluoro-1-iodododecane 在 N-甲基甲酰胺 、 盐酸 作用下， 以 乙醇 、 水 为溶剂， 反应 23.0h， 以98%的产率得到1,1,2,2,5,5,6,6,9,9,10,10-dodecahydroperfluoro-1-dodecanol
  参考文献：
  名称：

  乙烯-四氟乙烯（ETFE）共聚端碘化物及其向表面保护中间体的转化

  摘要：

  通过乙烯和四氟乙烯（TFE）与1 H，1 H，2 H，2 H-全氟烷基碘的共聚反应合成了一类新的含氟调聚物。端粒化导致乙烯-四氟乙烯（ETFE）共聚端碘化物，并以交替的方式在共聚端链中引入乙烯和TFE。通过控制反应参数，例如总压力，温度，单体的进料比，引发剂进料和转化率，可以优选制备八碳共聚端碘化物或更高的共聚端。ETFE共聚端碘化物被转化为多种中间体，例如醇，叠氮化物，胺和硫醇，可用于制造表面改性剂。

  DOI：

  10.1016/j.jfluchem.2014.10.004

文献信息

• FLUOROSILANES
  申请人：Herzog Axel Hans-Joachim

  公开号：US20090143598A1

  公开（公告）日：2009-06-04

  Fluoroalkyl silanes are a class of compounds useful for various industrial purposes. For example, fluoroalkyl silanes which have hydrolysable groups (called hydrolysable fluoroalkyl silanes), are compounds useful as surface treatment agents which provide durable hydrophobic and oleophobic coatings. In general, hydrolysable fluoroalkyl silanes can be represented with the following formula: (RO—) 3 Si—R T wherein R is H or an alkyl; and R T is a monovalent organic compound terminated by a perfluoroalkyl group. When used to coat a surface, the (RO—) 3 moiety reacts (via hydrolysis) with various chemical groups of the surface (e.g., hydroxyl, amine, or other reactive groups) thereby bonding the fluoroalkyl silane to the surface The R T moiety comprises a divalent organic linking group which links the silicon atom to a terminal group rich in fluorine atoms whose unique electronic properties impart desirable hydrophobic and oleophobic properties in a surface coating. Modification of the R T moiety is useful in the engineering of fluoroalkyl silanes. The present invention provides for fluoroalkyl silanes having R T moieties which have not been heretofore considered.

  氟烷基硅烷是一类在各种工业用途中有用的化合物。例如，具有可水解基团（称为可水解氟烷基硅烷）的氟烷基硅烷是作为表面处理剂有用的化合物，可以提供耐久的疏水和疏油涂层。通常，可水解氟烷基硅烷可以用以下公式表示：(RO—)₃Si—RT，其中R为H或烷基；RT是以全氟烷基基团为末端的一价有机化合物。当用于涂覆表面时，(RO—)₃基团通过水解与表面的各种化学基团（如羟基、胺基或其他反应性基团）发生反应，从而将氟烷基硅烷与表面结合。RT基团包括一种双价有机连接基团，将硅原子与富含氟原子的末端基团连接起来，其独特的电子性质赋予涂层中理想的疏水和疏油性能。对RT基团的修改对于工程氟烷基硅烷是有用的。本发明提供了具有未被考虑过的RT基团的氟烷基硅烷。
• FLUOROALKYL SILANES
  申请人：Herzog Axel Hans-Joachim

  公开号：US20120022266A1

  公开（公告）日：2012-01-26

  The present invention is directed to a fluorosilane represented by (L) 3 -Si—(CH 2 ) n —(Z 1 ) a —[C(X 1 )] x —(Z 2 ) l -Q 1 -R f where each n is independently an integer from 1 to 12; L is independently chosen from a hydrolysable or non-hydrolysable monovalent group; R f is chosen from a C 2 -C 12 perfluoroalkyl provided that: i) one fluorine atom of the perfluoroalkyl can be optionally replaced by hydrogen, and/or ii) the perfluoroalkyl can be optionally interrupted by at least one oxygen, methylene, or ethylene; Q 1 is chosen from the group consisting of a C 2 -C 12 hydrocarbylene optionally interrupted by at least one divalent organic group; X 1 is chosen from O or S; —Z 2 is —NH— and Z 1 is from the group consisting of —O—, and —S—; each R 1 is independently chosen from hydrogen, phenyl, or a monovalent C 1 -C 8 alkyl optionally terminated by —C 6 H 5 , preferably H or CH 3 .

  本发明涉及一种氟硅烷，其表示为(L)3-Si—(CH2)n—(Z1)a—[C(X1)]x—(Z2)l-Q1-Rf，其中n独立地为1到12的整数；L独立地选择自可水解或不可水解的一价基团；Rf选择自C2-C12全氟烷基，条件是：i）全氟烷基的一个氟原子可选地被氢取代，和/或ii）全氟烷基可选地被至少一个氧、亚甲基或乙烯间隔；Q1选择自C2-C12烃基烷基，可选地被至少一个二价有机基团中断；X1选择自O或S；—Z2为—NH—，Z1选择自—O—和—S—；每个R1独立地选择自氢、苯基或一价C1-C8烷基，可选地终止于—C6H5，优选H或CH3。
• FLUOROPOLYMER EMULSIONS
  申请人：Brown Gerald Oronde

  公开号：US20090149096A1

  公开（公告）日：2009-06-11

  A fluoropolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a fluoroalkyl monomer, or mixture of monomers, (b) from about 5% to about 80% of at least one of: (i) an alkyl (meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 18 carbons; or (ii) one or more ionizable water solvatable monomers; and (c) from about 0.05% to about 2% non-fluorinated polymerizable nanoparticles.

  一种含有以下重量百分比共聚单体的氟聚合物组合物：（a）约20％至约95％的氟烷基单体或单体混合物，（b）约5％至约80％的至少一种：（i）具有线性，分支或环状烷基的烷基（甲基）丙烯酸酯单体，其烷基含有约6至约18个碳原子；或（ii）一个或多个离子化水溶性单体；以及（c）约0.05％至约2％的非氟化聚合可纳米粒子。
• FLUOROPOLYMER COMPOSITIONS AND TREATED SUBSTRATES
  申请人：Brown Gerald Oronde

  公开号：US20090148654A1

  公开（公告）日：2009-06-11

  A composition comprising a polymer prepared by: reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, having isocyanate groups, and (b) at least one fluorinated compound selected from the formula (I): R f 1 -L-X   (I) wherein R f 1 is a monovalent, partially or fully fluorinated, linear or branched, alkyl radical having 2 to 100 carbon atoms; optionally interrupted by 1 to 50 oxygen atoms; wherein the ratio of carbon atoms to oxygen atoms is at least 2:1 and no oxygen atoms are bonded to each other; L is a bond or a linear or branched divalent linking group having 1 15 to 20 carbon atoms, said linking group optionally interrupted by 1 to 4 hetero-radicals selected from the group consisting or —O—, —NR—, —S—, —SO—, —SO 2 —, —N(R)C(O)— wherein R is H or C 1 -C 6 alkyl, and said linking group optionally substituted with CH 2 Cl; X is an isocyanate-reactive group selected from the group consisting of —OH, —N(R)H, and —SH wherein R is H or C 1 -C 6 alkyl; and thereafter reacting with (c) water and (d) an isocyanate-reactive non-fluorinated particulate component.

  一种组合物，包括由以下方法制备的聚合物：通过反应（a）至少一种具有异氰酸基的二异氰酸酯、多异氰酸酯或其混合物，和（b）选择自式（I）中的至少一种氟化合物：Rf1-L-X  （I）其中，Rf1是具有2到100个碳原子的单价部分或完全氟化的线性或支链烷基基团；可选地由1到50个氧原子中断；其中碳原子与氧原子的比率至少为2:1，且没有氧原子相互键合；L是1，15到20个碳原子的键或线性或支链二价连接基团，该连接基团可选地由1到4个来自所述群的杂原子基团中断，所述群包括—O—、—NR—、—S—、—SO—、—SO2—、—N（R）C（O）—，其中R是H或C1-C6烷基，并且该连接基团可选地用CH2Cl取代；X是选择自—OH、—N（R）H和—SH的异氰酸酯反应性基团，其中R是H或C1-C6烷基；然后与（c）水和（d）异氰酸酯反应性非氟化颗粒组分反应。
• [EN] PARTIALLY FLUORINATED SULFONATED SURFACTANTS<br/>[FR] AGENTS TENSIO-ACTIFS SULFONÉS PARTIELLEMENT FLUORÉS
  申请人：DU PONT

  公开号：WO2010002623A3

  公开（公告）日：2010-06-24