1'-n-dodecyl 2-oxo-propyl ether | 40657-12-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1'-n-dodecyl 2-oxo-propyl ether
• 英文别名: 1-Dodecoxypropan-2-one
• CAS: 40657-12-3
• 化学式: C₁₅H₃₀O₂
• 分子量: 242.402
• InChiKey: QNHASEGVJQQRNQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  17
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  烯丙基十二烷基醚 在 potassium tert-butylate 、 氧气 、 copper(l) chloride 、 palladium dichloride 作用下， 以 水 、 二甲基亚砜 、 N,N-二甲基甲酰胺 为溶剂， 反应 0.33h， 生成 1'-n-dodecyl 2-oxo-propyl ether
  参考文献：
  名称：

  A study of catalysed Wacker reaction for the deprotection of prop-2-enyl and prop-1-enyl ethers

  摘要：

  Pd(II)Cl-2 (1 mole equivalent)/CuCl/DMF-H2O/O-2/2h catalysed oxidation of various prop-2-enyl ethers 1a-12a is reported to result in the formation of Wacker ketones 1b,3b,5b,6b,9b,11b,12b (12-51%), hydrolysis products 2c,4c-7c,9c-12c (12-43%) and eta(2)-vinyl complexes of palladium chloride 2d,4d,7d,8d (52-94%) respectively. The corresponding prop-1-enyl ethers 2e,4e-12e under similar conditions react with a catalytic amount of Pd(II)Cl-2 (0.2 mole equivalent) rapidly (15-20 min.) to give exclusively hydroxy compounds 2c,4c-12c respectively in good yields (75-97%). (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(97)10198-3

文献信息

• Peroxyketals, process for their production, their use in polymerisation reactions, in moulding compositions and mouldings
  申请人：AKZO N.V.

  公开号：EP0000405A1

  公开（公告）日：1979-01-24

  Peroxyketals of the formula wherein R' represents a tert. alkyl group having 4-12 carbon atoms and R2 a branched or a nonbranched alkyl group having 1-12 carbon atoms or a substituted or unsubstituted cycloalkyl group having 5-12 carbon atoms; their preparation from R'OOH and alkoxyacetones; their use in chemical reactions under the influence of free radicals, more particularly in curing unsaturated polyester resin moulding compounds; and the mouldings obtained.

  式中的过氧酮 其中 R' 代表具有 4-12 个碳原子的叔烷基，R2 代表具有 1-12 个碳原子的支链或非支链烷基或具有 5-12 个碳原子的取代或未取代环烷基；从 R'OOH 和烷氧基丙酮中制备它们；它们在自由基影响下的化学反应中的用途，特别是在固化不饱和聚酯树脂模塑化合物中的用途；以及获得的模塑物。
• UV-CURABLE COATING COMPOSITIONS AND METHODS FOR USING THE SAME
  申请人：PPG Coatings (Tianjin) Co. Ltd.

  公开号：EP3041908B1

  公开（公告）日：2018-10-24
• US4287371A
  申请人：——

  公开号：US4287371A

  公开（公告）日：1981-09-01
• US4376842A
  申请人：——

  公开号：US4376842A

  公开（公告）日：1983-03-15
• A study of catalysed Wacker reaction for the deprotection of prop-2-enyl and prop-1-enyl ethers
  作者：Hari Babu Mereyala、Sarita Reddy Lingannagaru

  DOI：10.1016/s0040-4020(97)10198-3

  日期：1997.12

  Pd(II)Cl-2 (1 mole equivalent)/CuCl/DMF-H2O/O-2/2h catalysed oxidation of various prop-2-enyl ethers 1a-12a is reported to result in the formation of Wacker ketones 1b,3b,5b,6b,9b,11b,12b (12-51%), hydrolysis products 2c,4c-7c,9c-12c (12-43%) and eta(2)-vinyl complexes of palladium chloride 2d,4d,7d,8d (52-94%) respectively. The corresponding prop-1-enyl ethers 2e,4e-12e under similar conditions react with a catalytic amount of Pd(II)Cl-2 (0.2 mole equivalent) rapidly (15-20 min.) to give exclusively hydroxy compounds 2c,4c-12c respectively in good yields (75-97%). (C) 1997 Elsevier Science Ltd.