1,1,7,7-Tetraethyl-3,3,5,5-tetramethyl-2,6-dihydro-s-indacene-4,8-dione | 1297413-69-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1,7,7-Tetraethyl-3,3,5,5-tetramethyl-2,6-dihydro-s-indacene-4,8-dione
• 英文别名: 1,1,7,7-tetraethyl-3,3,5,5-tetramethyl-2,6-dihydro-s-indacene-4,8-dione
• CAS: 1297413-69-4
• 化学式: C₂₄H₃₆O₂
• 分子量: 356.549
• InChiKey: JPUYMAKGHSXGCT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-溴-1,1,7,7-四乙基-1,2,3,5,6,7-六氢-3,3,5,5-四甲基对称引达省 在 正丁基锂 、 copper(I) bromide 、 氧气 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 10.0h， 以18%的产率得到1,1,7,7-Tetraethyl-3,3,5,5-tetramethyl-2,6-dihydro-s-indacene-4,8-dione
  参考文献：
  名称：

  Air- and Moisture-Stable p-Monothiobenzoquinones Incorporated in an Octaalkyl-s-hydrindacene Skeleton

  摘要：

  p-Monothiobenzoquinones incorporated in a fused-ring octaalkyl-s-hydrindacene skeleton have been synthesized as air- and moisture-stable reddish orange, crystals by the oxidation of mercaptophenol derivatives with DDQ, which have been characterized by X-ray crystallography to show a planar quinoid framework.

  DOI：

  10.1021/ol200768b

文献信息

• Air- and Moisture-Stable <i>p</i>-Monothiobenzoquinones Incorporated in an Octaalkyl-<i>s</i>-hydrindacene Skeleton
  作者：Makoto Hachiya、Mikinao Ito、Tsukasa Matsuo、Daisuke Hashizume、Hiroyuki Fueno、Kazuyoshi Tanaka、Kohei Tamao

  DOI：10.1021/ol200768b

  日期：2011.5.20

  p-Monothiobenzoquinones incorporated in a fused-ring octaalkyl-s-hydrindacene skeleton have been synthesized as air- and moisture-stable reddish orange, crystals by the oxidation of mercaptophenol derivatives with DDQ, which have been characterized by X-ray crystallography to show a planar quinoid framework.