5-hydroxypentyl vinyl ether | 13188-62-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-hydroxypentyl vinyl ether
• 英文别名: 5-vinyloxypentanol；5-vinyloxy-pentan-1-ol；5-Ethenoxypentan-1-ol
• CAS: 13188-62-0
• 化学式: C₇H₁₄O₂
• 分子量: 130.187
• InChiKey: BCTDCDYHRUIHSF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  9
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  5-hydroxypentyl vinyl ether 、 甲基丙烯酸甲酯 在 甲醇 、 sodium methylate 作用下， 生成 methacrylic acid-(5-vinyloxy-pentyl ester)
  参考文献：
  名称：

  Esters of vinyloxyalkoxy compounds and unsaturated carboxylic acids and polymers thereof

  摘要：

  公开号：

  US02692256A1
• 作为产物：
  描述：

  乙酸乙烯酯 、 1,5-戊二醇 在 硫酸 、 mercury(II) diacetate 作用下， 生成 5-hydroxypentyl vinyl ether
  参考文献：
  名称：

  The Reactions of Vinyl Acetate with Aliphatic Hydroxy Compounds. A New Synthesis of Vinyl Ethers¹

  摘要：

  DOI：

  10.1021/ja01107a037

文献信息

• Direct vinylation of natural alcohols and derivatives with calcium carbide
  作者：Siew Ping Teong、Ariel Yi Hui Chua、Shiyun Deng、Xiukai Li、Yugen Zhang

  DOI：10.1039/c6gc03579e

  日期：——

  A transition metal-free, mild, and safe protocol has been developed for direct vinylation of various sugar alcohols, phenol and its derivatives with calcium carbide.

  已经开发了一种无过渡金属，温和且安全的规程，用于将各种糖醇，苯酚及其衍生物与电石直接乙烯基化。
• NITRILE OXIDE COMPOUND
  申请人：Tokyo Institute Of Technology

  公开号：US20210078944A1

  公开（公告）日：2021-03-18

  The present invention provides a compound represented by formula (I) wherein symbols in the formula are as defined in the specification.

  本发明提供了一种由式（I）表示的化合物，其中式中的符号如规范中定义的那样。
• Polymerizable Fluorine-Containing Compound
  申请人：ISONO Yoshimi

  公开号：US20110098500A1

  公开（公告）日：2011-04-28

  A polymerizable fluorine-containing compound represented by formula (1), wherein R 1 represents a polymerizable double-bond containing group, R 2 represents an acid-labile protecting group, R 3 represents a fluorine atom or fluorine-containing alkyl group, and W represents a bivalent linking group. This compound can provide a fluorine-containing polymer compound that has a weight-average molecular weight of 1,000-1,000,000 and contains a repeating unit represented by formula (2), wherein R 2 , R 3 and W are defined as above, each of R 4 , R 5 and R 6 independently represents a hydrogen atom, fluorine atom or monovalent organic group, at least two of R 4 , R 5 and R 6 may be combined to form a ring. This polymer compound can provide a resist composition capable of forming a pattern that is transparent to exposure light and superior in rectangularity.

  一种可聚合的含氟化合物，其化学式为（1），其中R1表示可聚合的双键含有基团，R2表示酸敏感保护基团，R3表示氟原子或含氟烷基团，W表示二价连接基团。该化合物可以提供一种含氟聚合物化合物，其重均分子量为1,000-1,000,000，并包含由式（2）表示的重复单元，其中R2、R3和W如上所述，R4、R5和R6中的每一个独立地表示氢原子、氟原子或一价有机基团，至少两个R4、R5和R6可以结合形成一个环。该聚合物化合物可以提供一种抗蚀剂组合物，能够形成透明的曝光光线图案，并具有优异的矩形度。
• Fluorine-Containing Compound, Fluorine-Containing Polymer, Negative-Type Resist Composition, and Patterning Process Using Same
  申请人：ISONO Yoshimi

  公开号：US20120226070A1

  公开（公告）日：2012-09-06

  A fluorine-containing unsaturated carboxylic acid represented by formula (1), wherein R 1 represents a polymerizable double-bond containing group, R 3 represents a fluorine atom or fluorine-containing alkyl group, and W represents a bivalent linking group. This compound can provide a fluorine-containing polymer compound that has a weight-average molecular weight of 1,000-1,000,000 and contains a repeating unit represented by formula (2), wherein R 3 and W are defined as above, each of R 4 , R 5 and R 6 independently represents a hydrogen atom, fluorine atom or monovalent organic group, at least two of R 4 , R 5 and R 6 may be combined to form a ring. This polymer compound can provide a chemically amplified resist composition that is transparent to KrF or ArF excimer laser light and has a high resolution and is capable of forming a pattern having a rectangular section with no swelling.

  化学式（1）所表示的含氟不饱和羧酸，其中R1代表可聚合的双键含基团，R3代表氟原子或含氟烷基团，W代表二价连接基团。该化合物可提供一种分子量为1,000-1,000,000且含有化学式（2）所表示的重复单元的含氟聚合物化合物，其中R3和W如上所定义，R4、R5和R6中的每一个独立地代表氢原子、氟原子或一价有机基团，R4、R5和R6中至少有两个可以结合形成环。该聚合物化合物可提供一种化学增强型光刻胶组合物，该组合物对KrF或ArF准分子激光光线透明，具有高分辨率，并能够形成具有矩形截面且无膨胀的图案。
• Fluorine-containing polymerizable monomers and polymers, anti-reflection film materials and resist compositions using same
  申请人：Central Glass Company, Limited

  公开号：US20030232940A1

  公开（公告）日：2003-12-18

  The present invention relates to a fluorine-containing polymerizable monomer having a structure of the general formula (1), 1 where each of R 1 and R 2 is independently a methyl group or trifluoromethyl group, and each of R 3 and R 4 is independently a hydrogen atom, an alkyl group, a fluorinated alkyl group, a ring structure having an aromatic ring, or an acid-labile protecting group, each of the alkyl group and the fluorinated alkyl group independently having a straight-chain, branched or ring form and having a carbon atom number of 1-25, each of R 3 and R 4 optionally and independently containing at least one of an oxygen atom and a carbonyl bond.

  本发明涉及一种含氟可聚合单体，其结构为通式（1），其中R1和R2各自独立地为甲基基团或三氟甲基基团，R3和R4各自独立地为氢原子、烷基、氟代烷基、含有芳香环的环结构或酸敏保护基，烷基和氟代烷基各自具有直链、支链或环形，并具有1-25个碳原子，R3和R4任意且独立地含有至少一个氧原子和一个羰基键。