hexa-O-allyl-D-mannitol | 82008-47-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: hexa-O-allyl-D-mannitol
• 英文别名: Hexa-O-allyl-D-mannit；mannitol hexaallyl ether；(2R,3R,4R,5R)-1,2,3,4,5,6-hexakis(prop-2-enoxy)hexane
• CAS: 82008-47-7
• 化学式: C₂₄H₃₈O₆
• 分子量: 422.562
• InChiKey: RZFOEAPJPZMXTQ-MOUTVQLLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  30
• 可旋转键数：
  23
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  55.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  hexa-O-allyl-D-mannitol 、 alkaline earth salt of/the/ methylsulfuric acid 生成 丙烯醛
  参考文献：
  名称：

  Net loss: A cost-benefit analysis of the Canadian Pacific salmon fishery

  摘要：

  DOI：

  10.1002/(sici)1520-6688(200024)19:1<23::aid-pam3>3.0.co;2-c
• 作为产物：
  描述：

  甘露醇 、 3-溴丙烯 在 sodium hydroxide 作用下， 生成 hexa-O-allyl-D-mannitol
  参考文献：
  名称：

  Net loss: A cost-benefit analysis of the Canadian Pacific salmon fishery

  摘要：

  DOI：

  10.1002/(sici)1520-6688(200024)19:1<23::aid-pam3>3.0.co;2-c

文献信息

• Process for the preparation of di- and poly-allyl ethers
  申请人：Ciba-Geigy Corporation

  公开号：US04433179A1

  公开（公告）日：1984-02-21

  A process for the preparation of allyl ethers of the formula R--O--CH.sub.2 --CH.dbd.CH.sub.2).sub.n in which R and n are as defined in claim 1, by reacting hydroxy compounds of the formula R--OH).sub.n with allyl chloride or allyl bromide by phase transfer catalysis, 0.8 to 5 mols of allyl chloride or allyl bromide, 1 to 6 mols of aqueous or solid sodium hydroxide and, as the phase transfer catalyst, 2 to 20 mol % of a quaternary ammonium salt, a quaternary ammonium base or a crown ether being employed per hydroxyl equivalent of the compound of the formula II, and the reaction being carried out in the temperature range from 20.degree. to 100.degree. C.

  一种制备化学式为R--O--CH.sub.2 --CH.dbd.CH.sub.2).sub.n的烯丙基醚的方法，其中R和n如权利要求1所定义，通过相转移催化，将化学式为R--OH).sub.n的羟基化合物与烯丙基氯或烯丙基溴反应，使用0.8至5摩尔的烯丙基氯或烯丙基溴，1至6摩尔的水合或固体氢氧化钠，作为相转移催化剂，每个化合物II的羟基当量使用2至20摩尔%的季铵盐、季铵碱或冠醚，并在20°C至100°C的温度范围内进行反应。
• Polymerizable Dental Material Comprising Reactive Paste Formers, Hardened Dental Material and Use Thereof
  申请人：Bublewitz Alexander

  公开号：US20130225699A1

  公开（公告）日：2013-08-29

  A polymerizable dental material with reactive paste-forming agent, hardened dental material and the use thereof. A polymerizable dental material containing at least one paste-like component A and at least one paste-like component B is described, whereby component A contains at least one initiator of the radical polymerization c) selected from the group of barbituric acid derivatives and/or of malonyl sulfamides, and whereby component B contains an organic compound d) comprising at least one acrylic acid ester and/or methacrylic acid ester, at least one metal compound e) and at least one halide and/or pseudo halide compound f). The polymerizable dental material is characterized in that component A as reactive paste-forming agent contains at least one organic compound a) derived from maleic acid and/or fumaric acid and/or itaconic acid, and/or at least one compound comprising at least one allyl and/or methallyl residue b). The polymerizable dental material can be stored easily and it quickly hardens after components A and B are mixed under mouth conditions, and forms hardened masses having excellent mechanical properties. In particular, these can be used in crowns and bridge materials or as dental cement.
• US9114079B2
  申请人：——

  公开号：US9114079B2

  公开（公告）日：2015-08-25
• Net loss: A cost-benefit analysis of the Canadian Pacific salmon fishery
  作者：Richard Schwindt、Aidan Vining、Steven Globerman

  DOI：10.1002/(sici)1520-6688(200024)19:1<23::aid-pam3>3.0.co;2-c

  日期：——