2,4-dichloro-6-(2,4-dichloro-phenoxy)-[1,3,5]triazine | 18247-77-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,4-dichloro-6-(2,4-dichloro-phenoxy)-[1,3,5]triazine
• 英文别名: dichloro-(2,4-dichloro-phenoxy)-[1,3,5]triazine；Dichlor-(2,4-dichlor-phenoxy)-[1,3,5]triazin；4,6-Dichlor-2-(2,4-dichlor-phenoxy)-1,3,5-triazin；2,4-Dichloro-6-(2,4-dichlorophenoxy)-1,3,5-triazine
• CAS: 18247-77-3
• 化学式: C₉H₃Cl₄N₃O
• mdl: MFCD00117398
• 分子量: 310.954
• InChiKey: WQXUKGWCDJPEPX-UHFFFAOYSA-N

物化性质

• 熔点：
  122-123 °C(Solv: hexane (110-54-3))
• 沸点：
  480.4±55.0 °C(Predicted)
• 密度：
  1.658±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  47.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,4-dichloro-6-(2,4-dichloro-phenoxy)-[1,3,5]triazine 在 三乙胺 、 三氟乙酸 、 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 17.17h， 生成 4,4-difluoro-8-(4-(4-chloro-6-(2,4-dichlorophenoxy)-1,3,5-triazin-2-yloxy)phenyl)-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indancene
  参考文献：
  名称：

  Synthesis and photophysical properties of tripod BODIPY dyes bearing mono-phenolic derivatives

  摘要：

  A series of new tripod boron dipyrromethene (BODIPY) dyes bearing mono-phenolic derivatives were synthesized and characterized. An optimized reaction condition for the synthesis of the bis-substituted intermediates was obtained. An unanticipated phenol-dependent effect on the yields was found and a hypothetic mechanism was proposed to elucidate the reactivity of the tripod dipyrromethene species during the complexation step. The new dyes showed typical photophysical properties of the BODIPY fluorophore. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2014.12.072
• 作为产物：
  描述：

  三聚氯氰 、 2,4-二氯酚 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 生成 2,4-dichloro-6-(2,4-dichloro-phenoxy)-[1,3,5]triazine
  参考文献：
  名称：

  Synthesis and photophysical properties of tripod BODIPY dyes bearing mono-phenolic derivatives

  摘要：

  A series of new tripod boron dipyrromethene (BODIPY) dyes bearing mono-phenolic derivatives were synthesized and characterized. An optimized reaction condition for the synthesis of the bis-substituted intermediates was obtained. An unanticipated phenol-dependent effect on the yields was found and a hypothetic mechanism was proposed to elucidate the reactivity of the tripod dipyrromethene species during the complexation step. The new dyes showed typical photophysical properties of the BODIPY fluorophore. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2014.12.072

文献信息

• Verfahren zur Herstellung von 4,6-Dihalogen-1,3,5-triazinen
  申请人：BAYER AG

  公开号：EP0002493B1

  公开（公告）日：1980-07-23
• UTILISATION DE COMPOSES HETEROCYCLIQUES CONTENANT DE L'AZOTE POUR REDUIRE LA PERTE D'HUMIDITE DES PLANTES ET AUGMENTER LE RENDEMENT DES RECOLTES
  申请人：RHONE POULENC NEDERLAND B.V.

  公开号：EP0258391A1

  公开（公告）日：1988-03-09
• US4220765A
  申请人：——

  公开号：US4220765A

  公开（公告）日：1980-09-02
• [EN] USE OF HETEROCYCLIC NITROGEN-CONTAINING COMPOUNDS FOR REDUCING MOISTURE LOSS FROM PLANTS AND INCREASING CROP YIELD
  申请人：RHONE-POULENC NEDERLANDS B.V.

  公开号：WO1987004321A2

  公开（公告）日：1987-07-30

  (EN) A method for reducing transpirational moisture loss from plants and increasing crop yield by applying to the plant surface or crop an effective amount of a heterocyclic nitrogen-containing compound. This invention also relates to novel heterocyclic nitrogen-containing compounds and processes for the preparation thereof.(FR) Procédé permettant de réduire les pertes d'humidité par la transpiration chez les plantes et d'augmenter le rendement des récoltes en appliquant sur la surface des plantes ou sur les récoltes une quantité efficace d'un composé hétérocyclique contenant de l'azote. Cette invention concerne également de nouveaux composés hétérocycliques contenant de l'azote ainsi que des procédés pour leur préparation.
• Synthesis and photophysical properties of tripod BODIPY dyes bearing mono-phenolic derivatives
  作者：Jiahui Lu、Xin Qi、Tao Yue、Weiran Tang、Liping Ding

  DOI：10.1016/j.tet.2014.12.072

  日期：2015.2

  A series of new tripod boron dipyrromethene (BODIPY) dyes bearing mono-phenolic derivatives were synthesized and characterized. An optimized reaction condition for the synthesis of the bis-substituted intermediates was obtained. An unanticipated phenol-dependent effect on the yields was found and a hypothetic mechanism was proposed to elucidate the reactivity of the tripod dipyrromethene species during the complexation step. The new dyes showed typical photophysical properties of the BODIPY fluorophore. (C) 2014 Elsevier Ltd. All rights reserved.