ethyl 9,10-dihydro-9-(tricyclo[3.3.1.1^3,7]decylidene)-10-acridineacetate | 178312-98-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: ethyl 9,10-dihydro-9-(tricyclo[3.3.1.1^3,7]decylidene)-10-acridineacetate
• 英文别名: Ethyl 2-[9-(2-adamantylidene)acridin-10-yl]acetate
• CAS: 178312-98-6
• 化学式: C₂₇H₂₉NO₂
• 分子量: 399.533
• InChiKey: DUDNLDOOKKORJX-UHFFFAOYSA-N

物化性质

• 沸点：
  545.3±39.0 °C(Predicted)
• 密度：
  1?+-.0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  30
• 可旋转键数：
  4
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  ethyl 9,10-dihydro-9-(tricyclo[3.3.1.1^3,7]decylidene)-10-acridineacetate 在 4-二甲氨基吡啶 、 sodium hydroxide 、 N,N'-二环己基碳二亚胺 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 生成 (4-methoxyphenyl) 2-[9-(2-adamantylidene)acridin-10-yl]acetate
  参考文献：
  名称：

  含有a啶-10-乙酸酯部分作为发光体和触发单元的新型1,2-二氧杂环丁烷的合成和化学发光性质

  摘要：

  制备具有a啶-10-乙酸酯部分的新型二氧杂环丁烷衍生物2并测试其潜在的化学发光探针。发现10-乙酸酯在稳定和在二氧杂环丁烷环的碱介导的平滑降解中均起重要作用。

  DOI：

  10.1016/s0040-4039(96)02463-x
• 作为产物：
  描述：

  吖啶酮 在 四氯化钛 、 sodium hydride 、 锌 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 29.0h， 生成 ethyl 9,10-dihydro-9-(tricyclo[3.3.1.1^3,7]decylidene)-10-acridineacetate
  参考文献：
  名称：

  A rapid screening method for thermal conductivity properties of thermal insulation materials by a thermochemiluminescence probe

  摘要：

  一种用于温度感应的热化学发光（TCL）探针可以应用于筛选不同隔热材料的导热性能。

  DOI：

  10.1039/d0cc04654j

文献信息

• Oxiranes having an acridane structure as a novel chemiluminescent precursor: synthesis and chemiluminescent studies
  作者：Kazuyuki Miyashita、Masatoshi Minagawa、Yohko Ueda、Yukie Tada、Nobuhiro Hoshino、Takeshi Imanishi

  DOI：10.1016/s0040-4020(01)00216-2

  日期：2001.4

  Oxirane derivatives having acridane and adamantane structures were designed as a novel chemiluminescent precursor and were found to have a characteristic chemiluminescent ability which is introduced by a two-step trigger reaction involving treatment with alkaline H2O2 and subsequent acidic treatment. Structural study of the oxirane derivatives showed that the CIEEL mechanism is involved in this chemiluminescent reaction and it was also found that the chemiluminescent profile is affected by the kind of acid employed in the trigger reaction. (C) 2001 Elsevier Science Ltd. All rights reserved.
• 9-Adamantylidene-10-alkyl-9,10-dihydroacridine oxide as a novel and potential chemiluminescent precursor: Proximity effect of the nitrogen atom
  作者：Takeshi Imanishi、Yohko Ueda、Masatoshi Minagawa、Nobuhiro Hoshino、Kazuyuki Miyashita

  DOI：10.1016/s0040-4039(97)00791-0

  日期：1997.6

  An oxirane derivative having acridane and adamantane moieties was prepared and proved to show potential chemiluminescent property on treatment with alkaline hydroperoxide and subsequently with hydrochloric acid, in which the electron-donating property of the nitrogen was experimentally shown to play an important role for the chemiluminescence. (C) 1997 Elsevier Science Ltd.
• Synthesis and chemiluminescent property of the novel 1,2-dioxetanes containing an acridane-10-acetate moiety as the luminophore and trigger unit
  作者：Takeshi Imanishi、Yohko Ueda、Ryoh Tainaka、Kazuyuki Miyashita、Nobuhiro Hoshino

  DOI：10.1016/s0040-4039(96)02463-x

  日期：1997.2

  Novel dioxetane derivatives 2 with an acridane-10-acetate moiety were prepared and tested for a potential chemiluminescent probe. The 10-acetate was found to play an important role both in stabilization and in base-mediated smooth degradation of the dioxetane ring.

  制备具有a啶-10-乙酸酯部分的新型二氧杂环丁烷衍生物2并测试其潜在的化学发光探针。发现10-乙酸酯在稳定和在二氧杂环丁烷环的碱介导的平滑降解中均起重要作用。
• A rapid screening method for thermal conductivity properties of thermal insulation materials by a thermochemiluminescence probe
  作者：Xu Teng、Mingzhe Jin、Caifeng Ding、Chao Lu

  DOI：10.1039/d0cc04654j

  日期：——

  A thermochemiluminescence (TCL) probe for temperature sensing could be applied to screen thermal conductivity properties of different thermal insulation materials.

  一种用于温度感应的热化学发光（TCL）探针可以应用于筛选不同隔热材料的导热性能。