5-(vinyloxy)pent-1-ene | 344329-17-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-(vinyloxy)pent-1-ene
• 英文别名: 5-Ethenoxypent-1-ene
• CAS: 344329-17-5
• 化学式: C₇H₁₂O
• 分子量: 112.172
• InChiKey: VFOONMUUZUQJEU-UHFFFAOYSA-N

物化性质

• 熔点：
  138-139 °C
• 沸点：
  118.7±19.0 °C(Predicted)
• 密度：
  0.797±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  8
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5-(vinyloxy)pent-1-ene 在 Grubbs catalyst first generation 叔丁基锂 作用下， 以 四氢呋喃 、 甲苯 、 正戊烷 为溶剂， 反应 13.5h， 生成 benzyl 2-[(E)-8-(1-[(benzyloxy)carbonyl]-vinyloxy)-4-octenyl]oxyacrylate
  参考文献：
  名称：

  Ring-closing metathesis of α-ester-substituted enol ethers: application to the shortest synthesis of KDO

  摘要：

  Ring-closing metathesis reactions of alpha-ester-substituted enol ethers are described. In the case of unsubstituted terminal olefins, isomerization prior to cyclization was observed as an undesired side reaction, which could not be completely inhibited. Furthermore, this methodology was applied to a formal synthesis of KDO, which now represents the shortest synthetic pathway to KDO and its deoxy analogue. Interestingly, in this route olefin isomerization was not observed, presumably due to the increased steric environment of the double bond. Finally, an efficient two-step conversion to transform an alcohol into an alpha-alkoxy acrylate is also described. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(03)00819-6
• 作为产物：
  描述：

  4-戊烯-1-醇 、 乙烯基乙醚 在 4,7-二苯基-1,10-菲罗啉 、 palladium diacetate 作用下， 以 二氯甲烷 为溶剂， 反应 96.0h， 以46%的产率得到5-(vinyloxy)pent-1-ene
  参考文献：
  名称：

  单步开环易位嵌段共聚物及其新型阻滞技术的组成分析。

  摘要：

  对嵌段共聚物使用一步合成路线可避免将单体重复添加到聚合混合物中，这很容易导致污染，并因此导致链增长的不必要终止。为此，探索了具有不同空间位阻和不同传播速率的单体（M1 - M5）。的共聚M1（快速传播）与M2（传播慢），M1与M3（传播非常慢）和M4与（快速传播）M5（缓慢地传播），得到二嵌段状使用的Grubbs第一（共聚物G1）或第三代催化剂（G3）。单体消耗之后进行1 H NMR光谱分析，结果表明M1和M2的反应率大不相同。在M1和M3的情况下，我们观察到有史以来针对共聚方法报道的反应率之差最高（r 1 = 324和r 2 = 0.003）。通过使用G3合成三嵌段共聚物，方法是先消耗掉M1和M2的混合物，然后再添加M1。另外，为了测量G3的快速反应速率M1催化剂，我们报告了一种基于不寻常的可逆G3费-卡宾向G3亚苄基/亚烷基转化的新型阻滞技术。

  DOI：

  10.1002/anie.202005366

文献信息

• ORGANIC SILANE COMPOUND FOR FORMING SI-CONTAINING FILM BY PLASMA CVD AND METHOD FOR FORMING SI-CONTAINING FILM
  申请人：Hamada Yoshitaka

  公开号：US20100137626A1

  公开（公告）日：2010-06-03

  An organic silane compound for forming a Si-containing film by plasma CVD is provided. The silane compound contains 2 or more silicon atoms bonded by an intervening straight chain or branched oxygen-containing hydrocarbon chain having 4 to 8 carbon atoms containing a bond represented by C p —O—C q wherein p and q independently represent number of carbon atoms with the proviso that 2≦p≦6 and 2≦q≦6 and the carbon chains do not contain an unsaturated bond which conjugates with the oxygen atom, wherein all of the 2 or more silicon atoms has 1 or more hydrogen atom or an alkoxy group having 1 to 4 carbon atoms.

  提供了一种有机硅烷化合物，用于通过等离子体CVD形成含硅膜。该硅烷化合物包含2个或更多硅原子，由介于直链或分支氧含量碳氢链之间的键合而成，其中含有一个由Cp-O-Cq表示的键，其中p和q独立地表示碳原子数，但须满足2≦p≦6和2≦q≦6，且碳链不含有与氧原子共轭的不饱和键，其中所有的2个或更多硅原子具有1个或更多氢原子或具有1到4个碳原子的烷氧基团。
• [EN] REDUCTION OF ALDEHYDES AND KETONES TO ALCOHOLS<br/>[FR] RÉDUCTION D'ALDÉHYDES ET DE CÉTONES EN ALCOOLS
  申请人：AMERICAN PACIFIC CORP

  公开号：WO2011060302A1

  公开（公告）日：2011-05-19

  The embodiments described herein provide a reduction of an aldehyde or a ketone, such as a Meerwein-Ponnorf-Verley (MPV) reaction of an aldehyde or ketone. In some embodiments, the reaction occurs in the presence of A1[OC(CH3)3]. In some embodiments, the reaction occurs in the presence of an aprotic solvent. In some embodiments, the aldehyde or ketone is an amino aldehyde or an amino ketone wherein the amine is group is protected such that the nitrogen of the amine has no proton. Other embodiments related to compositions and compounds related to the reduction reaction, or to the preparation or use of the aldehyde, the ketone, or the resulting alcohol.

  本文所述实施例提供了醛或酮的还原，例如醛或酮的Meerwein-Ponnorf-Verley(MPV)反应。在某些实施例中，反应发生在A1 [OC(CH3)3]的存在下。在某些实施例中，反应发生在无极溶剂的存在下。在某些实施例中，醛或酮是氨基醛或氨基酮，其中氨基团被保护，使得氨基的氮没有质子。其他实施例涉及与还原反应相关的组合物和化合物，或与醛、酮或所得醇的制备或使用相关的实施例。
• Synthesis of substituted aromatic compounds by Diels–Alder reactions of alkoxycyclobutenes produced via photocycloadditions between vinyl ethers and 1,3-dione enol esters
  作者：Andrew J. Barker、Michael J. Begley、Alan M. Birch、Gerald Pattenden

  DOI：10.1039/p19830001919

  日期：——

  The adduct (5) obtained from [2 + 2] photocycloaddition of ethyl vinyl ether to the 1,3-dione enol acetate (4) rapidly loses acetic acid producing the ethoxycyclobutene (7). On being warmed in the presence of a dienophile, the ethoxycyclobutene (7) undergoes electrocyclic ring-opening to give the ethoxydienone (8) followed by [4 + 2] cycloaddition to produce Diels–Alder adducts [e.g.(10) with dimethyl

  从乙基乙烯基醚的[2 + 2]光环加成到1,3-二酮烯醇乙酸酯（4）中获得的加合物（5）迅速失去乙酸，生成乙氧基环丁烯（7）。在亲二烯体存在下加热后，乙氧基环丁烯（7）经历电环开环反应生成乙氧基二烯酮（8），然后进行[4 + 2]环加成反应生成狄尔斯-阿尔德加合物[例如（10）与乙酰化二羧酸二甲酯] ; 从（10）中除去乙醇，得到邻苯二甲酸二甲酯（11）。在“一锅法”反应中，将（5）与1,4-萘醌在含二甲苯的氧化铝中的溶液加热可得到取代的蒽醌（12），产率为95％。
• MONOMERS AND POLYMERS CARRYING IMIDAZOLE AND BENZIMIDAZOLE GROUPINGS, AND PROTON EXCHANGE MEMBRANE CONTAINING THE SAME FOR THE PRODUCTION OF A FUEL CELL
  申请人：Glipa Xavier

  公开号：US20100151351A1

  公开（公告）日：2010-06-17

  The invention relates to a monomer ( 6, 14 ) carrying an imidazole-type heterocycle ( 3 ). According to the invention, the chemical structure of said monomer ( 6, 14 ) comprises at least one unit of formula (I) wherein R1 comprises an alkenyl grouping and R2 comprises a grouping for protecting one of the nitrogen atoms of the heterocycle. The invention also relates to a monomer carrying a benzimidazole-type heterocycle, and to protected polymers obtained from said monomers, deprotected polymers produced by the protected polymers, a proton exchange membrane based on deprotected polymers, and a fuel cell provided with said membrane. Furthermore, the invention relates to methods for producing the above-mentioned monomers and polymers.

  本发明涉及一种携带咪唑类杂环（3）的单体（6,14）。根据本发明，所述单体（6,14）的化学结构至少包括一个式（I）的单元，其中R1包括烯基基团，而R2包括用于保护杂环中的氮原子之一的基团。本发明还涉及一种携带苯并咪唑类杂环的单体，以及由所述单体获得的受保护聚合物，由受保护聚合物产生的去保护聚合物，基于去保护聚合物的质子交换膜，以及配备该膜的燃料电池。此外，本发明还涉及上述单体和聚合物的制备方法。
• Synthesis of Allyl and Alkyl Vinyl Ethers Using an in Situ Prepared Air-Stable Palladium Catalyst. Efficient Transfer Vinylation of Primary, Secondary, and Tertiary Alcohols
  作者：Martin Bosch、Marcel Schlaf

  DOI：10.1021/jo034376h

  日期：2003.6.1

  An air-stable palladium catalyst formed in situ from commercially available components efficiently catalyzed the transfer vinylation between butyl vinyl ether and various allyl and alkyl alcohols to give the corresponding allyl and alkyl vinyl ethers in 61-98% yield in a single step.