O-crotylhydroxylamine hydrochloride | 54149-66-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: O-crotylhydroxylamine hydrochloride
• 英文别名: O-but-2-enyl-hydroxylamine; hydrochloride；but-2-enyloxy-amine; hydrochloride；2-Butenyloxyamine hydrochloride；O-but-2-enylhydroxylamine;hydrochloride
• CAS: 54149-66-5
• 化学式: C₄H₉NO*ClH
• 分子量: 123.582
• InChiKey: OPJFWQSEOAELRV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.87
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  35.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  O-crotylhydroxylamine hydrochloride 、 苯丙炔酸 在 4-二甲氨基吡啶 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以53%的产率得到N-(2-buten-1-yloxy)-3-phenylpropynamide
  参考文献：
  名称：

  金催化O-烯丙基异羟肟酸酯的顺序环化/重排反应：3-羟基异恶唑的原子经济合成

  摘要：

  已经开发了具有炔基部分的O-烯丙基异羟肟酸酯的金催化的顺序反应，用于制备3-羟基异恶唑和异恶唑-3-酮。值得注意的是，该涉及环化和重排的多米诺反应提供了以高度原子经济的方式容易地获得所需化合物的方法。

  DOI：

  10.1016/j.tetlet.2016.03.032
• 作为产物：
  描述：

  O-ethyl benzoylhydroxamic acid 在 盐酸 作用下， 以 乙醇 为溶剂， 以26%的产率得到O-crotylhydroxylamine hydrochloride
  参考文献：
  名称：

  Singha, A. S.; Misra, B. N., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1982, vol. 21, # 4, p. 361 - 363

  摘要：

  DOI：

文献信息

• Certain aromatic or heterocyclic mercapto-alkylene-cyclohexene dione
  申请人：Sumitomo Chemical Company, Limited

  公开号：US04981971A1

  公开（公告）日：1991-01-01

  A novel cyclohexane compound represented by the general formula (I), ##STR1## wherein R.sup.1 represents a hydrogen atom or a (C.sub.1 -C.sub.6)alkyl or (C.sub.1 -C.sub.4)alkoxymethyl group, R.sup.2 represents a (C.sub.1 -C.sub.12)-alkyl, (C.sub.3 -C.sub.6)alkenyl, (C.sub.3 -C.sub.6)alkynyl, (C.sub.3 -C.sub.6)cycloalkylmethyl, halo(C.sub.3 -C.sub.6)alkenyl, cyano(C.sub.1 -C.sub.4)alkyl, (C.sub.1 -C.sub.4)alkoxymethyl, (C.sub.1 -C.sub.4)alkylthiomethyl or benzyl group, R.sup.3 represents a hydrogen atom or a methyl group, R.sup.4 represents a hydrogen atom or a methyl group, R.sup.5 is a hydrogen atom or a methyl group, and when R.sup.5 is a hydrogen atom, R.sup.6 is a hydrogen atom or a (C.sub.1 -C.sub.4)-alkoxycarbonyl group, and when R.sup.5 is a methyl group, R.sup.6 is a hydrogen atom, X represents a group represented by the formula CH or a nitrogen atom, Y represents a hydrogen or halogen atom, Z represents a trifluoromethyl, trifluoromethoxy or 1,1,2,2-tetrafluoroethoxy group and n is an integer of 0, 1 or 2 and its meal salt, ammonium salt and organic ammonium salt, its production and herbicides containing it as an active ingredient.

  一种新的环己烷化合物，其通式表示为(I)：##STR1## 其中，R.sup.1代表氢原子或(C.sub.1-C.sub.6)烷基或(C.sub.1-C.sub.4)烷氧甲基基团，R.sup.2代表(C.sub.1-C.sub.12)烷基，(C.sub.3-C.sub.6)烯基，(C.sub.3-C.sub.6)炔基，(C.sub.3-C.sub.6)环烷甲基，卤代(C.sub.3-C.sub.6)烯基，氰基(C.sub.1-C.sub.4)烷基，(C.sub.1-C.sub.4)烷氧甲基，(C.sub.1-C.sub.4)烷硫甲基或苄基；R.sup.3代表氢原子或甲基基团，R.sup.4代表氢原子或甲基基团，R.sup.5是氢原子或甲基基团，当R.sup.5是氢原子时，R.sup.6是氢原子或(C.sub.1-C.sub.4)烷氧羰基基团，当R.sup.5为甲基基团时，R.sup.6为氢原子，X代表由公式CH或氮原子表示的基团，Y代表氢原子或卤素原子，Z代表三氟甲基，三氟甲氧基或1,1,2,2-四氟乙氧基基团，n为0、1或2的整数，以及其金属盐、铵盐和有机铵盐、其制备方法和含有其作为活性成分的除草剂。
• Cyclohexane herbicides
  申请人：Sumitomo Chemical Company, Limited

  公开号：US05021579A1

  公开（公告）日：1991-06-04

  A novel cyclohexane compound represented by the general formula (I), ##STR1## wherein R.sup.1 represents a hydrogen atom or a (C.sub.1 -C.sub.6)alkyl or (C.sub.1 -C.sub.4)alkoxymethyl group, R.sup.2 represents a (C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.6)alkenyl, (C.sub.3 -C.sub.6)alkynyl, (C.sub.3 -C.sub.6)cycloalkylmethyl, halo(C.sub.3 -C.sub.6)alkenyl, cyano(C.sub.1 -C.sub.4)alkyl, (C.sub.1 -C.sub.4)alkoxymethyl, (C.sub.1 -C.sub.4)alkylthiomethyl or benzyl group, R.sup.3 represents a hydrogen atom or a methyl group, R.sup.4 represents a hydrogen atom or a methyl group, R.sup.5 is a hydrogen atom or a methyl group, and when R.sup.5 is a hydrogen atom, R.sup.6 is a hydrogen atom or a (C.sub.1 -C.sub.4)alkoxycarbonyl group, and when R.sup.5 is a methyl group, R.sup.6 is a hydrogen atom, X represents a group represented by the formula CH or a nitrogen atom, Y represents a hydrogen or halogen atom, Z represents a trifluoromethyl, trifluoromethoxy or 1,1,2,2-tetrafluoroethoxy group and n is an integer of 0, 1 or 2 and its metal salt, ammonium salt and organic ammonium salt, its production and herbicides containing it as an active ingredient.

  一种新的环己烷化合物，其通式为（I），其中R1代表氢原子或（C1-C6）烷基或（C1-C4）烷氧甲基基团，R2代表（C1-C12）烷基，（C3-C6）烯基，（C3-C6）炔基，（C3-C6）环烷基甲基，卤代（C3-C6）烯基，氰基（C1-C4）烷基，（C1-C4）烷氧甲基，（C1-C4）烷硫甲基或苄基，R3代表氢原子或甲基基团，R4代表氢原子或甲基基团，R5是氢原子或甲基基团，当R5是氢原子时，R6是氢原子或（C1-C4）烷氧羰基基团，当R5是甲基基团时，R6是氢原子，X代表公式CH或氮原子表示的基团，Y代表氢原子或卤原子，Z代表三氟甲基，三氟甲氧基或1,1,2,2-四氟乙氧基基团，n是0，1或2的整数，以及其金属盐，铵盐和有机铵盐，其制备方法和含有其作为活性成分的除草剂。
• Certain pyridyl thio or phenyl thio-E thane-1,3-cyclohexane
  申请人：Sumitomo Chemical Company, Limited

  公开号：US04789396A1

  公开（公告）日：1988-12-06

  A novel cyclohexane compound represented by the general formula (I), ##STR1## wherein R.sup.1 represents a hydrogen atom or a (C.sub.1 -C.sub.6)alkyl or (C.sub.1 -C.sub.4)alkoxymethyl group, R.sup.2 represents a (C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.6)alkenyl, (C.sub.3 -C.sub.6)alkynyl, (C.sub.3 -C.sub.6)cycloalkylmethyl, halo(C.sub.3 -C.sub.6)alkenyl, cyano(C.sub.1 -C.sub.4)alkyl, (C.sub.1 -C.sub.4)alkoxymethyl, (C.sub.1 -C.sub.4)alkylthiomethyl or benzyl group, R.sup.3 represents a hydrogen atom or a methyl group, R.sup.4 represents a hydrogen atom or a methyl group, R.sup.5 is a hydrogen atom or a methyl group, and when R.sup.5 is a hydrogen atom, R.sup.6 is a hydrogen atom or a (C.sub.1 -C.sub.4)alkoxycarbonyl group,, and when R.sup.5 is a methyl group, R.sup.6 is a hydrogen atom, X represents a group represented by a formula CH or a nitrogen atom, Y represents a hydrogen or halogen atom, Z represents a trifluoromethyl, trifluoromethoxy or 1,1,2,2-tetrafluoroethoxy group and n is an integer of 0, 1 or 2 and its metal salt, ammonium salt and organic ammonium salt, its production and herbicides containing it as an active ingredient.

  一种新的环己烷化合物，其一般式表示为（I），其中R1表示氢原子或（C1-C6）烷基或（C1-C4）烷氧甲基基团，R2表示（C1-C12）烷基，（C3-C6）烯基，（C3-C6）炔基，（C3-C6）环烷基甲基，卤代（C3-C6）烯基，氰基（C1-C4）烷基，（C1-C4）烷氧甲基，（C1-C4）烷基硫甲基或苄基，R3表示氢原子或甲基基团，R4表示氢原子或甲基基团，R5是氢原子或甲基基团，当R5是氢原子时，R6是氢原子或（C1-C4）烷氧羰基基团，当R5是甲基基团时，R6是氢原子，X表示由公式CH或氮原子表示的基团，Y表示氢或卤素原子，Z表示三氟甲基，三氟甲氧基或1,1,2,2-四氟乙氧基基团，n是0,1或2的整数，以及其金属盐，铵盐和有机铵盐，其生产和含有其作为活性成分的除草剂。
• Koyama, Junko; Sugita, Teruyo; Suzuta, Yukio, Chemical and pharmaceutical bulletin, 1983, vol. 31, # 8, p. 2601 - 2606
  作者：Koyama, Junko、Sugita, Teruyo、Suzuta, Yukio、Irie, Hiroshi

  DOI：——

  日期：——
• Irie, Hiroshi; Tanaka, Shoko; Zhang, Yong, Chemical and pharmaceutical bulletin, 1988, vol. 36, # 8, p. 3134 - 3137
  作者：Irie, Hiroshi、Tanaka, Shoko、Zhang, Yong、Koyama, Junko、Taga, Tooru、Machida, Katsunosuke

  DOI：——

  日期：——