5-丁基-4-壬烯 | 7367-38-6

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 中文名称: 5-丁基-4-壬烯
• 英文名称: 5-Butyl-non-4-en
• 英文别名: 4-Nonene, 5-butyl-；5-butylnon-4-ene
• CAS: 7367-38-6
• 化学式: C₁₃H₂₆
• 分子量: 182.349
• InChiKey: UKAAUKLRJKBIDI-UHFFFAOYSA-N

物化性质

• 熔点：
  -27.14°C (estimate)
• 沸点：
  225.78°C (estimate)
• 密度：
  0.7745

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5-丁基-4-壬烯 在 溶剂黄146 、 铂 作用下， 生成 5-丁基-壬烷
  参考文献：
  名称：

  Iwanow, Bulletin de la Societe Chimique de France, 1925, vol. <4>37, p. 289,293

  摘要：

  DOI：
• 作为产物：
  描述：

  5-壬酮 在 乙醚 、 草酸 作用下， 生成 5-丁基-4-壬烯
  参考文献：
  名称：

  Iwanow, Bulletin de la Societe Chimique de France, 1925, vol. <4>37, p. 289,293

  摘要：

  DOI：

文献信息

• Iron-Catalyzed Diastereoselective Synthesis of Unnatural Chiral Amino Acid Derivatives
  作者：Hao Zhang、Haifang Li、Haijun Yang、Hua Fu

  DOI：10.1021/acs.orglett.6b01493

  日期：2016.7.15

  An iron-catalyzed diastereoselective synthesis of unnatural chiral (S)-α-amino acids with γ-quaternary carbon centers has been developed. The protocol uses inexpensive iron salt as the catalyst, readily available 2-phthaloyl acrylamide and alkenes as the starting materials, and phenylsilane as the reductant, and the reactions were performed well in mixed solvent of 1,2-dichloroethane and ethylene glycol

  已经开发了铁催化的具有γ-季碳中心的非天然手性（S）-α-氨基酸的非对映选择性合成。该方案以廉价的铁盐为催化剂，易得的2-邻苯二甲酰基丙烯酰胺和烯烃为原料，苯基硅烷为还原剂，反应在室温下于1,2-二氯乙烷和乙二醇的混合溶剂中进行得很好。 。该方法显示出一些优点，包括底物简单且宽，条件温和，非对映选择性高以及后处理步骤容易。
• Iron-Catalyzed Alkenylation of Grignard Reagents by Enol Phosphates
  作者：Gérard Cahiez、Olivier Gager、Vanessa Habiak

  DOI：10.1055/s-2008-1067194

  日期：2008.8

  Stereoselective preparation of trisubstituted olefins can be easily performed from an Z/E-mixture of enol phosphates by reacting only the E-isomer with a Grignard reagent in the presence of Fe(acac) 3 . This procedure combines a kinetic differentiation and a stereoselective reaction. The coupling is very chemoselective in the presence of an alkyl chloride, an ester, a ketone or a nitrile.

  通过在 Fe(acac) 3 存在下仅使 E-异构体与格氏试剂反应，可以很容易地从烯醇磷酸酯的 Z/E-混合物进行三取代烯烃的立体选择性制备。该过程结合了动力学微分和立体选择性反应。在烷基氯、酯、酮或腈的存在下，偶联是非常化学选择性的。
• Iodine induced transformations of alcohols under solvent-free conditions
  作者：Gaj Stavber、Marko Zupan、Stojan Stavber

  DOI：10.1016/j.tetlet.2006.09.154

  日期：2006.11

  Iodine has been shown to be an efficient catalyst for transformations of alcohols under solvent-free conditions. In the presence of 5% of iodine, tertiary alcohols underwent dehydration forming the corresponding alkenes, while in the case of 2-phenylpropane-2-ol cyclodimerisation to 1,1,3-trimethyl-3-phenylindane took place. Secondary and primary benzyl alcohols under the same conditions gave the corresponding ethers. (c) 2006 Elsevier Ltd. All rights reserved.
• Dehydration of Alcohols in Dimethyl Sulfoxide^1,2
  作者：Vincent J. Traynelis、William L. Hergenrother、Joel R. Livingston、John A. Valicenti

  DOI：10.1021/jo01054a022

  日期：1962.7
• The Treatment of Facial Verrucae With the Pulsed Dye Laser
  作者：Hannah Vargas、Christopher R. Hove、Marsha L. Dupree、Edwin F. Williams

  DOI：10.1097/00005537-200209000-00007

  日期：2002.9

  AbstractObjectives/Hypothesis To evaluate the treatment of facial verrucae with the pulsed dye laser.Study Design A prospective, nonrandomized, nonblinded pilot study evaluating the treatment of facial verrucae with the pulsed dye laser.Methods Twelve patients with facial verrucae (four recalcitrant) were identified and followed in the study in the setting of a tertiary referral center. The treatment consisted of the flash‐lamp pumped pulsed dye laser (585 mn) with a spot size of 5 mm at fluences between 9.0 and 13 J/cm2. Each lesion received one or two pulses with 2 mm of surrounding normal skin included in the treatment. One patient had paring prior to pulse treatment. The patients were examined 3 to 4 weeks after each procedure, and clinical assessment of the lesion was documented.Results Patient ages ranged from 18 to 47 years. Four patients had refractory lesions, and eight patients had never undergone previous treatment. All 12 patients had full resolution of their facial warts after one to three treatment sessions. No complications such as scarring, alopecia, or recurrence were encountered. Follow‐up ranged from 10 to 33 months.Conclusions Pulsed dye laser therapy is highly effective and safe therapy for facial verrucae. This method appears to selectively destroy warts without damaging surrounding skin.