Bicyclo[2.2.1]heptane-1,2-dicarboxylic acid, dimethyl ester

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Bicyclo[2.2.1]heptane-1,2-dicarboxylic acid, dimethyl ester
• 英文别名: dimethyl bicyclo[2.2.1]heptane-1,2-dicarboxylate
• 化学式: C₁₁H₁₆O₄
• 分子量: 212.24
• InChiKey: HHQWUSYQGAHGKT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• METHOD OF PRODUCING NORBORNANEDICARBOXYLIC ACID ESTER
  申请人：Kawakami Hiroyuki

  公开号：US20140031579A1

  公开（公告）日：2014-01-30

  A method of producing a norbornanedicarboxylic acid ester, the method including a step of reacting a norbornadiene and a formic acid ester in the presence of a ruthenium compound, a cobalt compound, a halide salt and a basic compound.

  一种生产环戊二羧酸酯的方法，该方法包括在钌化合物、钴化合物、卤化物盐和碱性化合物存在下，将环戊二烯和甲酸酯反应的步骤。
• METHOD FOR PRODUCING ESTER COMPOUND
  申请人：JX NIPPON OIL & ENERGY CORPORATION

  公开号：US20160102044A1

  公开（公告）日：2016-04-14

  A method for producing an ester compound including reacting a compound having at least one cyclic structure of a norbornene ring and a norbornadiene ring with an alcohol and carbon monoxide by using a palladium catalyst and an oxidizing agent, to thereby introduce ester groups to carbon atoms forming a double bond in the cyclic structure and obtain the ester compound, wherein the palladium catalyst comprises a palladium complex having a bipyridyl as a ligand.

  一种制备酯化合物的方法，包括使用钯催化剂和氧化剂，将至少具有一个环状结构的诺博尔烯环和诺博尔二烯环化合物与醇和一氧化碳反应，从而将酯基引入环状结构中形成双键的碳原子，并获得酯化合物，其中钯催化剂包括以联吡啶为配体的钯配合物。
• Process for producing polyester resins
  申请人：——

  公开号：US20040059084A1

  公开（公告）日：2004-03-25

  The process of the present invention for producing a polyester resin comprising a dicarboxylic acid constitutional unit and a diol constitutional unit having a cyclic acetal skeleton comprises a step (1) of subjecting a diol (A) having a cyclic acetal skeleton and an ester (D) to transesterification reaction and a step (2) of mainly converting the resultant oligomer into a high polymer. The step (1) simultaneously satisfies the requirements (i) to (iv) as described in the specification. In the process of the present invention, the polyester resins having excellent moldability and mechanical properties are stably produced by a transesterification method which is less detrimental to environments.

  本发明生产聚酯树脂的工艺包括二羧酸结构单元和具有环缩醛骨架的二元醇结构单元，其步骤(1)是将具有环缩醛骨架的二元醇(A)和酯(D)进行酯交换反应，步骤(2)主要是将生成的低聚物转化为高聚物。步骤(1)同时满足说明书中描述的要求(i)至(iv)。在本发明的工艺中，通过对环境危害较小的酯交换反应方法，可以稳定地生产出具有优良成型性和机械性能的聚酯树脂。
• Process for producing polyester resins
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1411074B1

  公开（公告）日：2006-03-15
• RESIN COMPOSITION AND MOLDED OBJECT THEREOF
  申请人：Teijin Chemicals, Ltd.

  公开号：EP1808461B1

  公开（公告）日：2009-03-11