7H-indeno[2,1-c]quinoline | 205-16-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 7H-indeno[2,1-c]quinoline
• 英文别名: 7H-Indeno[2,1-c]chinolin；Indeno[2,1-c]quinoline；7H-indeno[2,1-c]quinoline
• CAS: 205-16-3
• 化学式: C₁₆H₁₁N
• 分子量: 217.27
• InChiKey: MFXPBQPWFGAZBS-UHFFFAOYSA-N

物化性质

• 沸点：
  410.6±14.0 °C(Predicted)
• 密度：
  1.236±0.06 g/cm3(Predicted)
• 熔点：
  96 °C

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  methyl (E)-3-phenyl-2<(phenylamino)methyl>prop-2-enoate 在 氢氧化钾 、 PPA 作用下， 以 甲醇 为溶剂， 反应 1.0h， 生成 7H-indeno[2,1-c]quinoline
  参考文献：
  名称：

  Synthesis of 4b,5,10a,11-tetrahydroindeno[1,2-b]quinolin-10-ones from Baylis–Hillman adducts

  摘要：

  We developed an efficient synthetic method for indenoquinoline skeletons from Baylis-Hillman adducts. 4b,5,10a,11-Tetrahydroindeno[1,2-b]quinolin-10-ones and 7H-indeno[2,1-c]quinolines were prepared from Baylis-Hillman adducts in polyphosphoric acid. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.08.075

文献信息

• ORGANIC MIXTURE AND APPLICATION THEREOF IN ORGANIC ELECTRONIC DEVICES
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20200317646A1

  公开（公告）日：2020-10-08

  The present invention relates to an organic mixture and an application thereof in organic electronic devices. The organic mixture comprises a spirofluorene organic compound containing a fused heterocyclic ring and an aromatic fused heterocyclic organic compound containing an electron-donating group. A combination of the two materials may be used as a host material of a phosphorescent organic light-emitting diode (OLED), which may use the energy of excitons and balance the charge transport to the greatest extent and which may effectively reduce the concentration of excitons and the operating voltage of a corresponding device, thereby effectively improving the efficiency and service life of the related electronic device in order to provide an effective solution for improving the overall performance of an organic electronic device.

  本发明涉及一种有机混合物及其在有机电子器件中的应用。该有机混合物包括含有螺环异芳烃环的螺芴有机化合物和含有供电子给体基团的芳香融合杂环有机化合物。这两种材料的组合可用作磷光有机发光二极管（OLED）的主体材料，该二极管可以利用激子的能量并最大程度地平衡电荷传输，从而有效降低激子的浓度和相应器件的工作电压，从而有效提高相关电子器件的效率和使用寿命，为改善有机电子器件的整体性能提供有效解决方案。
• Borsche; Sinn, Justus Liebigs Annalen der Chemie, 1939, vol. 538, p. 283,287
  作者：Borsche、Sinn

  DOI：——

  日期：——
• NOVEL FUSED INDAN DERIVATIVE AND PHARMACEUTICALLY ACCEPTABLE SALT THEREOF
  申请人：TAIHO PHARMACEUTICAL CO., LTD.

  公开号：EP0713870B1

  公开（公告）日：2001-07-18
• US6028079A
  申请人：——

  公开号：US6028079A

  公开（公告）日：2000-02-22
• Synthesis of 4b,5,10a,11-tetrahydroindeno[1,2-b]quinolin-10-ones from Baylis–Hillman adducts
  作者：Chang Gon Lee、Ka Young Lee、Saravanan GowriSankar、Jae Nyoung Kim

  DOI：10.1016/j.tetlet.2004.08.075

  日期：2004.9

  We developed an efficient synthetic method for indenoquinoline skeletons from Baylis-Hillman adducts. 4b,5,10a,11-Tetrahydroindeno[1,2-b]quinolin-10-ones and 7H-indeno[2,1-c]quinolines were prepared from Baylis-Hillman adducts in polyphosphoric acid. (C) 2004 Elsevier Ltd. All rights reserved.