2,4,7-triphenyl-1,10-phenanthroline | 894073-37-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2,4,7-triphenyl-1,10-phenanthroline
• 英文别名: 2,4,7-phenyl-1,10-phenanthroline
• CAS: 894073-37-1
• 化学式: C₃₀H₂₀N₂
• 分子量: 408.502
• InChiKey: GDLWRQFUPDEYHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  32
• 可旋转键数：
  3
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,4,7-triphenyl-1,10-phenanthroline 、 1-萘基溴化镁, 0.5M IN METHF 在 manganese(IV) oxide 作用下， 以 四氢呋喃 、 氯仿 为溶剂， 生成 2-Naphthalen-1-yl-4,7,9-triphenyl-1,10-phenanthroline
  参考文献：
  名称：

  ELECTRONIC DEVICE INCLUDING PHENANTHROLINE DERIVATIVE

  摘要：

  提供一种有阳极、空穴注入层、光活性层、电子传输层和阴极的有机电子器件。光活性层和/或电子传输层中至少包括具有以下式I的化合物，其中：R1相同或不同，可以是苯基、联苯基、萘基、萘基苯基、三苯胺基或咔唑基苯基；并满足以下条件之一：（i）R2=R3且为H、苯基、联苯基、萘基、萘基苯基、芳基蒽基、苯并芘基、三苯胺基或咔唑基苯基；或（ii）R2为H或苯基；且R3为苯基、联苯基、萘基、萘基苯基、芳基蒽基、苯并芘基、三苯胺基和咔唑基苯基；当R1均为苯基时，R2和R3可以是2-萘基、萘基苯基、芳基蒽基、9-苯并芘基、三苯胺基或m-咔唑基苯基。

  公开号：

  US20120065402A1
• 作为产物：
  描述：

  苯基锂 、 4,7-二苯基-1,10-菲罗啉 在 silica 作用下， 以 methanol-dichloromethane 为溶剂， 生成 2,4,7-triphenyl-1,10-phenanthroline
  参考文献：
  名称：

  Organic photosensitive optoelectronic device having a phenanthroline exciton blocking layer

  摘要：

  描述了一种有机光敏电子器件，该器件具有阳极、阴极和位于阳极和阴极之间的有机阻挡层，其中阻挡层包括苯并咪唑衍生物，并且至少部分地阻挡激子、电子和空穴中的至少一种。

  公开号：

  US20060138453A1

文献信息

• PHENANTHROLINE COMPOUND AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME
  申请人：Yen Feng-Wen

  公开号：US20080265746A1

  公开（公告）日：2008-10-30

  The present invention discloses a phenanthroline compound which can be used as electron-transporting material in organic electroluminescence devices is disclosed. The mentioned phenanthroline compound is represented by the following. wherein Ar is selected from the group consisting of hydrogen atom, alkyl, aryl, wherein R 1 , R 2 and R 3 are identical or different. R 1 , R 2 and R 3 are independently selected from the group consisting of hydrogen atom, alkyl, halide, wherein X 1 , X 2 and X 3 are identical or different. X 1 , X 2 and X 3 are independently selected from the atom or group consisting of O, S, N—R 4 and R 4 is selected from the group consisting of hydrogen atom, alkyl, aryl.

  本发明公开了一种苯并啉化合物，可用作有机电致发光器件中的电子传输材料。所述的苯并啉化合物由以下表示，其中Ar选自氢原子、烷基、芳基所组成的群，其中R1、R2和R3相同或不同。R1、R2和R3独立选自氢原子、烷基、卤素，其中X1、X2和X3相同或不同。X1、X2和X3独立选自O、S、N—R4和R4选自氢原子、烷基、芳基所组成的群。
• Phenanthroline derivative compound
  申请人：Nomura Ryoji

  公开号：US20070037983A1

  公开（公告）日：2007-02-15

  The present invention provides a novel phenanthroline derivative compound, and a manufacturing method thereof, and an electron transporting material, a light emitting element, a light emitting device, and an electronic device using the phenanthroline derivative compound. The phenanthroline derivative compound is characterized by being represented by General Formula 1. Note in General Formula 1 that Ar 1 represents an aryl group, and preferably a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted anthryl group, or a substituted or unsubstituted phenanthryl group. As an example of a preferable compound, there is TMPBP, NaBP, PBP, or the like. A light emitting element, a light emitting device, and an electronic device preferably contain the compound in a light emitting layer, and in that case, the compound is preferably utilized as a host.

  本发明提供了一种新颖的菲啰啉衍生物化合物及其制造方法，以及一种电子传输材料、发光元件、发光装置和使用该菲啰啉衍生物化合物的电子设备。该菲啰啉衍生物化合物的特征在于其由通用式1表示。请注意，在通用式1中，Ar1代表芳基，最好是取代或未取代的苯基、取代或未取代的萘基、取代或未取代的蒽基或取代或未取代的菲啰基。作为一种理想的化合物示例，有TMPBP、NaBP、PBP等。发光元件、发光装置和电子设备最好在发光层中含有该化合物，在这种情况下，该化合物最好用作宿主。
• Phenanthroline compound and organic light emitting device using the same
  申请人：Luminescene Technology Corp.

  公开号：US07754348B2

  公开（公告）日：2010-07-13

  The present invention discloses a phenanthroline compound which can be used as electron-transporting material in organic electroluminescence devices is disclosed. The mentioned phenanthroline compound is represented by the following. wherein Ar is selected from the group consisting of hydrogen atom, alkyl, aryl, wherein R1, R2 and R3 are identical or different. R1, R2 and R3 are independently selected from the group consisting of hydrogen atom, alkyl, halide, wherein X1, X2 and X3 are identical or different. X1, X2 and X3 are independently selected from the atom or group consisting of O, S, N—R4 and R4 is selected from the group consisting of hydrogen atom, alkyl, aryl.

  本发明揭示了一种苯并啉化合物，可用作有机电致发光器件中的电子传输材料。所述苯并啉化合物由以下式表示，其中Ar选自氢原子，烷基，芳基的群组中，而R1，R2和R3相同或不同。R1，R2和R3独立地选自氢原子，烷基，卤素化合物的群组中，而X1，X2和X3相同或不同。X1，X2和X3独立地选自O，S，N-R4的原子或群组中，而R4选自氢原子，烷基，芳基的群组中。
• PYRENE COMPOUND AND ORGANIC LIGHT EMITTING DIODE DEVICE INCLUDING THE SAME
  申请人：LG DISPLAY CO., LTD.

  公开号：US20140061600A1

  公开（公告）日：2014-03-06

  A pyrene compound and an organic light emitting diode device including the same are disclosed. The organic light emitting diode device includes at least two stacks provided between a first electrode and a second electrode, and a charge generation layer provided between the stacks and including an N type charge generation layer and a P type charge generation layer, wherein the N type charge generation layer is made of the pyrene compound.

  本发明公开了一种吡啶化合物以及包括该化合物的有机发光二极管装置。该有机发光二极管装置包括至少两个堆叠层，位于第一电极和第二电极之间，并且在堆叠层之间提供了一个电荷生成层，该电荷生成层包括N型电荷生成层和P型电荷生成层，其中N型电荷生成层由吡啶化合物制成。
• Organic electroluminescent device
  申请人：SONY CORPORATION

  公开号：EP1097981A2

  公开（公告）日：2001-05-09

  An organic electroluminescent device has a single hetero structure comprising, on a glass substrate, an ITO transparent electrode, a hole transport layer, an electron transport layer and a metal electrode superposed in this order wherein a hole-blocking layer containing a bathophenanthroline derivative of the following general formula is interposed between the hole transport layer and the electron transport layer. In this way, the electron-hole-re-combination in the hole transporting luminescent layer can be promoted. wherein X and Y may be the same or different and independently represent a hydrogen atom except the case where a hydrogen atom is at the 2 or 9 position, a substituted or unsubstituted alkyl group except the case where a methyl group is at the 2 or 9 position, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted amino group, a halogen atom, a nitro group, a cyano group or a hydroxyl group provided that at least one of these groups is contained at an arbitrary position.

  一种有机电致发光器件具有单一的异质结构，在玻璃基板上依次叠加有 ITO 透明电极、空穴传输层、电子传输层和金属电极，其中空穴传输层和电子传输层之间夹有含有下通式浴菲罗啉衍生物的空穴阻挡层。这样可以促进空穴传输发光层中的电子-空穴再结合。 其中，X 和 Y 可以相同或不同，并独立地代表氢原子（氢原子位于 2 或 9 位的情况除外）、取代或未取代的烷基（甲基位于 2 或 9 位的情况除外）、取代或未取代的环烷基、取代或未取代的芳基、取代或未取代的氨基、卤素原子、硝基、氰基或羟基，条件是这些基团中至少有一个位于任意位置。