Methyl 3,18,24,31-tetraoxaheptacyclo[18.14.0.04,17.05,10.011,16.022,33.025,30]tetratriaconta-1(20),4(17),5,7,9,11,13,15,21,25(30),26,28,33-tridecaene-27-carboxylate | 261639-84-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: Methyl 3,18,24,31-tetraoxaheptacyclo[18.14.0.04,17.05,10.011,16.022,33.025,30]tetratriaconta-1(20),4(17),5,7,9,11,13,15,21,25(30),26,28,33-tridecaene-27-carboxylate
• CAS: 261639-84-3
• 化学式: C₃₂H₂₄O₆
• 分子量: 504.539
• InChiKey: JOJCGOIKJKLCQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  38
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  63.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Methyl 3,18,24,31-tetraoxaheptacyclo[18.14.0.04,17.05,10.011,16.022,33.025,30]tetratriaconta-1(20),4(17),5,7,9,11,13,15,21,25(30),26,28,33-tridecaene-27-carboxylate 在 lithium hydroxide 作用下， 以 四氢呋喃 、 甲醇 、 水 为溶剂， 反应 3.0h， 以95%的产率得到
  参考文献：
  名称：

  Intramolecular Complex Formation between Flexible Molecular Tweezers and Weak Electron Acceptor

  摘要：

  DOI：

  10.3987/com-00-s(i)81
• 作为产物：
  描述：

  四溴甲苯 在 caesium carbonate 作用下， 以 丙酮 为溶剂， 生成 Methyl 3,18,24,31-tetraoxaheptacyclo[18.14.0.04,17.05,10.011,16.022,33.025,30]tetratriaconta-1(20),4(17),5,7,9,11,13,15,21,25(30),26,28,33-tridecaene-27-carboxylate
  参考文献：
  名称：

  Layered donor–acceptor–acceptor arrangement in complex of molecular tweezer based on dioxa[2.2]orthocyclophane

  摘要：

  Flexible molecular receptors having three aromatic chromophores can bind electron deficient pi-system such as TCNQ and TCNB with both face-to-face and face-to-edge interactions. The receptors have tweezer-type conformations when a guest was trapped within their cavities. Sandwich-type donor-acceptor-acceptor (DAA) arrangement was realized in the crystalline supramolecular complex. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)02095-x

文献信息

• Layered donor–acceptor–acceptor arrangement in complex of molecular tweezer based on dioxa[2.2]orthocyclophane
  作者：Hirotaka Kurebayashi、Takeharu Haino、Yoshimasa Fukazawa

  DOI：10.1016/s0040-4039(99)02095-x

  日期：2000.1

  Flexible molecular receptors having three aromatic chromophores can bind electron deficient pi-system such as TCNQ and TCNB with both face-to-face and face-to-edge interactions. The receptors have tweezer-type conformations when a guest was trapped within their cavities. Sandwich-type donor-acceptor-acceptor (DAA) arrangement was realized in the crystalline supramolecular complex. (C) 2000 Elsevier Science Ltd. All rights reserved.
• Intramolecular Complex Formation between Flexible Molecular Tweezers and Weak Electron Acceptor
  作者：Yoshimasa Fukazawa、Hirotaka Kurebayashi

  DOI：10.3987/com-00-s(i)81

  日期：——