1-(4-(Benzyloxy)-2-hydroxyphenyl)-1-tetradecanone | 143287-06-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(4-(Benzyloxy)-2-hydroxyphenyl)-1-tetradecanone
• 英文别名: 1-(2-hydroxy-4-phenylmethoxyphenyl)tetradecan-1-one
• CAS: 143287-06-3
• 化学式: C₂₇H₃₈O₃
• 分子量: 410.597
• InChiKey: CYAOZLGYCHGXKD-UHFFFAOYSA-N

物化性质

• 沸点：
  550.1±35.0 °C(Predicted)
• 密度：
  1.020±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.5
• 重原子数：
  30
• 可旋转键数：
  16
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(4-(Benzyloxy)-2-hydroxyphenyl)-1-tetradecanone 在 盐酸羟胺 、 potassium acetate 作用下， 以 乙醇 为溶剂， 反应 3.0h， 生成 1-(4-Benzyloxy-2-hydroxy-phenyl)-tetradecan-1-one oxime
  参考文献：
  名称：

  Synthese von 4-Alkoxy-2-hydroxyphenylketoximen als Metallextraktions-Reagenzien

  摘要：

  The C-Acylation (Friedel-Crafts reaction) of resorcinol with aluminium chloride, the monoetherification in 4-position of the resulting 2,4-dihydroxyphenylketones, and the preparation of oximes (8, 9, 10, 11) from this ketones were investigated. The compounds obtained are characterized by elemental analysis, and the i.r., u.v. and H-1-n.m.r. spectra are discussed. Solubility data of some oximes are determined in water, octane and toluene. The extraction properties for copper-(II)-and iron-(III)-ions are measured by isotope methods in relation to the extragent structure, the extraction time and the pH-range.

  DOI：

  10.1002/prac.19923340313
• 作为产物：
  描述：

  间苯二酚 、 alkaline earth salt of/the/ methylsulfuric acid 在 三氯化铝 、 potassium carbonate 作用下， 以 1,2-二氯乙烷 、 丙酮 为溶剂， 反应 25.0h， 生成 1-(4-(Benzyloxy)-2-hydroxyphenyl)-1-tetradecanone
  参考文献：
  名称：

  Synthese von 4-Alkoxy-2-hydroxyphenylketoximen als Metallextraktions-Reagenzien

  摘要：

  The C-Acylation (Friedel-Crafts reaction) of resorcinol with aluminium chloride, the monoetherification in 4-position of the resulting 2,4-dihydroxyphenylketones, and the preparation of oximes (8, 9, 10, 11) from this ketones were investigated. The compounds obtained are characterized by elemental analysis, and the i.r., u.v. and H-1-n.m.r. spectra are discussed. Solubility data of some oximes are determined in water, octane and toluene. The extraction properties for copper-(II)-and iron-(III)-ions are measured by isotope methods in relation to the extragent structure, the extraction time and the pH-range.

  DOI：

  10.1002/prac.19923340313

文献信息

• Synthese von 4-Alkoxy-2-hydroxyphenylketoximen als Metallextraktions-Reagenzien
  作者：J. Beger、H.-J. Binte、L. Brunne、R. Neumann

  DOI：10.1002/prac.19923340313

  日期：——

  The C-Acylation (Friedel-Crafts reaction) of resorcinol with aluminium chloride, the monoetherification in 4-position of the resulting 2,4-dihydroxyphenylketones, and the preparation of oximes (8, 9, 10, 11) from this ketones were investigated. The compounds obtained are characterized by elemental analysis, and the i.r., u.v. and H-1-n.m.r. spectra are discussed. Solubility data of some oximes are determined in water, octane and toluene. The extraction properties for copper-(II)-and iron-(III)-ions are measured by isotope methods in relation to the extragent structure, the extraction time and the pH-range.