8-(4-bromophenyl)-8-phenyl-8H-indolo-[3,2,1-de]acridine | 1029613-69-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 8-(4-bromophenyl)-8-phenyl-8H-indolo-[3,2,1-de]acridine
• 英文别名: 13-(4-bromophenyl)-13-phenyl-1-azapentacyclo[10.7.1.02,7.08,20.014,19]icosa-2,4,6,8(20),9,11,14,16,18-nonaene
• CAS: 1029613-69-1
• 化学式: C₃₁H₂₀BrN
• 分子量: 486.41
• InChiKey: GNTHSBBBBLAJEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  33
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  8-(4-bromophenyl)-8-phenyl-8H-indolo-[3,2,1-de]acridine 在 正丁基锂 、 双氧水 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 2.0h， 生成 8-(4-(diphenylphosphoryl)phenyl)-8-phenyl-8H-indolo[3,2,1-de]acridine
  参考文献：
  名称：

  JP5663566

  摘要：

  公开号：
• 作为产物：
  描述：

  咔唑 在 copper(l) iodide 、 正丁基锂 、 potassium carbonate 作用下， 以 四氢呋喃 、 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 8.16h， 生成 8-(4-bromophenyl)-8-phenyl-8H-indolo-[3,2,1-de]acridine
  参考文献：
  名称：

  JP5663566

  摘要：

  公开号：

文献信息

• Synthesis of fused phenylcarbazole phosphine oxide based high triplet energy host materials
  作者：Soon Ok Jeon、Jun Yeob Lee

  DOI：10.1016/j.tet.2010.07.008

  日期：2010.9

  High triplet energy host materials based on novel fused phenylcarbazole core structure and diphenylphosphine oxide were synthesized and the physical properties of the host materials were investigated. A high triplet energy of 2.95 eV was obtained from the fused phenylcarbazole based host materials and the energy levels could be manipulated using the diphenylphosphine oxide group. The fused phenylcarbazole

  合成了基于新型稠合苯基咔唑核结构和二苯基氧化膦的高三重态能量主体材料，并研究了主体材料的物理性能。从熔融的苯基咔唑基主体材料获得了2.95 eV的高三重态能量，并且可以使用二苯基氧化膦基团控制能级。熔融的苯基咔唑基高三重态能量主体材料在高温下显示出优异的形态稳定性。
• CARBAZOLE-BASED PHOSPHINE OXIDE COMPOUND, AND ORGANIC ELECTROLUMINESCENT DEVICE INCLUDING THE SAME
  申请人：Lee Jun-Yeob

  公开号：US20120068168A1

  公开（公告）日：2012-03-22

  The present invention relates to a carbazole-based phosphine oxide compound, and an organic electroluminescent device including the same. According to the present invention, provided are a compound for an organic electroluminescent device which can improve the thermal stability and efficiency characteristics which are unstable and low, respectively, corresponding to problems of known compounds for organic electroluminescent devices, and particularly, can implement excellent efficiency characteristics in a pure blue phosphorescent device, by using the carbazole-based phosphine oxide compound of the compound for the organic electroluminescent device, and the organic electroluminescent device. According to one aspect of the present invention, the carbazole-based phosphine oxide compound of the compound for the organic electroluminescent device is provided, and the organic electroluminescent device containing the same which can implement thermal stability and high efficiency characteristics is also provided.

  本发明涉及一种基于咔唑的膦氧化物化合物和包括该化合物的有机电致发光器件。根据本发明，提供了一种用于有机电致发光器件的化合物，可以改善已知有机电致发光器件化合物存在的热稳定性和效率特性不稳定和低下的问题，特别是可以通过使用该有机电致发光器件化合物中的基于咔唑的膦氧化物化合物，在纯蓝色磷光器件中实现优异的效率特性。根据本发明的一个方面，提供了用于有机电致发光器件的基于咔唑的膦氧化物化合物，并提供了包括该化合物的有机电致发光器件，该器件可以实现热稳定性和高效率特性。
• Carbazole-based phosphine oxide compound, and organic electroluminescent device including the same
  申请人：Lee Jun-Yeob

  公开号：US09278986B2

  公开（公告）日：2016-03-08

  The present invention relates to a carbazole-based phosphine oxide compound, and an organic electroluminescent device including the same. According to the present invention, provided are a compound for an organic electroluminescent device which can improve the thermal stability and efficiency characteristics which are unstable and low, respectively, corresponding to problems of known compounds for organic electroluminescent devices, and particularly, can implement excellent efficiency characteristics in a pure blue phosphorescent device, by using the carbazole-based phosphine oxide compound of the compound for the organic electroluminescent device, and the organic electroluminescent device. According to one aspect of the present invention, the carbazole-based phosphine oxide compound of the compound for the organic electroluminescent device is provided, and the organic electroluminescent device containing the same which can implement thermal stability and high efficiency characteristics is also provided.

  本发明涉及一种基于咔唑的膦氧化物化合物和包括该化合物的有机电致发光器件。根据本发明，提供了一种用于有机电致发光器件的化合物，可以改善已知有机电致发光器件化合物存在的热稳定性和效率特性不稳定和低下的问题，特别是使用基于咔唑的膦氧化物化合物可以在纯蓝色磷光器件中实现优异的效率特性，并提供了包括该化合物的有机电致发光器件。根据本发明的一方面，提供了用于有机电致发光器件的基于咔唑的膦氧化物化合物，以及包括该化合物的有机电致发光器件，可以实现热稳定性和高效率特性。
• US9278986B2
  申请人：——

  公开号：US9278986B2

  公开（公告）日：2016-03-08
• JP5663566
  申请人：——

  公开号：——

  公开（公告）日：——