6,11-bis[[tri(prop-2-yl)silyl]ethynyl]naphtho[2',3':5,6][1,4]dioxino[2,3-b]pyrazine | 1426074-07-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 6,11-bis[[tri(prop-2-yl)silyl]ethynyl]naphtho[2',3':5,6][1,4]dioxino[2,3-b]pyrazine
• 英文别名: Tri(propan-2-yl)-[2-[18-[2-tri(propan-2-yl)silylethynyl]-2,9-dioxa-4,7-diazatetracyclo[8.8.0.03,8.012,17]octadeca-1(18),3,5,7,10,12,14,16-octaen-11-yl]ethynyl]silane；tri(propan-2-yl)-[2-[18-[2-tri(propan-2-yl)silylethynyl]-2,9-dioxa-4,7-diazatetracyclo[8.8.0.03,8.012,17]octadeca-1(18),3,5,7,10,12,14,16-octaen-11-yl]ethynyl]silane
• CAS: 1426074-07-8
• 化学式: C₃₆H₄₈N₂O₂Si₂
• 分子量: 596.96
• InChiKey: DRMKQEZWKASZAT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.67
• 重原子数：
  42
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  44.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,3-二甲氧基萘 在 2-吡啶甲酸 、 potassium phosphate 、 copper(l) iodide 、 四(三苯基膦)钯 、 溴 、 三溴化硼 、 三乙胺 、 二异丙胺 、 三苯基膦 作用下， 以 乙二醇二甲醚 、 二氯甲烷 、 溶剂黄146 、 甲苯 为溶剂， 反应 43.75h， 生成 6,11-bis[[tri(prop-2-yl)silyl]ethynyl]naphtho[2',3':5,6][1,4]dioxino[2,3-b]pyrazine
  参考文献：
  名称：

  Alkynylated Diazadioxaacenes: Syntheses and Properties

  摘要：

  We report the successful synthesis of a series of ethynylated dioxadiazaacenes and investigate their properties. We developed a modular Cu-based catalytic procedure to build up [1,4]dioxino[2,3-b]pyrazine motifs starting from only a few building blocks. TIPS-acetylene-substituted benzene-1,2-diol and naphthalene-2,3-diol were reacted with 2,3-dichloropyrazine, 2,3-dichloroquinoxaline, and 2,3-dichlorobenzoquinoxaline to give a set of six novel and well-soluble dioxadiazaacenes. Different reaction conditions for the coupling were tested. Copper catalysis is most effective and gave the best yield of dioxadiazaacenes. The resulting azaoxaacenes were characterized in terms of optical and electronic properties and crystal packing.

  DOI：

  10.1021/jo400092r

文献信息

• Alkynylated Diazadioxaacenes: Syntheses and Properties
  作者：Manuel Schaffroth、Benjamin D. Lindner、Vladislav Vasilenko、Frank Rominger、U. H. F. Bunz

  DOI：10.1021/jo400092r

  日期：2013.4.5

  We report the successful synthesis of a series of ethynylated dioxadiazaacenes and investigate their properties. We developed a modular Cu-based catalytic procedure to build up [1,4]dioxino[2,3-b]pyrazine motifs starting from only a few building blocks. TIPS-acetylene-substituted benzene-1,2-diol and naphthalene-2,3-diol were reacted with 2,3-dichloropyrazine, 2,3-dichloroquinoxaline, and 2,3-dichlorobenzoquinoxaline to give a set of six novel and well-soluble dioxadiazaacenes. Different reaction conditions for the coupling were tested. Copper catalysis is most effective and gave the best yield of dioxadiazaacenes. The resulting azaoxaacenes were characterized in terms of optical and electronic properties and crystal packing.