7-十七酮 | 6064-42-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 7-十七酮
• 英文名称: heptadecan-7-one
• 英文别名: heptadecane-7-one；Heptadecan-7-on；Hexyl-decyl-keton；7-Heptadecanone
• CAS: 6064-42-2
• 化学式: C₁₇H₃₄O
• 分子量: 254.456
• InChiKey: NFRKSAMCQGIGRC-UHFFFAOYSA-N

物化性质

• 熔点：
  46.67°C (estimate)
• 沸点：
  322.67°C (estimate)
• 密度：
  0.8381 (estimate)
• LogP：
  7.091 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  18
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 危险性防范说明：
  P261,P264,P270,P271,P280,P301+P312,P302+P352,P304+P340,P305+P351+P338,P330,P332+P313,P337+P313,P362,P403+P233,P405,P501
• 危险性描述：
  H302,H315,H319,H335

反应信息

• 作为反应物：
  描述：

  7-十七酮 在 cobalt polysulfide 、 sulfur 、 溶剂黄146 作用下， 150.0~200.0 ℃ 、10.3 MPa 条件下， 生成 heptadecane-7-thiol
  参考文献：
  名称：

  Method of producing thiols

  摘要：

  公开号：

  US02402613A1
• 作为产物：
  描述：

  1-碘癸烷 在 锌铜偶 、 乙酸乙酯 、 甲苯 作用下， 生成 7-十七酮
  参考文献：
  名称：

  Breusch; Baykut, Chemische Berichte, 1953, vol. 86, p. 684,686

  摘要：

  DOI：

文献信息

• A General Approach to Intermolecular Olefin Hydroacylation through Light‐Induced HAT Initiation: An Efficient Synthesis of Long‐Chain Aliphatic Ketones and Functionalized Fatty Acids
  作者：Subhasis Paul、Joyram Guin

  DOI：10.1002/chem.202004946

  日期：2021.3

  hydroacylation protocol applies to a wide array of substrates bearing numerous functional groups and many complex structural units. The reaction proves to be scalable (up to 5 g). Different functionalized fatty acids, petrochemicals and naturally occurring alkanes can be synthesized with this protocol. A radical chain mechanism is implicated in the process.

  本文介绍了一种通过使用光诱导氢原子转移（HAT）引发对未活化底物进行分子间自由基加氢酰化的操作简单，对环境无害且有效的方法。使用可商购和廉价的光引发剂（Ph 2 CO和NHPI）使该方法具有吸引力。烯烃加氢酰化方案适用于多种带有许多官能团和许多复杂结构单元的底物。该反应证明是可扩展的（最大5 g）。可以使用该方案合成不同的官能化脂肪酸，石化产品和天然存在的烷烃。自由基链机制与该过程有关。
• Solvent-free chelation-assisted intermolecular hydroacylation: effect of microwave irradiation in the synthesis of ketone from aldehyde and 1-alkene by Rh(I) complex
  作者：Chul-Ho Jun、Jong-Hwa Chung、Dae-Yon Lee、André Loupy、Saber Chatti

  DOI：10.1016/s0040-4039(01)00853-x

  日期：2001.7

  As a green alternative to classical homogeneous catalyst in toluene in closed vessels, the intermolecular hydroacylation of 1-alkenes with aldehydes by Rh(I) complex (Wilkinson catalyst) can be realized efficiently under solvent-free conditions. When coupled to microwave activation, it results in a serious improvement when compared to classical conditions.

  作为封闭容器中甲苯中经典均相催化剂的绿色替代品，可以在无溶剂条件下有效地实现Rh（I）配合物（Wilkinson催化剂）对1-烯烃与醛的分子间加氢酰化反应。当与微波激活耦合时，与传统条件相比，它会带来严重的改善。
• Identification and Field Bioassay of <i>Rusicada privata</i> (Lepidoptera: Erebidae) Sex Pheromone
  作者：Junheon Kim、Sujin Lee

  DOI：10.1021/acs.jafc.3c00307

  日期：2023.5.31

  Rusicada privata (Lepidoptera: Erebidae) is a major pest insect on Hibiscus syriacus L. (Malvaceae: Malvales), which is usually planted in urban landscapes. Insecticidal control of R. privata is not ideal for urban landscaping due to its harmful effects and risk to human health. Therefore, nonchemical and ecofriendly alternatives are needed. To identify the sex pheromone of R. privata, abdominal tip

  Rusicada privata （鳞翅目：Erebidae）是Hibiscus syriacus L.（锦葵科：Malvales）的主要害虫，通常种植在城市景观中。对R. privata的杀虫控制由于其对人类健康的有害影响和风险而不适合城市景观美化。因此，需要非化学和生态友好的替代品。为了鉴定R. privata的性信息素，通过气相色谱 - 质谱法分析了雄性和雌性R. privata的腹​​部尖端提取物。雌性R. privata中 7-甲基十七烷 (7Me-17Hy) 的丰度腹部尖端提取物使我们假设它是主要的性信息素。该化合物由质谱库初步鉴定，并通过将雌性产生的化合物的保留时间和质谱与合成标准品的保留时间和质谱进行匹配来确认。这些化合物引发触角电图 (EAG) 活动。在野外诱捕实验中，只有含有 7Me-17Hy 的合成诱饵吸引了R. privata雄性。EAG活性和野外诱捕结果证实，7M
• Ims detection of chemical markers in petroleum products
  申请人：Authentix, Inc.

  公开号：EP2264130A2

  公开（公告）日：2010-12-22

  A method and composition for identifying chemically tagged petroleum products can be achieved by adding one or more chemicals to a selected petroleum product wherein the chemical is immune to extraction from the petroleum product by conventional inexpensive absorbents, cannot be removed by extraction with acids, bases, or immiscible solvents, cannot be easily oxidized, reduced or reacted with common agents, is difficult to disguise by masking with other agents, has a low polarity, and has a boiling pint in the range of the petroleum product the chemical is being added to. The presence of the chemical is determined by using ion mobility to spectroscopy.

  通过向选定的石油产品中添加一种或多种化学物质，可以实现识别化学标记石油产品的方法和组合物，其中的化学物质不会被传统的廉价吸收剂从石油产品中萃取出来，不能被酸、碱或不溶性溶剂萃取去除，不容易被氧化、还原或与普通制剂发生反应，难以用其他制剂掩盖，极性低，沸点在所添加化学物质的石油产品范围内。化学品的存在是通过离子迁移率和光谱来确定的。
• IMS detection of chemical markers in petroleum products
  申请人：——

  公开号：US20040147413A1

  公开（公告）日：2004-07-29

  A method and composition for identifying chemically tagged petroleum products can be achieved by adding one or more chemicals to a selected petroleum product wherein the chemical is immune to extraction from the petroleum product by conventional inexpensive absorbents, cannot be removed by extraction with acids, bases, or immiscible solvents, cannot be easily oxidized, reduced or reacted with common agents, is difficult to disguise by masking with other agents, has a low polarity, and has a boiling point in the range of the petroleum product the chemical is being added to. The presence of the chemical is determined by using ion mobility spectroscopy.

  通过向选定的石油产品中添加一种或多种化学物质，可以实现识别化学标记石油产品的方法和组合物，其中的化学物质不会被传统的廉价吸收剂从石油产品中萃取出来，不能被酸、碱或不溶性溶剂萃取去除，不易被氧化、还原或与普通制剂发生反应，难以用其他制剂掩盖，极性低，沸点在所添加化学物质的石油产品范围内。使用离子迁移率光谱法确定化学品的存在。

表征谱图