3-Heptafluorpropylhydroxymethylen-d-campher | 257289-31-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 3-Heptafluorpropylhydroxymethylen-d-campher
• 英文别名: (-)-C3F7C(O)C10H15O；3-(heptafluorobutyryl)-d-camphor；(1R)-3-(2,2,3,3,4,4,4-heptafluoro-1-oxobutyl)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one；3-heptafluorobutyryl-(+)-camphor；3-Heptafluorobutyryl-(-)-camphor；3-(2,2,3,3,4,4,4-heptafluorobutanoyl)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
• CAS: 257289-31-9
• 化学式: C₁₄H₁₅F₇O₂
• 分子量: 348.261
• InChiKey: PEWOESYEGLBLNR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  9

文献信息

• Luminous Compound Containing Lanthanide Ion
  申请人：Nakamura Koki

  公开号：US20090247736A1

  公开（公告）日：2009-10-01

  A luminous compound represented by the following formula (I): Met-COG-ChHet  Formula (I) wherein Met represents a group containing a lanthanide ion, COG represents a heterocyclic group bonded directly to the lanthanide ion contained in the group represented by Met, and ChHet represents a group having a heterocycle, where ChHet is preferably a group that conjugates with COG.

  一种由以下化学式（I）表示的发光化合物：Met-COG-ChHet  化学式（I）其中，Met代表含有镧系离子的基团，COG代表直接连接到Met所代表的基团中含有的镧系离子的杂环基团，ChHet代表具有杂环的基团，其中ChHet最好是与COG共轭的基团。
• NOVEL PLATINUM (II) COMPLEX, PROCESS FOR PREPARING THE SAME, AND THERAPEUTIC AGENT FOR MALIGNANT TUMOR
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0341318A1

  公开（公告）日：1989-11-15

  A novel platinum (II) complex represented by general formula (I), wherein A is an enol form of a β-diketone represented by general formula (II), wherein R, is an alkyl group hav. ing 1 to 4 carbon atoms or a perfluoroalkyl group having 1 to 4 carbon atoms, R2 is a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and R3 is hydrogen or an alkyl group having 1 to 3 carbon atoms, provided that R2 and R3 may be each combined to a carbon atom bonded thereto to form a ring: and the configuration of 1,2-diaminocyclohexane is cis, trans-1 or trans-d. The novel platinum (II) complex has a strong antitumor activity and is less toxic, which renders the platinum (II) complex useful as a therapeutic agent for malignant tumor.

  一种通式(I)表示的新型铂(II)络合物，其中A是通式(II)表示的β-二酮的烯醇形式，其中R是具有1至4个碳原子的烷基或具有1至4个碳原子的全氟烷基，R2是具有1至4个碳原子的取代或未取代的烷基，R3是氢或氢键。具有 1 至 4 个碳原子的烷基或具有 1 至 4 个碳原子的全氟烷基，R2 是具有 1 至 4 个碳原子的取代或未取代的烷基，R3 是氢或具有 1 至 3 个碳原子的烷基，条件是 R2 和 R3 可各自与与其结合的碳原子结合形成环：且 1，2-二氨基环己烷的构型为顺式、反式-1 或反式-d。新型铂(II)络合物具有很强的抗肿瘤活性，毒性较低，因此可用作恶性肿瘤的治疗剂。
• FLUORESCENT MATERIAL FOR CONVERTING WAVELENGTHS, RESIN COMPOSITION FOR CONVERTING WAVELENGTHS CONTAINING THE FLUORESCENT MATERIAL, SOLAR CELL MODULE PRODUCED USING THE FLUORESCENT MATERIAL OR THE RESIN COMPOSITION, PROCESS FOR PRODUCING RESIN COMPOSITION FOR CONVERTING WAVELENGTHS, AND PROCESS FOR PRODUCING SOLAR CELL MODULE
  申请人：Hitachi Chemical Company, Ltd.

  公开号：EP2485271A1

  公开（公告）日：2012-08-08

  Disclosed is a fluorescent material for conversing wavelengths used in a light transmitting layer of a solar cell module, by mixing a fluorescent substance and a vinyl compound. Also, disclosed is a resin composition for converting wavelengths by polymerizing the vinyl compound of the fluorescent material for converting wavelengths and then mixing it with a transparent dispersion medium resin. Therefore, there can be provided a fluorescent material for converting wavelengths capable of converting a light that contributes less to solar energy generation in the incident solar radiation, to a wavelength that contributes significantly to energy generation, as well as utilizing the solar radiation efficiently and stably without deteriorating, a resin composition for converting wavelengths and methods for producing thereof.

  本发明公开了一种用于太阳能电池组件透光层的波长转换荧光材料，该材料由荧光物质和乙烯基化合物混合而成。此外，本发明还公开了一种用于转换波长的树脂组合物，其方法是将用于转换波长的荧光材料的乙烯基化合物聚合，然后与透明分散介质树脂混合。因此，可以提供一种用于转换波长的荧光材料，该材料能够将入射太阳辐射中对太阳能发电贡献较小的光转换成对发电贡献较大的波长，并且能够高效、稳定地利用太阳辐射而不会变质，还可以提供一种用于转换波长的树脂组合物及其生产方法。
• SPHERICAL PHOSPHOR, SEALING MATERIAL FOR WAVELENGTH CONVERSION SOLAR BATTERY, SOLAR BATTERY MODULE AND METHOD FOR PRODUCING SAME
  申请人：Hitachi Chemical Company, Ltd.

  公开号：EP2557137A1

  公开（公告）日：2013-02-13

  A spherical phosphor is formed by including a fluorescent substance and a transparent material including the fluorescent substance. In addition, a wavelength conversion-type photovoltaic cell sealing material is formed by including a light transmissive resin composition layer including the spherical phosphor and a sealing resin.

  通过包括荧光物质和包括荧光物质的透明材料形成球形荧光粉。此外，通过包括球形荧光粉和密封树脂的透光树脂组合层，形成波长转换型光伏电池密封材料。
• WAVELENGTH-CONVERTING RESIN COMPOSITION FOR SOLAR CELL, AND SOLAR CELL MODULE
  申请人：Hitachi Chemical Company, Ltd.

  公开号：EP2557600A1

  公开（公告）日：2013-02-13

  A wavelength-converting resin composition for a photovoltaic cell, comprising: a fluorescent substance having a maximum absorption wavelength in an absorbance spectrum of which being λmax (nm); resin particles; and a dispersion medium resin, wherein a value of A1 (λ), which is represented by the following Equation 1, at the maximum absorption wavelength λmax (nm) is 3.0×10-4 (O. D. /µm) or less in a case in which: an intensity of transmitted light that is obtained as a result of incident light having a light intensity of I0 (λ) at a wavelength λ (nm) having passed through a resin film in a thickness direction of the resin film, the resin film being formed from the resin composition and having a thickness of t (µm), is defined as I (λ); and an intensity of transmitted light that is obtained as a result of the incident light having passed through a reference resin film in a thickness direction of the reference resin film, the reference resin film being formed from a reference resin composition obtained by excluding the fluorescent substance and the resin particles from the resin composition, and having a thickness of tref (µm), is defined as Iref (λ). A1λ=logI0λ/Iλ/t-logI0λ/Iλ/tref

  一种用于光伏电池的波长转换树脂组合物，包括：在吸收光谱中具有最大吸收波长 λmax (nm) 的荧光物质；树脂颗粒；以及分散介质树脂、 其中，在最大吸收波长 λmax (nm)处，A1 (λ)（用以下公式 1 表示）的值为 3.0×10-4 (O. D. /µm)或更小，在这种情况下，A1 (λ)的值为 3.0×10-4 (O. D. /µm)或更小： 在波长 λ (nm) 处光强为 I0 (λ) 的入射光沿树脂膜的厚度方向穿过树脂膜（树脂膜由树脂组合物形成，厚度为 t (µm)）后得到的透射光强度定义为 I (λ)；以及 因入射光沿参考树脂膜的厚度方向穿过参考树脂膜而获得的透射光强度，参考树脂膜由参考树脂组合物形成，该参考树脂组合物通过从树脂组合物中排除荧光物质和树脂颗粒而获得，其厚度为 tref (µm)，定义为 Iref (λ)。A1λ=logI0λ/Iλ/t-logI0λ/Iλ/tref

表征谱图