| 793719-94-5

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• CAS: 793719-94-5
• 化学式: C₂₀H₃₄Sn
• 分子量: 395.184
• InChiKey: HQNKPBYHNJXRDK-HLHUSFLGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.51
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  苯基乙炔三丁基锡 、 氘 在 二氯二羰基双(三苯基膦)钌 作用下， 以 二甲基亚砜 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Ruthenium-Catalyzed Hydrogenation of Alkynylstannanes with Migration of the Stannyl Group

  摘要：

  Molecular hydrogen adds to aliphatic and aromatic alkynylstannanes in the presence of a ruthenium catalyst, pushing the stannyl group to the adjacent carbon atom to give alpha-substituted vinylstannanes. This is the first achievement of hydrogenation of alkynylstannanes, which is applicable also to the deuteration affording precursors for an important class of deuterium-labeled compounds.

  DOI：

  10.1021/ja0458827

文献信息

• Ruthenium-Catalyzed Hydrogenation of Alkynylstannanes with Migration of the Stannyl Group
  作者：Eiji Shirakawa、Ryotaro Morita、Teruhisa Tsuchimoto、Yusuke Kawakami

  DOI：10.1021/ja0458827

  日期：2004.10.1

  Molecular hydrogen adds to aliphatic and aromatic alkynylstannanes in the presence of a ruthenium catalyst, pushing the stannyl group to the adjacent carbon atom to give alpha-substituted vinylstannanes. This is the first achievement of hydrogenation of alkynylstannanes, which is applicable also to the deuteration affording precursors for an important class of deuterium-labeled compounds.