triphenylene 1,2-oxide | 84849-89-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: triphenylene 1,2-oxide
• 英文别名: Triphenyleno(1,2-b)oxirene, 10a,11a-dihydro-；16-oxapentacyclo[12.5.0.02,7.08,13.015,17]nonadeca-1(14),2,4,6,8,10,12,18-octaene
• CAS: 84849-89-8
• 化学式: C₁₈H₁₂O
• 分子量: 244.293
• InChiKey: LLFGEXZJKGRDGN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  triphenylene 1,2-oxide 在 三乙胺 作用下， 以 氯苯 为溶剂， 反应 0.5h， 生成 phenanthro<10,9-b>oxepine
  参考文献：
  名称：

  菲，联苯，苯并[ a，c ]蒽和苯并[ a，h ]蒽的氧化芳烃代谢产物的合成和异构化

  摘要：

  由对映纯的二溴MTPA前体9A RRS *合成的Dibenz [ a，h ]蒽3,4-氧化物5A RS被发现已完全消旋，并伴随有苯并[5,6]蒽[1,2- b ]奥沙平 11A。菲3,4-氧化物5B RS，从对映纯细菌中获得代谢物 观察到，通过涉及氯醇酯16B的改进的合成方法，顺式-3,4-二羟基-3,4-二氢菲12B在环境温度下自发消旋。Dibenz [ a，h ]蒽3,4-氧化物5A RS / 5A SR，菲3,4-氧化物5B RS / 5B SR，联苯1,2-氧化物5C RS / 5C SR和dibenz [ a，c ]蒽1,2-氧化物5D RS / 5D SR通过新方法从相应的外消旋顺式-四氢二醇前体14A - 14D获得的，没有任何证据表明形成了苯并[5,6]蒽[1,2- b ]奥沙平 11A，萘[1,2- b ]奥西平 11B，菲咯[10,9- b ]奥沙平 分别为11C或苯并[3

  DOI：

  10.1039/b009712h
• 作为产物：
  描述：

  1,2-二氢苯并菲 在 N-溴代丁二酰亚胺(NBS) 、 四氧化锇 、 三甲基氯硅烷 、 偶氮二异丁腈 、 sodium methylate 、 三乙胺 、 苯甲酸 作用下， 以 四氢呋喃 、 四氯化碳 、 二氯甲烷 为溶剂， 反应 16.75h， 生成 triphenylene 1,2-oxide
  参考文献：
  名称：

  菲，联苯，苯并[ a，c ]蒽和苯并[ a，h ]蒽的氧化芳烃代谢产物的合成和异构化

  摘要：

  由对映纯的二溴MTPA前体9A RRS *合成的Dibenz [ a，h ]蒽3,4-氧化物5A RS被发现已完全消旋，并伴随有苯并[5,6]蒽[1,2- b ]奥沙平 11A。菲3,4-氧化物5B RS，从对映纯细菌中获得代谢物 观察到，通过涉及氯醇酯16B的改进的合成方法，顺式-3,4-二羟基-3,4-二氢菲12B在环境温度下自发消旋。Dibenz [ a，h ]蒽3,4-氧化物5A RS / 5A SR，菲3,4-氧化物5B RS / 5B SR，联苯1,2-氧化物5C RS / 5C SR和dibenz [ a，c ]蒽1,2-氧化物5D RS / 5D SR通过新方法从相应的外消旋顺式-四氢二醇前体14A - 14D获得的，没有任何证据表明形成了苯并[5,6]蒽[1,2- b ]奥沙平 11A，萘[1,2- b ]奥西平 11B，菲咯[10,9- b ]奥沙平 分别为11C或苯并[3

  DOI：

  10.1039/b009712h

文献信息

• Novel arylamine compound and organic electroluminescence device
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20020137969A1

  公开（公告）日：2002-09-26

  A novel arylamine compound represented by the following general formula (1): 1 wherein R 1 and R 2 each independently represent an alkyl group, an alkoxyl group, an aryl group, an arylalkyl group or an aryloxyl group, Ar 1 to Ar 4 each independently represent an aryl group or a heterocyclic group, with provisos that at least two of Ar 1 to Ar 4 each represent m-biphenyl group or a biphenyl group substituted with aryl groups and the others of Ar 1 to Ar 4 each represent biphenyl group and that, when the biphenyl group substituted with aryl groups is a biphenyl group substituted with two aryl groups, the others of Ar 1 to Ar 4 each represent an aryl group; and an organic electroluminescence device comprising a layer of organic compounds which comprises the novel arylamine compound. The organic electroluminescence device has a high luminance, excellent heat resistance and a long life and emits light; at a high efficiency. The novel arylamine compound provides the advantageous properties to the organic electroluminescence device.

  一种新的芳胺化合物，其通式如下（1）： 其中R1和R2分别独立表示烷基、烷氧基、芳基、芳基烷基或芳氧基，Ar1至Ar4分别独立表示芳基或杂环基，但至少两个Ar1至Ar4中的每一个表示m-联苯基或被芳基取代的联苯基，其余的Ar1至Ar4中的每一个表示联苯基；以及包括该新的芳胺化合物的有机电致发光器件。该有机电致发光器件具有高亮度、优异的耐热性和长寿命，并以高效率发光。该新的芳胺化合物为有机电致发光器件提供了有利的性能。
• MATERIAL FOR ORGANIC ELECTRO-OPTICAL DEVICE HAVING FLUORENE DERIVATIVE COMPOUND AND ORGANIC ELECTRO-OPTICAL DEVICE INCLUDING THE SAME
  申请人：Yu Eun Sun

  公开号：US20100187978A1

  公开（公告）日：2010-07-29

  The present invention relates to a material for an organic electro-optical device and an organic electro-optical device including the same. More particularly, the present invention relates to a material having thermal stability of a glass transition temperature of 120° C. or more and a thermal decomposition temperature of 450° C. or more, and being capable of providing an organic electro-optical device having high efficiency and a long life-span due to less crystallization and improved amorphous properties in a material for an organic electro-optical device. The material for an organic electro-optical device can be used singularly or as a host material in combination with a dopant, and includes an asymmetric fluorene derivative compound. An organic electro-optical device including the material for an organic electro-optical device is also provided.

  本发明涉及一种用于有机电光器件的材料以及包括该材料的有机电光器件。更具体地说，本发明涉及一种具有玻璃转变温度为120°C或更高以及热分解温度为450°C或更高的热稳定性材料，能够提供具有高效率和长寿命的有机电光器件，因为在有机电光器件材料中具有较少的结晶和改善的非晶性能。有机电光器件的材料可以单独使用或作为宿主材料与掺杂剂结合使用，并包括不对称的芴衍生物化合物。还提供了包括该有机电光器件材料的有机电光器件。
• MATERIAL FOR ORGANIC PHOTOELECTRIC DEVICE INCLUDING ELECTRON TRANSPORTING UNIT AND HOLE TRANSPORTING UNIT, AND ORGANIC PHOTOELECTRIC DEVICE INCLUDING THE SAME
  申请人：YU Eun-Sun

  公开号：US20120280221A1

  公开（公告）日：2012-11-08

  A material for an organic photoelectric device, the material including a compound including a pyridine ( ) moiety, the compound being a bipolar organic compound including both a hole transporting unit and an electron transporting unit, the compound being represented by the following Formula 1:

  一种用于有机光电器件的材料，该材料包括一种化合物，其中包括吡啶（）基团，该化合物是一种双极有机化合物，包括载流子传输单元和电子传输单元，该化合物由以下化学式1表示：
• AROMATIC AMINE COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1806334A1

  公开（公告）日：2007-07-11

  An aromatic amine compound of a specific structure having at least one fluorene structure. An organic electroluminescence device which comprises one or more organic thin film layers comprising at least one light emitting layer sandwiched between a cathode and an anode, wherein at least one of the thin film layers comprises the aromatic amine compound according to claim 1 singly or as its mixture component. Such an organic electroluminescence device has various luminescent hues, high heat resistance, long lifetime, high luminance and high luminous efficiency. The above-mentioned novel aromatic amine compound enables to realize such an organic electroluminescence device.

  一种具有至少一个芴结构的特定结构的芳香胺化合物。一种有机电致发光装置，其包括至少一个有机薄膜层，包括夹在阴极和阳极之间的至少一个发光层，其中至少一个薄膜层以权利要求1中的芳香胺化合物单独或作为其混合组分组成。这样的有机电致发光装置具有各种发光色调，高耐热性，长寿命，高亮度和高发光效率。上述新型芳香胺化合物使得实现这样的有机电致发光装置成为可能。
• Aromatic amine derivative and organic electroluminescence device using the same
  申请人：Hosokawa Chishio

  公开号：US20060251925A1

  公开（公告）日：2006-11-09

  To provide an organic electroluminescence device having high emission luminance, high heat resistance, excellent high-temperature storage stability, and a long lifetime, and an aromatic amine derivative for realizing the device. Provided are a novel aromatic amine derivative having a specific structure and an organic electroluminescence device including: a cathode; an anode; and one or multiple organic thin film layers including at least a light-emitting layer, the one or multiple organic thin film layers being interposed between the cathode and the anode, in which at least one layer of the one or multiple organic thin film layers contains the aromatic amine compound alone or as a component of a mixture.

  提供一种具有高发射亮度、高耐热性、优异的高温存储稳定性和长寿命的有机电致发光器件，以及实现该器件的芳香胺衍生物。提供了一种具有特定结构的新型芳香胺衍生物和有机电致发光器件，包括：阴极；阳极；和至少一个有机薄膜层，其中包括至少一个发光层，这些有机薄膜层被夹在阴极和阳极之间，其中至少一个有机薄膜层仅包含芳香胺化合物或作为混合物的组分之一。