11-Oxapentacyclo[6.5.1.13,6.02,7.09,13]pentadec-4-ene-10,12-dione | 53414-07-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 11-Oxapentacyclo[6.5.1.13,6.02,7.09,13]pentadec-4-ene-10,12-dione
• CAS: 53414-07-6
• 化学式: C₁₄H₁₄O₃
• 分子量: 230.26
• InChiKey: CKKGPNARILRMPQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二聚环戊二烯 、 马来酸酐 以 邻二甲苯 为溶剂， 165.0~220.0 ℃ 、1.78 kPa 条件下， 反应 3.0h， 以yielded 30.2 g of tetracyclo[6.2.1.13,6.02,7]dodeca-9-ene-4,5dicarboxylic anhydride的产率得到11-Oxapentacyclo[6.5.1.13,6.02,7.09,13]pentadec-4-ene-10,12-dione
  参考文献：
  名称：

  Polymer and positive type resist composition

  摘要：

  提供了一种技术，使得可以抑制在光刻或显影过程中产生的光阻图案表面粗糙度，或更好地在两个过程之后进行抑制。根据这项技术，使用包括树脂组分（A）的正向光刻胶组合物形成光刻胶图案，该组分包含一个含有内酯的结构单元（a1），如下所示的通式所代表，并在酸的作用下表现出增加的碱溶性（其中，R代表氢原子或甲基基团），酸发生器组分（B）在曝光时产生酸，以及有机溶剂（C）。

  公开号：

  US20060147832A1

文献信息

• METHOD FOR PRODUCING ESTER COMPOUND
  申请人：JX NIPPON OIL & ENERGY CORPORATION

  公开号：US20160102044A1

  公开（公告）日：2016-04-14

  A method for producing an ester compound including reacting a compound having at least one cyclic structure of a norbornene ring and a norbornadiene ring with an alcohol and carbon monoxide by using a palladium catalyst and an oxidizing agent, to thereby introduce ester groups to carbon atoms forming a double bond in the cyclic structure and obtain the ester compound, wherein the palladium catalyst comprises a palladium complex having a bipyridyl as a ligand.

  一种制备酯化合物的方法，包括使用钯催化剂和氧化剂，将至少具有一个环状结构的诺博尔烯环和诺博尔二烯环化合物与醇和一氧化碳反应，从而将酯基引入环状结构中形成双键的碳原子，并获得酯化合物，其中钯催化剂包括以联吡啶为配体的钯配合物。
• METHOD FOR PRODUCING ESTER COMPOUND AND PALLADIUM CATALYST USED IN THE METHOD
  申请人：JX Nippon Oil & Energy Corporation

  公开号：US20150343432A1

  公开（公告）日：2015-12-03

  A method for producing an ester compound includes reacting a compound having at least one cyclic structure of a norbornene ring and a norbornadiene ring with an alcohol and carbon monoxide by using a palladium catalyst and an oxidizing agent, to thereby introduce ester groups to carbon atoms forming a double bond in the cyclic structure and obtaining the ester compound, wherein the palladium catalyst includes a palladium acetate having a nitrite ligand in an amount of 10% by mole or more in terms of metal, and the palladium acetate having a nitrite ligand is represented by the general formula (1): Pd 3 (CH 3 COO) 5 (NO 2 ).

  一种制备酯类化合物的方法，包括使用钯催化剂和氧化剂，通过将至少具有一个环状结构的诺博尔烯环和诺博尔二烯环化合物与醇和一氧化碳反应，从而将酯基引入到环状结构中形成双键的碳原子中，并获得酯类化合物，其中钯催化剂包括具有硝基配体的乙酸钯，其金属量为摩尔数的10％或更多，乙酸钯的硝基配体由通式（1）表示：Pd3（CH3COO）5（NO2）。
• POLAR-GROUP-CONTAINING OLEFIN COPOLYMER, MULTINARY POLAR-GROUP-CONTAINING OLEFIN COPOLYMER, OLEFIN-BASED RESIN COMPOSITION, AND ADHESIVE AND LAYERED PRODUCT COMPRISING SAME
  申请人：Japan Polyethylene Corporation

  公开号：EP2980107A1

  公开（公告）日：2016-02-03

  A polar-group-containing olefin copolymer which comprises 99.999 to 80 mol% of structural units derived from at least one of ethylene and α-olefin having 3 to 20 carbon atoms and 20 to 0.001 mol% of structural units derived from at least one polar-group-containing monomer which contains an epoxy group and is represented by the following structural formula (I) or following structural formula (II), the polar-group-containing olefin copolymer being a random copolymer obtained by copolymerization in the presence of a transition metal catalyst and having a linear molecular structure.

  一种含极性基团的烯烃共聚物，它包含 99.999 至 80 摩尔%的结构单元，这些结构单元至少来自乙烯和具有 3 至 20 个碳原子的 α-烯烃中的一种，以及 20 至 0.001 摩尔%的结构单元，这些结构单元至少来自一种含有环氧基团的含极性基团单体，并由以下结构式(I)或以下结构式(II)表示，该含极性基团的烯烃共聚物是在过渡金属催化剂存在下通过共聚得到的无规共聚物，具有线性分子结构。
• Insulating tape for covering, and method for producing structure
  申请人：AGC Inc.

  公开号：US10304583B2

  公开（公告）日：2019-05-28

  To provide an insulating tape for covering, in which a polyimide film and a fluorinated resin film are laminated with excellent adhesion, and a method for producing a structure, which comprises covering a conductor with such an insulating tape for covering, followed by thermal treatment. The insulating tape for covering, comprises a polyimide film and a fluorinated resin film directly laminated on one or both surfaces of the polyimide film, wherein the fluorinated resin film contains a fluorinated copolymer (A) which has a melting point of from 220 to 320° C. and can be melt-molded and which has at least one type of functional groups selected from the group consisting of carbonyl group-containing groups, hydroxy groups, epoxy groups and isocyanate groups.

  提供一种将聚酰亚胺薄膜和氟化树脂薄膜层压在一起且附着力极佳的包覆用绝缘胶带，以及一种生产结构的方法，该方法包括用这种包覆用绝缘胶带包覆导体，然后进行热处理。覆盖用绝缘胶带包括聚酰亚胺薄膜和直接层压在聚酰亚胺薄膜的一个或两个表面上的氟化树脂薄膜，其中氟化树脂薄膜含有氟化共聚物 (A)，该共聚物的熔点为 220 至 320°C，可熔融成型，并具有至少一种从含羰基、羟基、环氧基和异氰酸酯基组成的组中选出的官能团。
• Nadic anhydride polymers and photosensitive compositions derived therefrom
  申请人：PROMERUS, LLC

  公开号：US10591818B2

  公开（公告）日：2020-03-17

  Various vinyl addition polymers of nadic anhydride are disclosed. Examples of such polymers include copolymers and terpolymers of nadic anhydride with a wide variety of norbornene-type monomers. The nadic anhydride polymers are found to be useful in forming a wide variety of photosensitive compositions, both positive and negative, which are capable of forming high resolution imagable films exhibiting excellent dielectric properties (low-k) and thermal properties, and thus are useful in the fabrication of a variety of microelectronic and optoelectronic devices, among others.

  本文公开了纳丁酸酐的各种乙烯基加成聚合物。此类聚合物的例子包括纳丁酸酐与各种降冰片烯类单体的共聚物和三元共聚物。我们发现萘酸酐聚合物可用于形成各种光敏组合物，包括正性和负性组合物，这些组合物能够形成高分辨率的可成像薄膜，表现出优异的介电性能（低 K 值）和热性能，因此可用于制造各种微电子和光电设备等。