2-methylbicyclo[2.2.1]heptane-2,3-dicarboxylic acid | 28871-70-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 2-methylbicyclo[2.2.1]heptane-2,3-dicarboxylic acid
• CAS: 28871-70-7
• 化学式: C₁₀H₁₄O₄
• 分子量: 198.22
• InChiKey: ICOICHVCIDIDRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

文献信息

• [EN] ASYMMETRIC CYCLIC DIESTER COMPOUNDS<br/>[FR] COMPOSÉS DIESTERS CYCLIQUES ASYMÉTRIQUES
  申请人：FERRO CORP

  公开号：WO2011071674A1

  公开（公告）日：2011-06-16

  Compounds useful as plasticizers and the synthesis thereof are disclosed. In general, the invention includes mixed alkyl/aryl asymmetric cyclic diesters where the aryl and alkyl ester moieties are attached to a cyclic structure at vicinal carbons. The invention also includes synthetic processes of making such compounds. Blends of these asymmetric cyclic diesters with other plasticizers are demonstrated to be of use in plasticizing polymers.

  本文披露了作为增塑剂有用的化合物及其合成方法。一般来说，该发明包括混合烷基/芳基不对称环状二酯，其中芳基和烷基酯基连接到环状结构的邻位碳上。该发明还包括制备这类化合物的合成过程。这些不对称环状二酯与其他增塑剂的混合物被证明在增塑聚合物中具有用途。
• METHOD OF SEPARATING STEREOISOMERS OF NORBORNENE, DICARBOXYLIC ACID HAVING NORBORNANE STRUCTURE, OR DERIVATIVE THEREOF
  申请人：Hitachi Chemical Co., Ltd.

  公开号：EP1669342A1

  公开（公告）日：2006-06-14

  A method of efficiently extracting a high-purity stereoisomer from a mixture comprising the endo isomer and the exo isomer of a dicarboxylic acid having a norbomene or norbomane structure, or a derivative thereof. The present invention relates to a method of separating the endo isomer and the exo isomer of a dicarboxylic acid represented by a general formula (1) or (2) or a derivative thereof, and includes the step of stirring and mixing a mixture comprising mainly the endo isomer of the dicarboxylic acid represented by the general formula (1) or (2) or a derivative thereof, and the exo isomer of the dicarboxylic acid represented by the general formula (1) or (2) or a derivative thereof, with a basic compound and a solvent. (wherein, R1 to R8 represent a hydrogen atom, methyl group, ethyl group, or butyl group), (wherein, R'1 to R'10 represent a hydrogen atom, methyl group, ethyl group, or butyl group)

  一种从包含诺博烯或诺博烷结构的二羧酸的内异构体和外异构体或其衍生物的混合物中高效提取高纯度立体异构体的方法。本发明涉及一种分离由通式（1）或（2）表示的二羧酸的内异构体和外异构体或其衍生物的方法，包括搅拌和混合主要包含由通式（1）或（2）表示的二羧酸的内异构体和由通式（1）或（2）表示的二羧酸的外异构体或其衍生物的混合物与一种碱性化合物和一种溶剂的步骤。（其中，R1至R8代表氢原子，甲基基团，乙基基团或丁基基团），（其中，R'1至R'10代表氢原子，甲基基团，乙基基团或丁基基团）
• THIOL COMPOUNDS, SYNTHESIS METHOD THEREFOR, AND UTILIZATION OF SAID THIOL COMPOUNDS
  申请人：SHIKOKU CHEMICALS CORPORATION

  公开号：US20200369606A1

  公开（公告）日：2020-11-26

  The purpose of the present invention is to provide: novel thiol compounds; a method for synthesizing said thiol compounds; curing agents containing said thiol compounds; resin compositions containing said thiol compounds and an epoxy compound; and resin compositions containing said thiol compounds and an ene compound having a carbon-carbon double bond in a molecule. Furthermore, the purpose of the present invention is to provide adhesives and sealants having these resin compositions as ingredients. The thiol compounds of the present invention are represented by chemical formula (I) to chemical formula (VII).

  本发明的目的是提供：新型硫醇化合物；合成该硫醇化合物的方法；含有该硫醇化合物的固化剂；含有该硫醇化合物和环氧化合物的树脂组合物；以及含有该硫醇化合物和分子中含有碳碳双键的烯烃化合物的树脂组合物。此外，本发明的目的是提供将这些树脂组合物作为成分的粘合剂和密封剂。本发明的硫醇化合物由化学式(I)到化学式(VII)表示。
• Asymmetric Cyclic Diester Compounds
  申请人：Bradshaw John D.

  公开号：US20090312470A1

  公开（公告）日：2009-12-17

  Compounds useful as plasticizers and the synthesis thereof are disclosed. In general, the invention includes mixed alkyl/aryl diesters where the aryl and alkyl ester moieties are attached to a cyclic structure at vicinal carbons. The invention also includes synthetic processes of making such compounds.

  本发明揭示了作为增塑剂有用的化合物及其合成方法。总的来说，该发明包括混合的烷基/芳基二酯，其中芳基和烷基酯基团附着在环状结构上的邻位碳上。该发明还包括制备此类化合物的合成过程。
• RESIN COMPOSITION FOR OPTICAL-SEMICONDUCTOR ENCAPSULATION
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1426394A1

  公开（公告）日：2004-06-09

  A photosemiconductor encapsulating resin composition, excellent in light transmittance, ultraviolet resistance and heat resistance, comprising the following component (A) and component (B): (A): a (meth)acrylic polymer containing an epoxy group, and (B): at least one hardener selected from the group consisting of the following components (b1) to (b4): (b1) a polyvalent carboxylic acid, (b2) a polyvalent carboxylic anhydride, (b3) a reaction product of a polyvalent carboxylic acid with a compound of the following general formula (B-1), and (b4) a reaction product of a polyvalent carboxylic anhydride with a compound of the following general formula (B-2) wherein R1 to R6 represent each independently a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, R3 and R4 may be bonded to form an alkylene group having 1 to 8 carbon atoms; R7 represents an alkylene group; a methylene group contained the alkylene group and the alkyl group represented by R1 to R7 may be substituted by an ether group and/or carbonyl group; Y1 and Y2 represent each independently an oxygen atom, or sulfur atom, is provided.

  一种光半导体封装树脂组合物，具有优异的透光性、抗紫外线性和耐热性，由以下组分（A）和组分（B）组成： (A) 含有环氧基团的（甲基）丙烯酸聚合物，和 (B) 至少一种固化剂，选自以下组份 (b1) 至 (b4)： (b1) 多价羧酸、 (b2) 多价羧酸酐、 (b3) 多价羧酸与下述通式（B-1）化合物的反应产物，和 (b4) 多价羧酸酐与下式通式（B-2）化合物的反应产物 其中 R1 至 R6 各自独立地代表氢原子或具有 1 至 8 个碳原子的烷基，R3 和 R4 可键合形成具有 1 至 8 个碳原子的亚烷基；R7 代表亚烷基；R1 至 R7 所代表的亚烷基和烷基中所含的亚甲基可被醚基和/或羰基取代；Y1 和 Y2 各自独立地代表氧原子或硫原子。