4-Oxatetracyclo[6.2.1.0^{2,7}.0^{3,5}]undecan-10-yl acetate | 2500-84-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 4-Oxatetracyclo[6.2.1.0^{2,7}.0^{3,5}]undecan-10-yl acetate
• 英文别名: 4-oxatetracyclo[6.2.1.02,7.03,5]undecan-10-yl acetate
• CAS: 2500-84-7
• 化学式: C₁₂H₁₆O₃
• 分子量: 208.25
• InChiKey: INYGWUFTISSLHX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• [EN] OXIME ESTER PHOTOINITIATORS<br/>[FR] PHOTOAMORCEURS À BASE D'ESTER D'OXIME
  申请人：BASF SE

  公开号：WO2015036910A1

  公开（公告）日：2015-03-19

  Disclosed are oxime ester compounds which have specific benzo (unsaturated 5-membered ring)-carbonyl group and their use as photoinitiators in photopolymerizable compositions, in particular in photoresist formulations for display applications, e.g. liquid crystal display (LCD), organic light emitting diode (OLED) and touch panel.

  披露的是具有特定苯并（不饱和五元环）-羰基基团的肟酯化合物及其作为光聚合组合物中的光引发剂的使用，特别是在显示应用的抗蚀剂配方中，例如液晶显示（LCD）、有机发光二极管（OLED）和触摸面板。
• [EN] OXIME ESTER PHOTOINITIATORS<br/>[FR] PHOTOINITIATEURS D'ESTER D'OXIME
  申请人：BASF SE

  公开号：WO2013083505A1

  公开（公告）日：2013-06-13

  Oxime ester compounds of formula (I), wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 independently of each other are hydrogen, C1-C20alkyl, (A),COR14, NO2, or OR15; provided that at least one of R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 is (A), and provided that at |east one of the remaining R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 is COR14 or NO2; R11 is for example C1-C20alkyl, M or (B); X and X1 are for example a direct bond; R12 and R'12 are for example hydrogen or C1-C20alkyl; R13 and R'13 are for example C6-C20aryl or C3-C20heteroaryl; M is (X), (Y) or (Z); X3 is O, S or NR19; R14 and R15 are for example phenyl; R20, R21 , R22, R23, R24, or R25 for example are hydrogen, COR14, NO2, or (B); provided that at least two oxime ester groups are present in the molecule; are useful as photoinitiators.

  氧化酮酯化合物的化学式（I），其中R1、R2、R3、R4、R5、R6、R7、R8、R9和R10彼此独立地为氢、C1-C20烷基、（A）、COR14、NO2或OR15；但要求R1、R2、R3、R4、R5、R6、R7、R8、R9和R10中至少有一个是（A），并且剩余的R1、R2、R3、R4、R5、R6、R7、R8、R9和R10中至少有一个是COR14或 ；R11例如是C1-C20烷基、M或（B）；X和X1例如是直接键；R12和R'12例如是氢或C1-C20烷基；R13和R'13例如是C6-C20芳基或C3-C20杂环芳基；M是（X）、（Y）或（Z）；X3是O、S或NR19；R14和R15例如是苯基；R20、R21、R22、R23、R24或R25例如是氢、COR14、 或（B）；要求分子中至少有两个氧化酮酯基团存在；可用作光引发剂。
• [EN] OXIME ESTER PHOTOINITIATORS<br/>[FR] PHOTOINITIATEURS À BASE D'ESTER D'OXIME
  申请人：BASF SE

  公开号：WO2015004565A1

  公开（公告）日：2015-01-15

  Compounds of the formula (I) n, wherein Q is a direct bond or an n-valent linking group; n is an integer 2, 3, or 4; Z is for example C1-C20alkylene, C2-C20alkenylene,C5-C8 cycloalkylene or C5-C8 cycloalkenylene; Y is for example C6-C20aryl or C3-C20heteroaryl; R1 is for example hydrogen, C2-C5alkenyl, C3-C8cycloalkyl, C1-C12alkyl, phenyl, naphthyl, C3-C20heteroaryl, C1-C8alkoxy, benzyloxy or phenoxy; R2 is for example C1-C20alkyl, C2-C12alkenyl, C4-C8cycloalkenyl, C2-C12alkinyl, C3-C10cycloalkyl, phenyl or naphthyl; R15, R16, R17, R18, R19 and R20 independently of each other for example are hydrogen, halogen, C1-C20alkyl, C6-C20aryl or C4-C20heteroaryl; provided that a compound wherein R15, R16, R17, R18, R19 and R20 are hydrogen, Y is thienyl, R1 is methyl, R2 is ethyl, n is 2, Q is a direct bond and Z is n-propylene and a compound wherein R15, R16, R17, R18, R19 and R20 are hydrogen, Y is thienyl, R1 is methyl, R2 is ethyl, n is 2, Q as an n-valent linking group is methylene and Z is methylene are excluded; are reactive photoinitiators in particular in electronic applications.

  化合物的公式（I）n，其中Q是直接键或n价键合基团；n是整数2、3或4；Z例如是C1-C20烷基，C2-C20烯基，C5-C8环烷基或C5-C8环烯基；Y例如是C6-C20芳基或C3-C20杂环芳基；R1例如是氢，C2-C5烯基，C3-C8环烷基，C1-C12烷基，苯基，萘基，C3-C20杂环芳基，C1-C8烷氧基，苄氧基或苯氧基；R2例如是C1-C20烷基，C2-C12烯基，C4-C8环烯基，C2-C12炔基，C3-C10环烷基，苯基或萘基；R15、R16、R17、R18、R19和R20彼此独立地例如是氢，卤素，C1-C20烷基，C6-C20芳基或C4-C20杂环芳基；前提是化合物中R15、R16、R17、R18、R19和R20为氢，Y为噻吩基，R1为甲基，R2为乙基，n为2，Q为直接键，Z为n-丙烯基和化合物中R15、R16、R17、R18、R19和R20为氢，Y为噻吩基，R1为甲基，R2为乙基，n为2，Q作为n价键合基团为亚甲基，Z为亚甲基被排除；在特定电子应用中是具有反应性的光引发剂。
• PHOTORESIST COMPOSITION
  申请人：BASF SE

  公开号：EP2411430B1

  公开（公告）日：2015-10-14
• OXIME ESTER PHOTOINITIATORS
  申请人：BASF SE

  公开号：EP2303833B1

  公开（公告）日：2013-10-16