N,N,N’,N’-四(对氨基苯基)对苯二胺 | 3283-07-6

• 物质功能分类: 有机原料 - 氨基化合物
• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N,N,N’,N’-四(对氨基苯基)对苯二胺
• 中文别名: N,N,N',N'-四(对氨基苯基)对苯二胺；N,N,N',N'-四(4-氨基苯基)-1,4-苯二胺；四(4-氨基苯)-1,4苯二胺；N,N,N",N"-四(对氨基苯基)对苯二胺
• 英文名称: N,N,N’,N’-tetrakis (4-amino-phenyl)-1,4-phenylenediamine
• 英文别名: N,N,N',N'-tetrakis(4-aminophenyl)-1,4-benzenediamine；N,N,N',N'-Tetrakis(4-aminophenyl)-1,4-phenylenediamine；4-N-[4-(4-amino-N-(4-aminophenyl)anilino)phenyl]-4-N-(4-aminophenyl)benzene-1,4-diamine
• CAS: 3283-07-6
• 化学式: C₃₀H₂₈N₆
• mdl: MFCD06657652
• 分子量: 472.593
• InChiKey: LVPYYSKDNVAARK-UHFFFAOYSA-N

物化性质

• 熔点：
  >300°C
• 沸点：
  765.6±60.0 °C(Predicted)
• 密度：
  1.309
• 溶解度：
  溶于DMSO、DMF 不溶于甲醇和水

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  111
• 氢给体数：
  4
• 氢受体数：
  6

安全信息

• 安全说明：
  S22,S36/37/39
• 危险类别码：
  R20/21/22
• 海关编码：
  2921590090
• 危险性防范说明：
  P280,P305+P351+P338
• 危险性描述：
  H302
• 储存条件：
  存于室温、干燥且密封的环境。

SDS

Material Safety Data Sheet

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Section 1. Identification of the substance
Product Name: N,N,N’,N’-Tetrakis(4-aminophenyl)-1,4-phenylenediamine
Synonyms:

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Section 2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.

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Section 3. Composition/information on ingredients.
Ingredient name: N,N,N’,N’-Tetrakis(4-aminophenyl)-1,4-phenylenediamine
CAS number: 3283-07-6

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Section 4. First aid measures
Skin contact: Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact: Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation: Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion: Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

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Section 5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

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Section 6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution: Wear approved mask/respirator
Hand precaution: Wear suitable gloves/gauntlets
Skin protection: Wear suitable protective clothing
Eye protection: Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

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Section 7. Handling and storage
Handling: This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Store in closed vessels.
Storage:

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Section 8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

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Section 9. Physical and chemical properties
Appearance: Not specified
Boiling point: No data
No data
Melting point:
Flash point: No data
Density: No data
Molecular formula: C30H28N6
Molecular weight: 472.6

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Section 10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, nitrogen oxides.

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Section 11. Toxicological information
No data.

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Section 12. Ecological information
No data.

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Section 13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

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Section 14. Transportation information
Non-harzardous for air and ground transportation.

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Section 15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  N,N,N’,N’-四(对氨基苯基)对苯二胺 在 palladium on activated charcoal 氢气 作用下， 以 甲苯 为溶剂， 反应 7.0h， 生成
  参考文献：
  名称：

  NEAR-INFRARED ABSORPTIVE COLORING MATTER AND NEAR-INFRARED ABSORPTIVE COMPOSITION

  摘要：

  本发明的目的是提供一种近红外吸收染料，能够提供具有优异透明性、高耐热性和耐潮湿性的近红外屏蔽滤光片。该近红外吸收染料的特点在于它是由式（1）所表示的二氢铵盐的非晶态形式制成的。

  公开号：

  US20120251831A1
• 作为产物：
  描述：

  N,N,N',N'-四(对硝基苯基)对苯二胺 在 palladium 10% on activated carbon 、 一水合肼 作用下， 以 1,4-二氧六环 、 乙醇 为溶剂， 反应 36.25h， 以50%的产率得到N,N,N’,N’-四(对氨基苯基)对苯二胺
  参考文献：
  名称：

  Ultrastable tetraphenyl-p-phenylenediamine-based covalent organic frameworks as platforms for high-performance electrochemical supercapacitors

  摘要：

  在这项研究中，我们合成了两种基于四苯基-p-苯二胺的共价有机框架(TPPDA-TPPyr 和 TPPDA-TPTPE COF)，以便在高性能电化学超级电容器中进行潜在应用。

  DOI：

  10.1039/c9cc08107k

文献信息

• NEAR-INFRARED ABSORBING DYE, NEAR-INFRARED ABSORPTIVE FILM-FORMING COMPOSITION, AND NEAR-INFRARED ABSORPTIVE FILM
  申请人：OHASHI Masaki

  公开号：US20120119171A1

  公开（公告）日：2012-05-17

  A near-infrared absorbing dye has an anion of formula (1) wherein A 1 is H or CF 3 , R 0 is OH or —OC(═O)—R′, and R′ is a monovalent hydrocarbon group. The dye has excellent solvent solubility as well as good optical properties and heat resistance, offering the advantages of easy coating and effective working during film formation. The dye free of heavy metal in its structure is advantageously used in the process of fabricating semiconductor devices.

  一种近红外吸收染料具有如下式（1）的阴离子，其中A1为H或CF3，R0为OH或—OC(═O)—R′，而R′为一价碳氢基团。该染料具有优异的溶剂溶解性以及良好的光学性能和耐热性，提供易于涂覆和在薄膜形成过程中有效工作的优点。该染料在其结构中不含重金属，因此在制造半导体器件的过程中具有优势应用。
• STABLE, WATER-SOLUBLE NEAR INFRARED DYES
  申请人：Cohen Murray S.

  公开号：US20090236571A1

  公开（公告）日：2009-09-24

  The synthesis of stable, water-soluble tris and tetrakis aminium dyes. More particularly, carboxylic-acid modified tris and tetrakis dye intermediates, as well as salts and near-infrared dyes formed therefrom, as well as compositions including the dyes.

  稳定的、水溶性三胺和四胺染料的合成。更具体地说，是羧酸修饰的三胺和四胺染料中间体，以及由此形成的盐和近红外染料，以及包含这些染料的组合物。
• Diimmonium-based component and near infrared absorption filter using same
  申请人：Kang Ju-Sik

  公开号：US09158048B2

  公开（公告）日：2015-10-13

  Disclosed are a novel diimmonium-based compound that has low light absorption in visible light region and has superior light absorption efficiency in near infrared region, and has superior durability and weatherability, and a near infrared absorption filter using the same. The diimmonium-based compound is represented by the formula 1 of claim 1.

  本发明公开了一种新型的双铵基化合物，该化合物在可见光区域具有低的光吸收率，在近红外区域具有优异的光吸收效率，并具有优异的耐久性和耐候性，以及使用该化合物的近红外吸收滤光片。该双铵基化合物由权利要求1的公式1表示。
• Strongly Reducing (Diarylamino)benzene-Based Covalent Organic Framework for Metal-Free Visible Light Photocatalytic H₂O₂ Generation
  作者：Chidharth Krishnaraj、Himanshu Sekhar Jena、Laurens Bourda、Andreas Laemont、Pradip Pachfule、Jérôme Roeser、C. Vinod Chandran、Sander Borgmans、Sven M. J. Rogge、Karen Leus、Christian V. Stevens、Johan A. Martens、Veronique Van Speybroeck、Eric Breynaert、Arne Thomas、Pascal Van Der Voort

  DOI：10.1021/jacs.0c09684

  日期：2020.11.25

  with high charge transfer kinetics. Covalent organic frameworks (COFs) are an emerging class of photoactive semiconductors, tunable at a molecular level for high charge carrier generation and transfer. Herein, we report two newly designed two-dimensional COFs based on a (diarylamino)benzene linker that form a Kagome (kgm) lattice and show strong visible light absorption. Their high crystallinity and large

  分子氧的光催化还原是可持续生产过氧化氢 (H2O2) 的一条有前途的途径。这个具有挑战性的过程需要光敏半导体，以实现太阳能驱动的生成以及具有高电荷转移动力学的电子和空穴的分离。共价有机骨架 (COF) 是一类新兴的光敏半导体，可在分子水平上进行调节，以产生和转移高电荷载流子。在此，我们报告了两种新设计的基于（二芳基氨基）苯连接体的二维 COF，它们形成 Kagome (kgm) 晶格并显示出强烈的可见光吸收。它们的高结晶度和大表面积（高达 1165 m2·g–1）允许有效的电荷转移和扩散。二芳基胺（供体）单元具有很强的还原性能，使这些 COF 能够有效地减少氧气以形成 。总体而言，使用无金属、可回收的光催化系统可以实现高效的光催化太阳能转化。
• METHOD OF PRODUCING NEAR-INFRARED ABSORBING DYE COMPOUND
  申请人：Kimura Keizo

  公开号：US20070055071A1

  公开（公告）日：2007-03-08

  A method of producing a near-infrared absorbing dye compound, useful for image forming materials, infrared heat-sensitive recording devices, optical film materials, and the like, containing a process of reacting a compound represented by formula (I) with halogenating agent. wherein R 111 , R 112 , R 121 , R 122 , R 131 , R 132 , R 141 and R 142 each independently represent a hydrogen atom, an aliphatic group or an aromatic group; R 103 , R 113 , R 123 , R 133 and R 143 each independently represent a substituent; and n 103 , n 113 , n 123 , n 133 and n 143 each independently denote an integer from 0 to 4.

  一种生产近红外吸收染料化合物的方法，该方法适用于图像形成材料、红外热敏记录装置、光学薄膜材料等领域，包括通过卤化试剂反应式（I）所表示的化合物的过程。其中，R111、R112、R121、R122、R131、R132、R141和R142各自独立地表示氢原子、脂肪基或芳香基；R103、R113、R123、R133和R143各自独立地表示取代基；n103、n113、n123、n133和n143各自独立地表示0至4的整数。