3,3-Dimethyl-5-phenylpent-1-ene | 61142-18-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3-Dimethyl-5-phenylpent-1-ene
• 英文别名: 3,3-dimethyl-5-phenyl-1-pentene；(3,3-dimethylpent-4-en-1-yl)benzene；3,3-Dimethyl-5-phenyl-1-penten；3,3-dimethylpent-4-enylbenzene
• CAS: 61142-18-5
• 化学式: C₁₃H₁₈
• 分子量: 174.286
• InChiKey: ISMIOTYQFKQVBV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2902909090

反应信息

• 作为反应物：
  描述：

  硝酸 、 溶剂黄146 、 3,3-Dimethyl-5-phenylpent-1-ene 、 在 乙醚 、 碳酸氢钠 、 magnesium sulfate 作用下， 以 乙酸酐 为溶剂， 反应 12.0h， 以providing the product as a yellow oil in 97% yield (55.95 g)的产率得到2-(3,3-dimethylpent-4-enyl)nitrobenzene
  参考文献：
  名称：

  Imido-tethered carbenes of molybdenum for ring-opening metathesis polymerization and ring-closing metathesis

  摘要：

  本文描述了用于催化开环寡聚物化剂和环闭合寡聚物化剂的烯烃的环开合交换反应的化合物和过程。该化合物是一种钼或钨金属(M)配合物，包括一个亚胺配体(N—R)与M结合形成M=N—R位点，一个M=C反应位点，其中M=C反应位点的C通过一个含有1到12个碳原子的碳链或碳和杂原子(NOS)链与亚胺配体的R相连形成环状结构，并且还包括两到四个配体(R′)与M结合形成两到四个M-R′位点。在特定实施例中，M-R′位点包括与M结合的双烷氧基配体的每个氧原子或η1-吡咯配体的每个氮原子。

  公开号：

  US07250523B2
• 作为产物：
  描述：

  苯乙烯 、 magnesium,2-methylbut-2-ene,chloride 生成 3,3-Dimethyl-5-phenylpent-1-ene
  参考文献：
  名称：

  Lehmkuhl,H. et al., Justus Liebigs Annalen der Chemie, 1975, p. 1176 - 1192

  摘要：

  DOI：

文献信息

• Palladium-Catalyzed Electrochemical Allylic Alkylation between Alkyl and Allylic Halides in Aqueous Solution
  作者：Yin-Long Lai、Jing-Mei Huang

  DOI：10.1021/acs.orglett.7b00473

  日期：2017.4.21

  A new route for the direct cross-coupling of alkyl and allylic halides using electrochemical technique has been developed in aqueous media under air. Catalyzed by Pd(OAc)2, the Zn-mediated allylic alkylations proceed smoothly between a full range of alkyl halides (primary, secondary, and tertiary) and substituted allylic halides. Protection–deprotection of acidic hydrogen in the substrates is avoided

  在空气中的水性介质中，已经开发出了一种使用电化学技术直接交叉偶联烷基卤化物和烯丙基卤化物的新途径。在Pd（OAc）2的催化下，Zn介导的烯丙基烷基化反应在各种烷基卤化物（伯，仲和叔）和取代的烯丙基卤化物之间平稳进行。避免了底物中酸性氢的保护-去保护。
• Synthesis and structure of an imido-tethered Schrock carbene of molybdenumElectronic supplementary information (ESI) available: Synthetic details for the generation of 2-(3,3-dimethypent-4-enyl)aniline (1) and the tethered molybdenum carbene 4. Tables for the X-ray diffraction study on 4. See http://www.rsc.org/suppdata/dt/b3/b311320p/
  作者：James T. Ciszewski、Baohan Xie、Changsheng Cao、Aaron L. Odom

  DOI：10.1039/b311320p

  日期：——

  An 8-membered molybdenum azametallacycle, where a MoC bond and a MoN bond are linked, incorporating two triflate co-ligands has been synthesized and structurally characterized.

  我们合成了一种 8 元钼叠氮金属环，其中连接着一个 MoC 键和一个 MoN 键，并包含两个三late 共配位体，其结构特征已被确定。
• A convenient coupling reaction of allyl alcohols with grignard reagents using 1-chloro-2-methyl-N,N-tetramethylenepropenylamine
  作者：Tamotsu Fujisawa、Sachio Iida、Hisashi Yukizaki、Toshio Sato

  DOI：10.1016/s0040-4039(00)94190-x

  日期：1983.1

  1-Chloro-2-methyl-N,N-tetramethylenepropenylamine was found to be a good condensation reagent for a regioselective coupling reaction of allyl alcohols with Grignard reagents under mild conditions to afford olefinic products.

  发现1-氯-2-甲基-N，N-四亚甲基丙烯胺是良好的缩合试剂，用于烯醇与格氏试剂在温和条件下的区域选择性偶联反应，得到烯烃产物。
• The direct formation of functionalized alkyl(aryl)zinc halides by oxidative addition of highly reactive zinc with organic halides and their reactions with acid chlorides, .alpha.,.beta.-unsaturated ketones, and allylic, aryl, and vinyl halides
  作者：Lishan Zhu、Richard M. Wehmeyer、Reuben D. Rieke

  DOI：10.1021/jo00004a021

  日期：1991.2

  Highly reactive zinc, prepared by the lithium naphthalenide reduction of ZnCl2, readily undergoes oxidative addition to alkyl, aryl, and vinyl halides under mild conditions to generate the corresponding organozinc compounds in excellent yields. Significantly, the reaction will tolerate a spectrum of functional groups on the organic halides. Accordingly, this approach can now be used to prepare a wide variety of highly functionalized organozinc compounds. In the presence of Cu(I) salts, the organozinc compounds cross-couple with acid chlorides, conjugatively add to alpha,beta-unsaturated ketones, and regioselectively undergo S(N)2' substitution reactions with allylic halides. They also cross-couple with aryl or vinyl halides with Pd(0) catalysts.
• FUJISAWA, TAMOTSU;IIDA, SACHIO;YUKIZAKI, HISASHI;SATO, TOSHIO, TETRAHEDRON LETT., 1983, 24, N 51, 5745-5748
  作者：FUJISAWA, TAMOTSU、IIDA, SACHIO、YUKIZAKI, HISASHI、SATO, TOSHIO

  DOI：——

  日期：——