N,N’’-(亚甲基二-4,1-亚苯基)二(N’,N’-二甲基脲) | 10097-09-3

• 物质功能分类: 有机原料 - 氨基化合物 - 酰胺类化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: N,N’’-(亚甲基二-4,1-亚苯基)二(N’,N’-二甲基脲)
• 中文别名: N,N""-(亚甲基二-4,1-亚苯基)二(N",N"-二甲基脲)
• 英文名称: 4,4'-Bis-(3,3-dimethylureido)diphenylmethan
• 英文别名: Urea, N,N''-(methylenedi-4,1-phenylene)bis[N',N'-dimethyl-；3-[4-[[4-(dimethylcarbamoylamino)phenyl]methyl]phenyl]-1,1-dimethylurea
• CAS: 10097-09-3
• 化学式: C₁₉H₂₄N₄O₂
• mdl: MFCD00025667
• 分子量: 340.425
• InChiKey: MOAPNXVHLARBNQ-UHFFFAOYSA-N

物化性质

• 熔点：
  345 °C
• 沸点：
  595.5±50.0 °C(Predicted)
• 密度：
  1.204±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.263
• 拓扑面积：
  64.7
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• PREPREG AND CARBON FIBER-REINFORCED COMPOSITE MATERIAL
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20150210813A1

  公开（公告）日：2015-07-30

  A prepreg includes; sizing agent-coated carbon fibers coated with a sizing agent; and a thermosetting resin composition impregnated into the sizing agent-coated carbon fibers. The sizing agent includes an aliphatic epoxy compound (A) and an aromatic compound (B) at least containing an aromatic epoxy compound (B1). The thermosetting resin composition includes a thermosetting resin (D) and a latent hardener (E), and optionally includes an additive (F) other than the thermosetting resin (D) and the latent hardener (E). The (a)/(b) ratio is within a predetermined range where (a) is the height of a component at a binding energy assigned to CHx, C—C, and C═C and (b) is the height of a component at a binding energy assigned to C—O in a C 1s core spectrum of the surfaces of the sizing agent-coated carbon fibers analyzed by X-ray photoelectron spectroscopy.

  预浸料包括：涂有分散剂的碳纤维，涂有分散剂；以及浸渍在涂有分散剂的碳纤维中的热固性树脂组合物。分散剂包括脂肪族环氧化合物（A）和至少含有芳香族环氧化合物（B1）的芳香族化合物（B）。热固性树脂组合物包括热固性树脂（D）和潜在硬化剂（E），并且可选地包括除热固性树脂（D）和潜在硬化剂（E）以外的添加剂（F）。在由X射线光电子能谱分析的涂有分散剂的碳纤维表面的C1s光谱中，（a）是分配给CHx，C-C和C═C的结合能的组分高度，（b）是分配给C-O的结合能的组分高度，（a）/（b）比值在预定范围内。
• PREPREG AND CARBON FIBER REINFORCED COMPOSITE MATERIAL
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20150252184A1

  公开（公告）日：2015-09-10

  To provide a prepreg and a carbon fiber reinforced composite material that are excellent in adhesion between a matrix resin and carbon fibers and long-term storage stability and also excellent in microcrack resistance due to the increased toughness. The present invention provides a prepreg that includes; agent-coated carbon fibers coated with a sizing agent; and a thermosetting resin composition impregnated into the sizing agent-coated carbon fibers. The sizing agent includes an aliphatic epoxy compound (A) and an aromatic epoxy compound (B1). The sizing agent-coated carbon fibers are in a shape of woven fabric or braid. The thermosetting resin composition includes a thermosetting resin (D), a thermoplastic resin (F), and a latent hardener (G). The sizing agent-coated carbon fibers have an (a)/(b) ratio in a certain range where (a) is the height of a component at a binding energy assigned to CHx, C—C, and C═C and (b) is the height of a component at a binding energy assigned to C—O in a C 1s core spectrum of the surfaces of the sizing agent-coated carbon fibers analyzed by X-ray photoelectron spectroscopy.

  提供一种预浸料和碳纤维增强复合材料，其在基体树脂和碳纤维之间具有优异的附着性和长期储存稳定性，并且由于增加韧性而具有优异的微裂纹抗性。本发明提供一种预浸料，其包括：涂有分散剂的碳纤维；以及浸渍在涂有分散剂的碳纤维中的热固性树脂组合物。分散剂包括脂肪族环氧化合物（A）和芳香族环氧化合物（B1）。涂有分散剂的碳纤维呈编织物或编织带状。热固性树脂组合物包括热固性树脂（D）、热塑性树脂（F）和潜在硬化剂（G）。涂有分散剂的碳纤维在X射线光电子能谱分析的表面C1s谱中，具有（a）在分配给CHx、C—C和C═C的结合能处的组分高度和（b）在分配给C—O的结合能处的组分高度之间的（a）/（b）比率在一定范围内。
• Resin particle-filled, fiber-reinforced composites
  申请人：AMOCO CORPORATION

  公开号：EP0351028A2

  公开（公告）日：1990-01-17

  Layered, fiber-reinforced composites comprising a cycloaliphatic epoxy resin matrix and continuous fiber are toughened by including a resinous particulate modifier in said matrix resin within the inter-ply spacing of the layered composite. The method of the invention is particularly effective in providing composite structures having a marked improvement in toughness over similar composites based on other epoxy resins.

  通过在层状复合材料的层间距内的基体树脂中加入树脂微粒改性剂，可对由环脂族环氧树脂基体和连续纤维组成的层状纤维增强复合材料进行增韧。与基于其他环氧树脂的类似复合材料相比，本发明的方法在提供韧性明显改善的复合材料结构方面特别有效。
• Prepreg with improved room temperature storage stability
  申请人：AMOCO CORPORATION

  公开号：EP0484632A2

  公开（公告）日：1992-05-13

  Prepreg comprising structural fiber and matrix resin formulated from epoxys selected from the group consisting of polyglycidyl ethers of polycyclic bridged hydroxy-substituted polyaromatic compounds and N,N,N',N'-tetraglycidyl-bis(4-amino-3-ethylphenyl) methane with from about 6 to about 150 pbw, per hundred parts by weight of the epoxy resin components, of a solid aromatic diamine hardener insoluble in said composition in an amount effective to cure said epoxy resin exhibiting improved storage stability characteristics at room temperature.

  预浸料，由结构纤维和基体树脂配制而成，环氧树脂选自多环桥接羟基取代的多芳香族化合物的聚缩水甘油醚和 N,N,N',N'-四raglycidyl-bis(4-amino-3-ethylphenyl)methane、以每百份环氧树脂组分重量计，加入不溶于所述组合物的固体芳香族二胺固化剂，其有效用量可固化所述环氧树脂，使其在室温下具有更好的储存稳定性。
• EPOXY RESIN COMPOSITION FOR CARBON-FIBER-REINFORCED COMPOSITE MATERIAL, PREPREG, INTEGRATED MOLDING, SHEET OF FIBER-REINFORCED COMPOSITE MATERIAL AND CABINET FOR ELECTRICAL/ELECTRONIC EQUIPMENT
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP1731553A1

  公开（公告）日：2006-12-13

  The present invention provides a light-weight fiber-reinforced composite material that has excellent flame retardance and mechanical properties and never emits a halogen gas. The present invention also provides a prepreg and en epoxy resin composition suited to obtain the above described fiber-reinforced composite material. The present invention also provides an integrated molding which is produced using the above described fiber-reinforced composite material, thereby suitable for use in electric/electronic casings. The epoxy resin composition is such that it contains the following components [A], [B] and [C]: [A] epoxy resin, [B] amine curing agent, and [C] phosphorus compound, wherein the concentration of the component [C] is 0.2 to 15% by weight in terms of phosphorus atom concentration.

  本发明提供了一种轻质纤维增强复合材料，该材料具有优异的阻燃性和机械性能，并且不会释放卤素气体。本发明还提供了一种适用于获得上述纤维增强复合材料的预浸料和环氧树脂组合物。本发明还提供了一种使用上述纤维增强复合材料生产的集成模塑，从而适用于电气/电子外壳。环氧树脂组合物包含以下组分[A]、[B]和[C]： [A] 环氧树脂、 [B] 氨基固化剂，和 [C] 磷化合物、 其中，以磷原子浓度计，组分[C]的浓度为 0.2%至 15%（按重量计）。