Hexylcyclobutane | 126832-03-9

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 英文名称: Hexylcyclobutane
• CAS: 126832-03-9
• 化学式: C₁₀H₂₀
• 分子量: 140.269
• InChiKey: YOCAUDPGVDLKLW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  辛烯 、 3-氯丙烯 在 二氯二茂锆 bis(acetylacetonato)palladium(II) 、 三乙基铝 、 三苯基膦 作用下， 生成 Hexylcyclobutane
  参考文献：
  名称：

  A new method for the synthesis of monoalkyl-substituted cyclobutanes

  摘要：

  DOI：

  10.1007/bf00957813

文献信息

• Joint cycloalumination of ethylene and other unsaturated compounds with EtAlCl2 in the presence of Cp2ZrCl2. Synthesis of aluminacarbocycles
  作者：A. G. Ibragimov、L. O. Khafizova、L. I. Khusainova、T. V. Tyumkina、U. M. Dzhemilev

  DOI：10.1134/s1070428010040032

  日期：2010.4

  A procedure has been developed for the selective synthesis of five-membered aluminum-containing heterocycles, 2,3-dialkyl-1-ethylaluminacyclopent-2-enes, 3-alkyl-1-ethylaluminacyclopentanes, 2-alkylidene-1-ethylaluminacyclopentanes, and 3-alkyl-1-ethyl-2-methylidenealuminacyclopentanes, via joint cycloalumination of ethylene and other unsaturated compounds (acetylenes, olefins, and allenes) with EtAlCl2 in the presence of Cp2ZrCl2 as catalyst.
• Regio- and stereoselective synthesis for a novel class of organoaluminium compounds — substituted aluminacyclopentanes and aluminacyclopentenes assis
  作者：U.M. Dzhemilev、A.G. Ibragimov

  DOI：10.1016/0022-328x(94)88022-0

  日期：1994.2

  A novel regio- and stereoselective method has been developed for the catalytic cyclometallation of olefins and acetylenes with alkylalanes in the presence of Cp(2)ZrCl(2), to give in one stage high yields of 3-substituted aluminacyclopentanes and aluminacyclopentenes. Applications of these reactions to a wide range of linear and cyclic olefins and to those containing functional substituents have been studied. The transformation of the aluminacyclopentanes thus produced, into five-membered heterocycles, mono- and di-substituted cyclobutanes and cyclopropanes, has been demonstrated.
• DZHEMILEV, U. M.;IBRAGIMOV, A. G.;ZOLOTAREV, A. P.;MUSLUXOV, R. R.;TOLSTI+, IZV. AN CCCP. CEP. XIM.,(1989) N, S. 2152
  作者：DZHEMILEV, U. M.、IBRAGIMOV, A. G.、ZOLOTAREV, A. P.、MUSLUXOV, R. R.、TOLSTI+

  DOI：——

  日期：——
• A new method for the synthesis of monoalkyl-substituted cyclobutanes
  作者：U. M. Dzhemilev、A. G. Ibragimov、A. P. Zolotarev、R. R. Muslukhov、G. A. Tolstikov

  DOI：10.1007/bf00957813

  日期：1989.9