Spiro[3-oxatricyclo[3.2.1.02,4]octane-6,2'-oxirane] | 5628-76-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Spiro[3-oxatricyclo[3.2.1.02,4]octane-6,2'-oxirane]
• CAS: 5628-76-2
• 化学式: C₈H₁₀O₂
• 分子量: 138.16
• InChiKey: GEIDOFPJIIHSCE-UHFFFAOYSA-N

物化性质

• 沸点：
  56 °C(Press: 0.9 Torr)
• 密度：
  1.36±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.1
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• AROMATIC AMINE COMPOUND, CURING AGENT FOR EPOXY COMPOUND, CURABLE COMPOSITION, CURED PRODUCT, METHOD FOR PRODUCING CURED PRODUCT, AND METHOD FOR PRODUCING AROMATIC AMINE COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20210130284A1

  公开（公告）日：2021-05-06

  An aromatic amine compound capable of satisfactorily forming a cured product having exceptional alkali resistance by reaction with an epoxy compound; a curing agent for an epoxy compound, the curing agent including the aromatic amine compound; a curable composition including the curing agent for an epoxy compound; a cured product of the curable composition; a method for producing the cured product; and a method for producing the abovementioned aromatic amine compound. The aromatic amine compound has a structure such that a specific position in a central skeleton comprising a fused ring such as a fluorene ring is substituted with a side-chain group including two aromatic groups linked by a flexible bond such as an amide bond, at least one amino group is bonded to the end of the side-chain group, and the structure has no hydroxyl groups.

  一种芳香胺化合物，通过与环氧化合物反应能够满意地形成具有异常碱性抗性的固化产品；一种环氧化合物的固化剂，该固化剂包括芳香胺化合物；一种包括环氧化合物的固化剂的可固化组合物；可固化组合物的固化产品；生产所述固化产品的方法；以及生产上述芳香胺化合物的方法。该芳香胺化合物具有这样的结构，即中心骨架中的特定位置包括类似于芴环的融合环，该位置被取代为包括通过柔性键（如酰胺键）连接的两个芳香基的侧链基团，至少一个氨基固定在侧链基团的末端，并且该结构不含羟基。
• CURABLE COMPOSITION, CURED PRODUCT, AND COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20220177641A1

  公开（公告）日：2022-06-09

  a curable composition that gives a cured product exhibiting a high refractive index and a surface without defects such as roughness or cracks, a cured product of the composition, and a compound that may be blended to the composition. In a curable composition including a triazine compound having three aromatic-ring-containing groups each bonded to the triazine ring via an amino group, an aromatic-ring-containing group having a specific structure having a radically polymerizable group-containing group or a cationically polymerizable group-containing group is used as at least one of the three aromatic-ring-containing groups bonded to the triazine ring in the triazine compound mentioned above.

  一种可治愈的组合物，可产生具有高折射率和表面无缺陷（如粗糙或裂纹）的固化产品，该组合物的固化产品以及可混合到该组合物中的化合物。在包括三嗪化合物的可固化组合物中，每个含有芳香环的基团均通过氨基与三嗪环结合，具有特定结构的含芳香环基团具有具有自由基聚合基团或阴离子聚合基团的群组，至少用作上述三嗪化合物中与三嗪环结合的三个芳香环含基团之一。
• Photocurable resin composition and resin composition for plastics comprising the same
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1630215A2

  公开（公告）日：2006-03-01

  A photocurable resin composition comprises a cationic polymerizable compound (A), an acrylic resin (B) and a cationic photopolymerization initiator (C), in which the acrylic resin (B) has a cationic polymerizable functional group, and the content of the component (A) is 30 to 95 parts by mass and the content of the component (B) is 5 to 70 parts by mass, based on 100 parts by mass of the total amount of the components (A) and (B). In addition, the functional group of the acrylic resin (B) preferably contains at least one of a cyclic ether group, a vinyloxy group, an acid adduct of a vinyloxy group, and an active hydrogen group, with the active hydrogen group being a hydroxyl group is more preferable. The photocurable resin composition which has sufficient curability and sufficient adhesiveness to rigid plastics such as polycarbonate and PET having poor adhesive property.

  一种光固化树脂组合物包括阳离子可聚合化合物 (A)、丙烯酸树脂 (B) 和阳离子光聚合引发剂 (C)，其中丙烯酸树脂 (B) 具有阳离子可聚合官能团，以组分 (A) 和 (B) 总量的 100 重量份为基准，组分 (A) 的含量为 30 至 95 重量份，组分 (B) 的含量为 5 至 70 重量份。此外，丙烯酸树脂（B）的官能团最好含有环醚基、乙烯氧基、乙烯氧基的酸加合物和活性氢基中的至少一种，活性氢基最好是羟基。 这种光固化树脂组合物对聚碳酸酯和 PET 等粘合性较差的硬质塑料具有足够的固化性和足够的粘合性。
• CATIONICALLY PHOTOPOLYMERIZABLE RESIN COMPOSITION AND OPTICAL DISK SURFACE PROTECTION MATERIAL
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1630189A1

  公开（公告）日：2006-03-01

  The invention provides a cation polymerizable resin composition excellent in curing properties and corrosion resistance with less resin coloration and less cure shrinkage, which is a material suitable as a surface protective material for optical disk. Specifically, the cation polymerizable resin composition comprises an epoxy compound (A) as an essential ingredient represented by formula 1 wherein R1 and R2 each represent a saturated or unsaturated carbon atom, and R3 represents a hydrogen atom or a saturated or unsaturated carbon atom, a cation polymerizable compound (B) other than the epoxy compound represented by formula 1, a photo cation polymerization initiator (C) and a photo radical polymerization initiator (D).

  本发明提供了一种固化性能和耐腐蚀性能优异、树脂着色少、固化收缩小的阳离子可聚合树脂组合物，它是一种适用于光盘表面保护材料的材料。具体地说，阳离子可聚合树脂组合物包括作为基本成分的环氧化合物（A）（由式 1 表示，其中 R1 和 R2 分别代表饱和或不饱和碳原子，R3 代表氢原子或饱和或不饱和碳原子）、除式 1 所示环氧化合物以外的阳离子可聚合化合物（B）、光阳离子聚合引发剂（C）和光自由基聚合引发剂（D）。
• CURABLE COMPOSITION
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：EP3002304A1

  公开（公告）日：2016-04-06

  To provide a curable composition which is curable at a low temperature within a short time regardless of the type of epoxy compound to be mixed, and also exhibits a long pot life; an adhesive comprising the curable composition; a method for producing a fiber-reinforced composite material using the curable composition; and a fiber-reinforced composite material comprising a matrix consisting of the curable composition. An (A) epoxy compound, (B) at least one crosslinking agent selected from the group consisting of a polyhydric amine compound and a polyhydric carboxylic anhydride, and a (C) compound which is an imidazolyl group-containing compound having a predetermined structure are mixed in a curable composition.

  本发明旨在提供一种可固化组合物，该组合物无论混合何种类型的环氧化合物，均可在短时间内低温固化，并且具有较长的固化寿命；一种包含该可固化组合物的粘合剂；一种使用该可固化组合物生产纤维增强复合材料的方法；以及一种包含由该可固化组合物构成的基体的纤维增强复合材料。将(A)环氧化合物、(B)至少一种从多氢胺化合物和多氢羧酸酐组成的组中选出的交联剂和(C)具有预定结构的含咪唑基团的化合物混合在可固化组合物中。