苯甲酸镁盐 | 553-70-8

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 苯甲酸镁盐
• 中文别名: 苯甲酸镁
• CAS: 553-70-8
• 化学式: C7H6MgO2
• 分子量: 146.43
• InChiKey: WDSMIUJRDRSKFV-UHFFFAOYSA-N

物化性质

• 熔点：
  200 °C

计算性质

• 辛醇/水分配系数(LogP)：
  1.0
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2916310090

制备方法与用途

水中溶解度为每100毫升40℃时5克。

文献信息

• METHOD FOR PRODUCING CARBOXYLIC ACID ANHYDRIDE AND METHOD FOR PRODUCING CARBOXYLIC ACID ESTER
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：US20170088502A1

  公开（公告）日：2017-03-30

  Provided is a production method whereby corresponding carboxylic acid anhydrides and carboxylic acid esters can be obtained at high yield from various carboxylic acids even without a solvent and near room temperature. A method for producing a carboxylic acid anhydride represented by formula (II), the method comprising reacting a compound represented by formula (I) and a carboxylic acid in the presence of a Group II metal compound having an ionic ligand containing an oxygen atom. A method for producing a carboxylic acid ester, the method comprising reacting a carboxylic acid anhydride produced by the aforementioned method and an alcohol. In formula (I), R 1 represents a C 1-20 hydrocarbon group. In formula (II), R 2 represents a C 1-20 hydrocarbon group.

  提供了一种生产方法，可以从各种羧酸中高产率地获得相应的羧酸酐和羧酸酯，甚至无需溶剂且接近室温。一种生产由式（II）表示的羧酸酐的方法，该方法包括在含有含氧原子的离子配体的二价金属化合物存在下，使式（I）表示的化合物与羧酸发生反应。一种生产羧酸酯的方法，该方法包括将上述方法产生的羧酸酐与醇发生反应。在式（I）中，R1代表一个C1-20烃基。在式（II）中，R2代表一个C1-20烃基。
• CARBOXYLIC ACID ESTER PRODUCTION METHOD
  申请人：Mitsubishi Chemical Corporation

  公开号：US20180354885A1

  公开（公告）日：2018-12-13

  Provided is a production method whereby corresponding carboxylic acid esters can be obtained from a variety of carboxylic acids at a high yield, even under conditions using a simple reaction operation and little catalyst and even if the amount of substrate used is theoretical. A production method for carboxylic acid ester, whereby a prescribed diester dicarbonate, carboxylic acid, and alcohol are reacted in the presence of at least one type of magnesium compound and at least one type of alkali metal compound.

  提供的是一种生产方法，可以从各种羧酸中以高收率获得相应的羧酸酯，即使在使用简单的反应操作和少量催化剂的条件下，即使使用的底物量是理论上的。一种羧酸酯的生产方法，其中在至少一种镁化合物和至少一种碱金属化合物的存在下，将规定的二酯二碳酸酯、羧酸和醇反应。
• [EN] METHOD OF PRODUCING ALCOHOLS<br/>[FR] PROCÉDÉ DE PRODUCTION D'ALCOOLS
  申请人：SAJET DEV LLC

  公开号：WO2013119230A1

  公开（公告）日：2013-08-15

  A method of making alcohols involves forming of alcohol esters from liquid alkane halides and a solution of metallic salts of organic acids to produce gaseous alcohol esters for reaction with magnesium or metal hydroxides to form the alcohol and the metal salt of the organic acids. In an improvement method, liquid phase alcohol esters instead of gaseous alcohol esters are produced from liquid alkane halides and a solution of metal salts of organic acids whose alkane esters are less soluble in water than that of the alkane halide and treating of the alcohol ester formed with magnesium or metal hydroxides to form the alcohol and the metal salt of the organic acids.

  一种制备醇的方法涉及从液态烷烃卤化物和有机酸金属盐溶液中形成醇酯，以产生用于与镁或金属羟化物反应形成醇和有机酸金属盐的气态醇酯。在一种改进方法中，从液态烷烃卤化物和有机酸金属盐溶液中生成液相醇酯，其烷基酯在水中的溶解度低于烷烃卤化物，然后用镁或金属羟化物处理形成的醇酯，以形成醇和有机酸金属盐。
• [EN] PRODUCION METHOD OF PROPYLENE OXIDE<br/>[FR] PROCÉDÉ DE PRODUCTION D'OXYDE DE PROPYLÈNE
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2009119901A1

  公开（公告）日：2009-10-01

  A production method of propylene oxide, wherein hydrogen, oxygen and propylene are reacted by a multistep process in a mixed solvent of acetonitrile and water, in the presence of a layered precursor of Ti-MWW and a catalyst comprising palladium supported on a carrier.

  一种丙烯氧化物的生产方法，其中氢气、氧气和丙烯在丙腈和水的混合溶剂中，通过多步骤过程，在Ti-MWW的层状前驱体和载体上支撑的钯催化剂的存在下发生反应。
• USE OF DICYCLOHEXYLMETHANOL DERIVATIVES HAVING ANTIMICROBIAL PROPERTIES
  申请人：MERCK PATENT GmbH

  公开号：US20150118172A1

  公开（公告）日：2015-04-30

  The present invention relates to the use of at least one dicyclohexylmethanol derivative of the formula (I) as antimicrobial active compound or as anti-acne, antidandruff, deodorant or antiperspirant active compound, to preparations comprising these compounds, and to specific dicyclohexylmethanol derivatives and to a process for the preparation thereof.

  本发明涉及将式(I)的至少一种二环己基甲醇衍生物用作抗微生物活性化合物或用作抗痘、抗头皮屑、除臭剂或止汗剂活性化合物，以及含有这些化合物的制剂，以及特定的二环己基甲醇衍生物及其制备方法。