1,1-bis(allyloxy)hexane | 1415932-30-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1-bis(allyloxy)hexane
• 英文别名: 1,1-bis(prop-2-enoxy)hexane
• CAS: 1415932-30-7
• 化学式: C₁₂H₂₂O₂
• 分子量: 198.305
• InChiKey: JUGSXYWGFTWTTJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  14
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,1-bis(allyloxy)hexane 、 顺丁烯二酸 在 乙酸酐 作用下， 以 N,N-二甲基乙酰胺 、 水 、 甲苯 为溶剂， 生成 2-allylhexanal
  参考文献：
  名称：

  Method for Producing Bicyclic Compound via Claisen Rearrangement

  摘要：

  本发明要解决的问题是提供一种生产作为α2δ配体具有优异活性的化合物的方法。其解决方法是使用重排反应生产由通式（VI）表示的化合物或其盐：[在公式中，R1：氢原子或C1-C6烷基]。

  公开号：

  US20140094623A1
• 作为产物：
  描述：

  正己醛 在 对甲苯磺酸一水合物 、 magnesium sulfate 、 potassium carbonate 作用下， 以 正己烷 、 水 为溶剂， 生成 1,1-bis(allyloxy)hexane
  参考文献：
  名称：

  Method for Producing Bicyclic Compound via Claisen Rearrangement

  摘要：

  本发明要解决的问题是提供一种生产作为α2δ配体具有优异活性的化合物的方法。其解决方法是使用重排反应生产由通式（VI）表示的化合物或其盐：[在公式中，R1：氢原子或C1-C6烷基]。

  公开号：

  US20140094623A1

文献信息

• DIENE-BASED CARBOXYLATE ANION AND SALT THEREOF, AND POLYMERIZABLE OR CURABLE COMPOSITION THEREOF
  申请人：Kaneko Tomomasa

  公开号：US20130197123A1

  公开（公告）日：2013-08-01

  The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

  所述发明提供了一种新颖的化合物，此化合物以前未被研究过，即一种含有特定结构的二烯二酸盐阴离子及其盐。所述发明进一步提供了一种二烯二酸盐阴离子及其盐，特别是其金属盐，这些盐在一般有机溶剂、反应性稀释剂和树脂中易溶解，在常温下可能处于液态，具有高聚合性。这些的聚合/固化产生的树脂引入了许多离子键和金属，提供了硬度、抗刮擦性、防指纹性、气体屏障性、阻水汽性、氧气吸收性、紫外线保护、红外线保护、颜色开发和着色、高折射率、粘附性、各种催化能力、荧光能力和发光能力、光学放大、分散性和抗静电性等各种性能。此外，该阴离子和盐可用作功能性细颗粒和金属纳米粒子复合材料的原材料，也可用于MOD材料。所述发明还提供了一种生产二烯二酸盐阴离子及其盐的优势方法。
• Methods for producing bicyclic compounds via claisen rearrangements
  申请人：Daiichi Sankyo Company, Limited

  公开号：US09162971B2

  公开（公告）日：2015-10-20

  The problem to be solved by the present invention is to provide a method for producing a compound having excellent activity as an α2δ ligand. The solution thereto is a method for producing a compound represented by the general formula (VI) or a salt thereof using rearrangement reaction: [in the formula, R1: a hydrogen atom or a C1-C6 alkyl group]

  本发明要解决的问题是提供一种生产α2δ配体活性优异的化合物的方法。其解决方案是使用重排反应生产由通式（VI）表示的化合物或其盐的方法：[在式中，R1：氢原子或C1-C6烷基]。
• POLYFUNCTIONAL POLYMERIZABLE COMPOUND AND COLORED COMPOSITION
  申请人：FUJIFILM Wako Pure Chemical Corporation

  公开号：EP3444304A1

  公开（公告）日：2019-02-20

  With a colored composition of the related art, elution resistance within a practical range is not obtained. Therefore, an object of the present invention is to provide a colored composition having better elution resistance (less dye elution) than that of the colored composition of the related art. The present invention relates to a compound represented by the following general formula (1), a colored composition comprising the compound, and the like. In the formula, Dye represents a dye residue, R1 represents a hydrogen atom or a methyl group, Y0 represents a single bond or the like, Y1 and Y2 each independently represent -O- or the like, A1 represents a specific alkylene group or the like, A2 represents an alkylene group which may have -O- in a chain and has a group represented by the following general formula (2) in the chain or on the terminal of the chain, and n represents 1 or 2; (in the formula, R1 and Y2 are the same as described above, R3 represents a group represented by the following general formula (2-1) or the like, and A3 represents a specific alkylene group or the like; [in the formula, R1, A3, and Y2 are the same as described above.].).}

  相关技术中的有色组合物无法获得实用范围内的抗洗脱性。因此，本发明的目的是提供一种有色组合物，它比相关技术的有色组合物具有更好的耐洗脱性（染料洗脱更少）。 本发明涉及由以下通式（1）表示的化合物、包含该化合物的有色组合物等。 在式中，染料代表染料残基，R1代表氢原子或甲基，Y0代表单键或类似物，Y1和Y2各自独立地代表-O-或类似物，A1代表特定的亚烷基或类似物，A2代表在链中可能具有-O-并在链中或链的末端具有下式通式（2）所代表的基团的亚烷基，n代表1或2； (式中，R1 和 Y2 与上述相同，R3 代表下式通式（2-1）或类似通式所代表的基团，A3 代表特定的亚 烷基或类似基团）； [式中，R1、A3 和 Y2 与上述相同）。
• TWO-COMPONENT-TYPE RESIN COMPOSITION FOR HEAT-RADIATING MATERIAL
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP4023716A1

  公开（公告）日：2022-07-06

  This resin composition for a heat-radiating material contains an A liquid and a B liquid, wherein: the A liquid contains a (meth)acrylic polymer, a radically polymerizable monomer, a reaction accelerator, and at least one crosslinking agent selected from the group consisting of a (meth)acrylate-based crosslinking agent and an ally-based crosslinking agent; the B liquid contains a (meth)acrylic polymer and a peroxide-based polymerization initiator; and said resin composition is interposed between a heat-generating element such as an electrical part, such as an automobile battery, and an electronic part, and a heat-radiating element such as a heat sink, a heat-radiating fin, a resin film, and a metal plate, and is thus useful for radiating heat generated from the heat-generating element.

  这种用于热辐射材料的树脂组合物含有 A 液体和 B 液体，其中A 液体含有(甲基)丙烯酸聚合物、可辐射聚合的单体、反应促进剂和至少一种交联剂，该交联剂选自由(甲基)丙烯酸酯基交联剂和烯丙基交联剂组成的组；B 液体含有(甲基)丙烯酸聚合物和过氧化物基聚合引发剂；所述树脂组合物介于发热元件（如汽车电池等电气部件和电子部件）和散热元件（如散热器、散热片、树脂薄膜和金属板）之间，因此可用于散发发热元件产生的热量。
• Viscosity index improver, method for producing the same and lubricating oil composition
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：US10443013B2

  公开（公告）日：2019-10-15

  A viscosity index improver comprising a polymer which has a high viscosity index and good shear stability and which exhibits sufficient solubility in a lubricating base oil, a process for producing the same, and a lubricating oil composition containing the viscosity index improver are provided, wherein the viscosity index improver comprising a polymer satisfying the following (1) to (4): (1) weight-average molecular weight (Mw) of 200,000 or more and 600,000 or less; (2) number-average molecular weight (Mn) of 90,000 or more; (3) molecular weight distribution (Mw/Mn) of 4.0 or less; and (4) branching degree of 1.0 or more.

  本发明提供了一种由聚合物组成的粘度指数改进剂，该聚合物具有较高的粘度指数和良好的剪切稳定性，并且在润滑基础油中具有足够的溶解性，还提供了生产该粘度指数改进剂的工艺以及含有该粘度指数改进剂的润滑油组合物，其中该粘度指数改进剂由满足以下(1)至(4)条件的聚合物组成：(1) 重量平均分子量 (Mw) 为 200,000 或以上，600,000 或以下；(2) 数均分子量 (Mn) 为 90,000 或以上；(3) 分子量分布 (Mw/Mn) 为 4.0 或以下；以及 (4) 支化度为 1.0 或以上。