(+/-)-trans-Pyrethriusaeure | 188745-19-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (+/-)-trans-Pyrethriusaeure
• 英文别名: 3-(2'-methyl-2'-methoxycarbonylvinyl)-2,2-dimethylcyclopropane-1-carboxylic acid；2,2-Dimethyl-3-(2'-methoxycarbonyl-1'-propenyl)-cyclopropanecarboxylic acid；2-(2'-methyl-2'-methoxycarbonylvinyl)-3,3-dimethylcyclopropanecarboxylic acid；Cyclopropanecarboxylic acid, 3-[2-(methoxycarbonyl)-1-propenyl)-2,2-dimethyl-；3-[(E)-3-methoxy-2-methyl-3-oxoprop-1-enyl]-2,2-dimethylcyclopropane-1-carboxylic acid
• CAS: 188745-19-9
• 化学式: C₁₁H₁₆O₄
• 分子量: 212.246
• InChiKey: UIWNHGWOYRFCSF-AATRIKPKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-(4-prop-2-ynylphenyl)prop-2-yn-1-ol 、 (+/-)-trans-Pyrethriusaeure 生成 1-(4-prop-2-ynylphenyl)prop-2-ynyl 3-[(E)-3-methoxy-2-methyl-3-oxoprop-1-enyl]-2,2-dimethylcyclopropane-1-carboxylate
  参考文献：
  名称：

  KATSUDA, JOSIO

  摘要：

  DOI：

文献信息

• Asymmetric copper complex and cyclopropanation reaction using the same
  申请人：——

  公开号：US20020177718A1

  公开（公告）日：2002-11-28

  There are disclosed asymmetric copper complex comprising, as components, (a) an optically active bisoxazoline compound of formula (1): 1 wherein R 1 and R 2 are different and each represent a hydrogen atom, an alkyl group, a cycloalkyl group, or a phenyl or aralkyl group which may be substituted, R 3 and R 4 each represent a hydrogen atom, an alkyl group, a cycloalkyl group, or a phenyl or aralkyl group which may be substituted, or R 3 and R 4 may be bonded to each other to form a C 3-5 cyclic alkylene group, R 5 represents a hydrogen atom or a C 1-6 alkyl group, or the two R 5 groups may be bonded to each other to represent a C 3-5 cyclic alkylene group, (b) a monovalent or divalent copper compound, and (c) a strong acid or a Lewis acid or a mixture thereof, and a process for producing an optically active cyclopropanecarboxylate using the same.

  揭示了包括以下组分的不对称铜络合物：（a）公式（1）的手性双噁唑啉化合物：其中R1和R2不同，每个代表氢原子、烷基、环烷基、苯基或芳基烷基，可能被取代，R3和R4每个代表氢原子、烷基、环烷基、苯基或芳基烷基，可能被取代，或者R3和R4可以相互连接形成C3-5环烷基，R5代表氢原子或C1-6烷基，或者两个R5基团可以相互连接形成C3-5环烷基；（b）一价或二价铜化合物；和（c）强酸或Lewis酸或二者混合物，以及使用它们制备手性环丙烷羧酸酯的方法。
• Microbial enzymatic transformations of chrysanthemol, lavandulol and analogous alcohols to acids
  申请人：BOARD OF REGENTS THE UNIVERSITY OF TEXAS SYSTEM

  公开号：EP0258666A2

  公开（公告）日：1988-03-09

  A method for the production of chrysanthemic, lavandulic and analogous acids involving adding together and incubating under oxidizing conditions the corresponding chrysanthemol, lavandulol or analogous alcohol substrate and one or more oxidizing enzymes originated from a microorganism.

  一种生产菊酸、薰衣草酸和类似酸的方法，包括将相应的菊醇、薰衣草醇或类似醇底物和一种或多种源自微生物的氧化酶加在一起，并在氧化条件下培养。
• Novel carboxylic acid esters, methods for producing them and insecticides containing them as an active ingredient
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0345801A1

  公开（公告）日：1989-12-13

  This invention relates to novel carboxylic acid esters represented by the formula (I) below, methods for their production and insecticides containing them as an active ingredient, wherein R¹ represents a hydrogen atom, a fluorine atom or a methyl group; and R² represents a C₁₋₅ alkyl group, a C₃₋₆ cycloalkyl group, a C₃₋₆ alkenyl group, a C₃₋₆ alkynyl group or a C₁₋₅ haloalkyl group.

  本发明涉及下式(I)所代表的新型羧酸酯、其生产方法以及含有它们作为活性成分的杀虫剂、 其中 R¹ 代表氢原子、氟原子或甲基；和 R² 代表 C₁₋₅ 烷基、C₃₋₆ 环烷基、C₃₋₆ 烯基、C₃₋₆ 炔基或 C₁₋₅ 卤烷基。
• Pyrethroide, Verfahren zu ihrer Herstellung und ihre Verwendung zur Bekämpfung von Schädlingen sowie Vorprodukte für die Herstellung der Pyrethroide
  申请人：BASF Aktiengesellschaft

  公开号：EP0230018B1

  公开（公告）日：1992-08-26
• US3954793A
  申请人：——

  公开号：US3954793A

  公开（公告）日：1976-05-04