硅烷也被称为硅氢化合物,是由硅和氢两种元素组成的化合物。最简单的代表物如甲硅烷(SiH₄)和乙硅烷(Si₂H₆),在组成、结构及物理性质方面与烷烃相似,但亦存在差异。硅烷通常只包含数量不多的硅原子同系物,目前已知最长的链是Si₆H₁₄。
相较于烷烃,硅烷的化学性质更为活泼,Si—H键比C—H键更容易断裂,且热稳定性较差,容易分解为硅和氢。分子量较大的硅烷更加不稳定,在空气中易自燃生成二氧化硅(SiO₂)和水,并能被碱溶液水解。然而,烷基取代的硅烷则具有较好的热稳定性,例如(CH₃)₄Si在空气中不会发生自燃。
室温下,硅烷与卤素反应极为剧烈,可生成卤硅烷;在催化剂存在的情况下,还能与卤化氢作用生成相应的卤化物。尽管硅烷难以合成,目前仍处于理论研究阶段。
中文名称 | 英文名称 | CAS号 | 化学式 | 结构式图片 |
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(4-乙烯基苯基)三甲氧基硅烷 | 4-trimethoxysilylstyrene | 18001-13-3 | C11H16O3Si |
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(4-(1,3-二噁烷-2-基)丁-1-炔-1-基)三甲基硅烷 | 2-<4-(trimethylsilyl)-3-butynyl>-1,3-dioxolane | 79975-88-5 | C10H18O2Si |
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(3S)-4-氯-3-[(三甲基硅烷基)氧基]丁腈 | (3S)-4-chloro-3-[(trimethylsilyl)oxy]butyronitrile | 727382-14-1 | C7H14ClNOSi |
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(3-氰基丙基)二甲基氯硅烷 | (3-cyanopropyl)dimethylsilyl chloride | 18156-15-5 | C6H12ClNSi |
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(2R)-2-[[(叔丁基)二甲基硅烷基]氧基]科立内酯 | (3aR,4S,5R,6aS)-5-((tert-butyldimethylsilyl)oxy)-4-(hydroxymethyl)hexahydro-2H-cyclopenta[b]furan-2-one | 39968-95-1 | C14H26O4Si |
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(2-溴乙炔基)三异丙基硅烷 | 1-bromo-2-(triisopropylsilyl)acetylene | 111409-79-1 | C11H21BrSi |
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(2-溴乙基)三甲硅烷 | (2-bromoethyl)trimethylsilane | 18156-67-7 | C5H13BrSi |
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(2-氰乙基)三乙氧基硅烷 | 2-cyanoethyltriethoxysilane | 919-31-3 | C9H19NO3Si |
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(1R,3r,4s)-4-((叔丁基二甲基甲硅烷基)氧基)-3-(((叔丁基二甲基甲硅烷基)氧基)甲基)-2-亚甲基环戊醇 | (1R,3R,4S)-4-(tert-butyldimethylsilyloxy)-3-[(tert-butyldimethylsilyloxy)methyl]-2-methylenecyclopentanol | 701278-56-0 | C19H40O3Si2 |
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(1-溴乙烯基)三甲硅烷 | 1-bromo-1-(trimethylsilyl)ethene | 13683-41-5 | C5H11BrSi |
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(1-氟乙烯基)甲基二苯基硅烷 | (1-fluorovinyl)(methyl)diphenylsilane | 257610-49-4 | C15H15FSi |
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—— | 5-bromo-2-(((tert-butyldimethylsilyl)oxy)methyl)-3-chloropyridine | 1268816-39-2 | C12H19BrClNOSi |
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—— | trimethyl((tetrahydro-2H-pyran-4-yl)ethynyl)silane | 1604039-54-4 | C10H18OSi |
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—— | Silane, bicyclo[2.2.1]hept-2-yldimethoxymethyl- | 104821-32-1 | C10H20O2Si |
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—— | 1,2-Ethanediamine, N'-[3-(dimethoxymethylsilyl)propyl]-N,N-dimethyl- | 94491-23-3 | C10H26N2O2Si |
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—— | 1-((2S,3R)-1-(diphenylphosphino)-3((triisopropylsilyl)oxy)butan-2-yl)-3-(4-fluorophenyl)thiourea | 1333260-42-6 | C32H44FN2OPSSi |
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—— | 1-diisopropylsilyl-2-[(4-chloromethyl)phenyl]ethane | 214681-46-6 | C15H25ClSi |
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—— | fluorodichlorotrimethylsilane | 90503-30-3 | C4H9Cl2FSi |
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—— | Dimethyl-(trimethylsilyl)-arsin | 6618-05-9 | C5H15AsSi |
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—— | Gd[N(SiMe<sub>3</sub>)<sub>2</sub>]<sub>3</sub> | 35789-03-8 | C18H54GdN3Si6 |
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—— | 1-(2-(benzyloxy)ethyl)-4-(tert-butyldimethylsilyloxy)cyclohexanecarbaldehyde | 943515-17-1 | C22H36O3Si |
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—— | (2-{[(1,1-dimethylethyl)(diphenyl)silyl]oxy}-1-methylpropyl)amine | 1228431-46-6 | C20H29NOSi |
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—— | Chloromethylphenylsilane | 1631-82-9 | C7H8ClSi |
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—— | Trihexylsilane | 2929-52-4 | C18H39Si |
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—— | Chlorodimethylsilane | 1066-35-9 | C2H6ClSi |
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—— | Methyldiethoxysilane | 2031-62-1 | C5H13O2Si |
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—— | trimethoxysilyl radical | 99702-90-6 | C3H9O3Si |
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—— | Phenylsilane | 694-53-1 | C6H5Si |
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—— | Silicopropane | 7783-26-8 | Si3 |
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—— | Dimethylethoxysilane | 14857-34-2 | C4H11OSi |
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—— | 1,1,1,3,3,5,5-Heptamethyltrisiloxane | 2895-07-0 | C7H21O2Si3 |
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—— | Diphenylsilanol | 32129-24-1 | C12H11OSi |
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—— | 1,2,3,4,5,6,7,8-Octamethylcyclotetrasilazane | 2587-47-5 | C8H24N4Si4 |
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—— | Einecs 253-761-8 | 38051-57-9 | C12H26ClSi |
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—— | Tris(trimethylsilyl)germane | 104164-54-7 | C9H28GeSi3 |
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—— | (2S,4R)-4-((tert-butyldimethylsilyl)oxy)pentan-2-ol | 571206-60-5 | C11H26O2Si |
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—— | Tripropylsilane | 998-29-8 | C9H21Si |
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—— | Tris(2-chloroethoxy)silane | 10138-79-1 | C6H12Cl3O3Si |
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—— | N,O-bis(diethylhydrogensilyl)trifluoroacetamide | 105384-38-1 | C10H22F3NOSi2 |
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—— | (E)-trimethyl (3,3,3-trifluoroprop-1-enyl)silane | 55364-28-8 | C6H11F3Si |
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—— | 4-bromo-1-fluoro-2-<<<(1,1-dimethylethyl)dimethylsilyl>oxy>methyl>benzene | 99725-14-1 | C13H20BrFOSi |
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—— | (R)-1-((tert-butyldimethylsilyl)oxy)-3-(octadecyloxy)propan-2-ol | 866784-45-4 | C27H58O3Si |
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—— | (C2H5)2SiH2 | 542-91-6 | C4H10Si |
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—— | Diethylchlorosilane | 1609-19-4 | C4H10ClSi |
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—— | 1,4-Bis(dimethylsilyl)benzene | 228860-42-2 | C10H16Si2 |
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—— | 5-[2-amino-6-(benzyloxy)-9H-purin-9-yl]-3-[dimethyl(phenyl)silyl]-1,2-bis(hydroxymethyl)cyclopentan-1-ol | 701278-05-9 | C27H33N5O4Si |
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—— | [2-(5-{[tert-Butyl(dimethyl)silyl]oxy}-2-methylidenecyclohexylidene)ethyl](oxo)diphenyl-lambda~5~-phosphane | 100858-27-3 | C27H37O2PSi |
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—— | tris<(trimethylsilyl)methyl>phosphine oxide | 18138-52-8 | C12H33OPSi3 |
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—— | tris(triisopropylsilylethynyl)phosphine | 923013-78-9 | C33H63PSi3 |
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—— | 37013-20-0 | C6H14NaO2Si |
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