N-((2S,3S,4R,5S,6S)-2,3,4,5,6-Pentahydroxy-heptyl)-acetamide | 14040-16-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: N-((2S,3S,4R,5S,6S)-2,3,4,5,6-Pentahydroxy-heptyl)-acetamide
• CAS: 14040-16-5
• 化学式: C₉H₁₉NO₆
• 分子量: 237.253
• InChiKey: NTADRNZXXUWBCK-OPZJRAHQSA-N

反应信息

• 作为产物：
  描述：

  1-C-Nitro-1.7-dideoxy-L-glycero-L-taloheptitol 在 palladium on activated charcoal 氢气 作用下， 生成 N-((2S,3S,4R,5S,6S)-2,3,4,5,6-Pentahydroxy-heptyl)-acetamide
  参考文献：
  名称：

  The Synthesis of 2,7-Dideoxy-L-manno-heptose

  摘要：

  2,7-Dideoxy-l-manno-heptose was synthesized from 1-C-nitro-1,7-dideoxy-l-glycero-l-talo-heptitol by the elimination of the C-2 hydroxyl group (nitroolefin formation), by hydrogenation and by the Nef reaction. The corresponding ethyl α-glycoside, its acetate, and a few related 1-amino-1-deoxy derivatives were also described.

  DOI：

  10.1246/bcsj.39.1775