Acetic acid (2S,3S,6R)-2-[(E)-(1S,2R,3R,7R,8S,9S,10R,12R,16S)-3-ethyl-7-hydroxy-2,8,12,16-tetramethyl-5,13-dioxo-10-(2-oxo-ethyl)-4,17-dioxa-bicyclo[14.1.0]heptadec-14-en-9-yloxy]-6-methyl-4-oxo-tetrahydro-pyran-3-yl ester | 77455-43-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Acetic acid (2S,3S,6R)-2-[(E)-(1S,2R,3R,7R,8S,9S,10R,12R,16S)-3-ethyl-7-hydroxy-2,8,12,16-tetramethyl-5,13-dioxo-10-(2-oxo-ethyl)-4,17-dioxa-bicyclo[14.1.0]heptadec-14-en-9-yloxy]-6-methyl-4-oxo-tetrahydro-pyran-3-yl ester
• CAS: 77455-43-7
• 化学式: C₃₁H₄₆O₁₁
• 分子量: 594.7
• InChiKey: IINGJVZTPADOOX-VWNBSTMMSA-N

反应信息

• 作为产物：
  描述：

  乙酸酐 、 rosaramicin N-oxide 以 氯仿 为溶剂， 反应 8.0h， 生成 Acetic acid (2S,3S,6R)-2-[(E)-(1S,2R,3R,7R,8S,9S,10R,12R,16S)-3-ethyl-7-hydroxy-2,8,12,16-tetramethyl-5,13-dioxo-10-(2-oxo-ethyl)-4,17-dioxa-bicyclo[14.1.0]heptadec-14-en-9-yloxy]-6-methyl-4-oxo-tetrahydro-pyran-3-yl ester 、 Acetic acid (2S,3R,4S,6R)-4-(acetyl-methyl-amino)-2-[(E)-(1S,2R,3R,7R,8S,9S,10R,12R,16S)-3-ethyl-7-hydroxy-2,8,12,16-tetramethyl-5,13-dioxo-10-(2-oxo-ethyl)-4,17-dioxa-bicyclo[14.1.0]heptadec-14-en-9-yloxy]-6-methyl-tetrahydro-pyran-3-yl ester
  参考文献：
  名称：

  Chemical degradation and X-ray crystal structure of rosaramicin

  摘要：

  DOI：

  10.1016/0040-4039(80)88097-x