Acetic acid (1R,2R)-2,3-diacetoxy-1-((1S,3S,5R,7R)-7-{2-[(2R,3R,5S)-3-acetoxy-5-(benzoylamino-methyl)-tetrahydro-furan-2-yl]-ethyl}-2,6-dioxa-bicyclo[3.2.1]oct-3-ylmethyl)-propyl ester | 83861-77-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Acetic acid (1R,2R)-2,3-diacetoxy-1-((1S,3S,5R,7R)-7-{2-[(2R,3R,5S)-3-acetoxy-5-(benzoylamino-methyl)-tetrahydro-furan-2-yl]-ethyl}-2,6-dioxa-bicyclo[3.2.1]oct-3-ylmethyl)-propyl ester
• CAS: 83861-77-2
• 化学式: C₃₂H₄₃NO₁₂
• 分子量: 633.693
• InChiKey: XMUQOGOIJGQTPH-TVQQYFBLSA-N

反应信息

• 作为产物：
  描述：

  Acetic acid (1R,2R)-2,3-diacetoxy-1-[(1S,3S,5R,7R)-7-(2-{(2R,3R,5S)-3-acetoxy-5-[(4-bromo-benzoylamino)-methyl]-tetrahydro-furan-2-yl}-ethyl)-2,6-dioxa-bicyclo[3.2.1]oct-3-ylmethyl]-propyl ester 在 palladium on activated charcoal 甲醇 、 溶剂黄146 作用下， 生成 Acetic acid (1R,2R)-2,3-diacetoxy-1-((1S,3S,5R,7R)-7-{2-[(2R,3R,5S)-3-acetoxy-5-(benzoylamino-methyl)-tetrahydro-furan-2-yl]-ethyl}-2,6-dioxa-bicyclo[3.2.1]oct-3-ylmethyl)-propyl ester
  参考文献：
  名称：

  Stereochemistry of palytoxin. Part 1. C85-C115 segment

  摘要：

  DOI：

  10.1021/ja00389a098