(2S,3R,4S,5S,6R)-4-Amino-2-[(1S,2S,3R,4S,6R)-4,6-diamino-3-((2S,3R,6R)-3-amino-6-aminomethyl-6-methyl-3,6-dihydro-2H-pyran-2-yloxy)-2-hydroxy-cyclohexyloxy]-6-hydroxymethyl-tetrahydro-pyran-3,5-diol | 82225-15-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (2S,3R,4S,5S,6R)-4-Amino-2-[(1S,2S,3R,4S,6R)-4,6-diamino-3-((2S,3R,6R)-3-amino-6-aminomethyl-6-methyl-3,6-dihydro-2H-pyran-2-yloxy)-2-hydroxy-cyclohexyloxy]-6-hydroxymethyl-tetrahydro-pyran-3,5-diol
• CAS: 82225-15-8
• 化学式: C₁₉H₃₇N₅O₈
• 分子量: 463.531
• InChiKey: KDXYVDFXLUVARU-BTMRVIOHSA-N

反应信息

• 作为反应物：
  描述：

  (2S,3R,4S,5S,6R)-4-Amino-2-[(1S,2S,3R,4S,6R)-4,6-diamino-3-((2S,3R,6R)-3-amino-6-aminomethyl-6-methyl-3,6-dihydro-2H-pyran-2-yloxy)-2-hydroxy-cyclohexyloxy]-6-hydroxymethyl-tetrahydro-pyran-3,5-diol 在 platinum(IV) oxide 氢气 作用下， 以 水 为溶剂， 以91%的产率得到4-O-(2-amino-2,3,4,6-tetradeoxy-5-C-methyl-L-threo-hexapyranosyl)-6-O-(3-amino-3-deoxy-α-D-glucopyranosyl)-2-deoxystreptamine
  参考文献：
  名称：

  Regiospecific introduction of a branched-chain to kanamycin B and stereospecific transformation of the 2,6-diamino-2,6-dideoxy-D-glucopyranosyl moiety into 2,6-diamino-2,3,4,6-tetradeoxy-3-C-methyl-l-arabino or lyxo-hexopyranosyl, or 2-amino-2,3,4,6-tetradeoxy-5-C-methyl-L-threo-hexopyranosyl

  摘要：

  DOI：

  10.1016/s0040-4039(00)97538-5
• 作为产物：
  描述：

  以 水 、 三氟乙酸 为溶剂， 以78%的产率得到(2S,3R,4S,5S,6R)-4-Amino-2-[(1S,2S,3R,4S,6R)-4,6-diamino-3-((2S,3R,6R)-3-amino-6-aminomethyl-6-methyl-3,6-dihydro-2H-pyran-2-yloxy)-2-hydroxy-cyclohexyloxy]-6-hydroxymethyl-tetrahydro-pyran-3,5-diol
  参考文献：
  名称：

  Regiospecific introduction of a branched-chain to kanamycin B and stereospecific transformation of the 2,6-diamino-2,6-dideoxy-D-glucopyranosyl moiety into 2,6-diamino-2,3,4,6-tetradeoxy-3-C-methyl-l-arabino or lyxo-hexopyranosyl, or 2-amino-2,3,4,6-tetradeoxy-5-C-methyl-L-threo-hexopyranosyl

  摘要：

  DOI：

  10.1016/s0040-4039(00)97538-5