3,4,6,7,9,12,14,15,17,18,21,23,24,26,27,30,32,33,35,36,38,41,43,44,46,47,50,52,53,55,56,58-dotriacontahydro-10,39:11,40-bis(methanoxyethanoxyethanoxymethano)-1H,20H,29H,49H-bis<1,4,7,12,15,18>hexaoxacyclodocosino<9,10-i,9',10'-t><1,4,7,12,15,18>hexaoxac | 108801-75-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,4,6,7,9,12,14,15,17,18,21,23,24,26,27,30,32,33,35,36,38,41,43,44,46,47,50,52,53,55,56,58-dotriacontahydro-10,39:11,40-bis(methanoxyethanoxyethanoxymethano)-1H,20H,29H,49H-bis<1,4,7,12,15,18>hexaoxacyclodocosino<9,10-i,9',10'-t><1,4,7,12,15,18>hexaoxac
• CAS: 108801-75-8
• 化学式: C₅₆H₉₆O₂₄
• 分子量: 1153.36
• InChiKey: ZDSHLHKYOPOCMG-GTYCZPHISA-N

反应信息

• 作为产物：
  描述：

  3,4,6,7,9,12,14,15,17,18,21,23,24,26,27,30,32,33,35,36,38,41,43,44,46,47,50,52,53,55,56,58-dotriacontahydro-39,40-bis((2-(2-hydroxyethoxy)ethoxy)methyl)-1H,20H,29H,49H-bis(1,4,7,12,15,18)hexaoxacyclodocosino(9,10-i:9'10'-t)(1,4,7,12,15,18)hexaoxacyclodo 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 17.0h， 生成 3,4,6,7,9,12,14,15,17,18,21,23,24,26,27,30,32,33,35,36,38,41,43,44,46,47,50,52,53,55,56,58-dotriacontahydro-10,40:11,39-bis(methanoxyethanoxyethanoxymethano)-1H,20H,29H,49H-bis<1,4,7,12,15,18>hexaoxacyclodocosino<9,10-i,9',10'-t><1,4,7,12,15,18>hexaoxac 、 3,4,6,7,9,12,14,15,17,18,21,23,24,26,27,30,32,33,35,36,38,41,43,44,46,47,50,52,53,55,56,58-dotriacontahydro-10,39:11,40-bis(methanoxyethanoxyethanoxymethano)-1H,20H,29H,49H-bis<1,4,7,12,15,18>hexaoxacyclodocosino<9,10-i,9',10'-t><1,4,7,12,15,18>hexaoxac
  参考文献：
  名称：

  百里香聚醚：分子打结环的合成方法

  摘要：

  讨论了实现莫比乌斯带状方法合成分子三叶结的最新进展。具体地，提出了由四羟基甲基乙烯（THYME）单元稠合的冠醚环组成的4-阶梯形二醇二甲苯磺酸酯的合成和环化。另外，讨论了一些低维拓扑的新颖结果，这是由于考虑了由本发明化合物定义的新颖分子图的几何形状而引起的。

  DOI：

  10.1016/s0040-4020(01)87608-0