N-{(2S,3R,4R,5R)-4-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-2,3,5,6-tetrahydroxy-hexyl}-N-(4-nitro-benzyloxy)-acetamide | 129090-71-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: N-{(2S,3R,4R,5R)-4-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-2,3,5,6-tetrahydroxy-hexyl}-N-(4-nitro-benzyloxy)-acetamide
• CAS: 129090-71-7
• 化学式: C₂₇H₄₂N₂O₁₉
• 分子量: 698.632
• InChiKey: UYGNSLBAORYCLK-LHIPJKEWSA-N

反应信息

• 作为反应物：
  描述：

  N-{(2S,3R,4R,5R)-4-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-2,3,5,6-tetrahydroxy-hexyl}-N-(4-nitro-benzyloxy)-acetamide 、 碘甲烷 在 dimsylpotassium 作用下， 生成 N-{(2S,3R,4R,5R)-4-[(2R,3R,4S,5R,6R)-3,4-Dimethoxy-6-methoxymethyl-5-((2R,3R,4S,5R,6R)-3,4,5-trimethoxy-6-methoxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-2,3,5,6-tetramethoxy-hexyl}-N-methyl-acetamide
  参考文献：
  名称：

  1-Alkoxyamino-1-deoxy alditols, useful u.v.-absorbing derivatives of neutral and acidic oligosaccharides

  摘要：

  DOI：

  10.1016/0008-6215(90)84230-r
• 作为产物：
  描述：

  (2S,3R,4R,5R)-4-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-2,3,5,6-tetrahydroxy-hexanal O-(4-nitro-benzyl)-oxime 在 吡啶 、 盐酸 、 sodium cyanoborohydride 作用下， 以 甲醇 为溶剂， 反应 6.0h， 生成 N-{(2S,3R,4R,5R)-4-[(2R,3R,4R,5S,6R)-3,4-Dihydroxy-6-hydroxymethyl-5-((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-2-yloxy]-2,3,5,6-tetrahydroxy-hexyl}-N-(4-nitro-benzyloxy)-acetamide
  参考文献：
  名称：

  1-Alkoxyamino-1-deoxy alditols, useful u.v.-absorbing derivatives of neutral and acidic oligosaccharides

  摘要：

  DOI：

  10.1016/0008-6215(90)84230-r